退火对4-硝基苯硫酚分子常规拉曼峰的影响

文章利用氮气氛围下退火实验实现了4-硝基苯硫酚(PNTP)固体粉末样品中PNTP分子和4,4’-二硝基二苯二硫醚(NPDS)分子的有效分离,考察了不同温度对退火的影响,并利用拉曼光谱对其进行定性分析,同时利用理论计算对NPDS分子的拉曼峰进行了指认.该方法为快速定性PNTP分子中是否含有NPDS提供了快速简便的方法.福建省自然科学基金面上项目(2019J01746

Study on Electrocatalytic Oxidation of sec-Butyl Alcohol on Pt Electrode Modified with Adatoms

运用电化学循环伏安和石英晶体微天平研究了HClO4溶液中仲丁醇在Pt电极及以Sb和S吸附原子修饰的Pt(Pt/Sbad和Pt/Sad)电极上的电催化氧化过程 .从电极表面质量变化可以看出 ,仲丁醇的氧化与电极表面的氧物种有着极其密切的关系 .Pt电极表面Sb吸附原子可在较低的电位下吸附氧 ,明显提高仲丁醇的氧化活性 .与Pt电极相比 ,Sb吸附原子修饰的Pt电极使仲丁醇氧化的峰电位负移约 10 0mV .相反 ,Pt电极表面S吸附原子的氧化会消耗表面氧物种 ,抑制仲丁醇的氧化 .从电极表面质量变化提供了吸附原子电催化作用的数据The processes of adsorption and oxidation of sec butyl alcohol on Pt electrode and Pt electrodes modified with Sb and S (Pt/Sb ad and Pt/S ad ) were studied by using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM). The results demonstrated that the oxidation of sec butyl alcohol depends strongly on oxidation states of electrode surface. Sb adatoms on Pt surface can adsorb oxygen at relatively low potentials, and exhibit catalytic effects for sec butyl alcohol oxidation. In comparison with the case of Pt electrode, the oxidation peak potential of sec butyl alcohol on Pt surface modified with Sb was negatively shifted about 100 mV. On the contrary, the oxidation of S adatoms consumes oxygen species on Pt electrode surface. As a consequence, the oxidation of sec butyl alcohol was inhibited by the presence of S ad . The EQCM studies provided quantitative results of surface mass changes during sec butyl alcohol oxidation, and have thrown new light on elucidating different effects of adatoms Sb ad and S ad on Pt electrode towards sec butyl alcohol oxidation.国家自然科学基金 (2 983 3 0 60 );; 教育部博士点专项科研基金 (19990 3 840 3 );; 福建省教委科研基金资助项目 (K2 0 0 110 1

罗氏沼虾人工育苗若干技术问题的探讨

罗氏沼虾(MACrObrAnCHIunSIWAlIkEnSIS)是一种热带大型虾类,具有生长快、耐高温和食性广等特点,是优良淡水养殖种类。福建省近几年罗氏沼虾养殖发展很快,随之苗种需求也增多,许多单位相继开展该种的人工育苗技术,取得一定成绩,但生产效果仍不够稳定。关于该种的人工育苗技术,在国内已有一些报道。本文系作者根据1995年和199

自组装单层保护金纳米团簇的量子化电容充电

本文研究自组装单层保护金纳米团簇(C12Au MPC)在常温下二氯甲烷溶液中的量子化电容充电效应.示差脉冲伏安曲线显示金核平均直径为2.0 nm的C12Au MPC在-0.6~0.6 V电位区间内有9个明显的量子化电容充电峰,其双电层电容总的变化趋势为在零电荷电位附近最小,随着电位正移或负移电容变大.而且随着该金核尺寸的增大,MPC双电层电容值也变大

Measurement of the Static Optoelectronic Characteristics of InGaAs/InP Avalanche Photodiode

建立了雪崩二极管的静态光电特性的自动测试系统。利用该系统对光敏面的直径为500μm的台面型InGaAs/InP雪崩光电二极管(APDs)进行测试。测试结果表明,该APD器件在90%击穿电压下的暗电流为151nA,在直径500μm的光敏面上其光响应均匀性良好。提出一种测量雪崩二极管倍增因子的方法,只需利用普通的测量电流-电压的测试仪器,就可以获得开始倍增时的光电流,从而得到APD的倍增因子。通过该方法得到的InGaAs/InPAPD器件最大倍增因子的典型值在10～100量级。A measurement system is set up which could measure static optoelectronic characteristics of avalanche photodiodes (APDs). By using this system, the mesa-structure InP/InGaAs APDs is measured. The results show that the APDs have a relatively low dark current (～150 nA at 90% of breakdown) and a uniform photoresponse profile of about 500 μm diameter. A method of getting APDs's multiplication gain is also proposed. Through getting the photocurrent at the point where multiplication is beginning, the multiplication gain can be obtained by the simple current-voltage equipment. For InP/InGaAs APDs, the typical maximum multiplication gain measured by this method is about 10～100

有机玻璃表面增强增透的研究

采用溶胶-凝胶体系制备光学塑料(有机玻璃:PMMA)表面增强的有机硅树脂涂层,制得Si-O-Si刚性交联网络涂层,具有良好的耐磨性及附着力,其表面平整、光滑,同时对PMMA基板的透光性具有明显的改善.并通过红外吸收光谱(FT-IR),紫外分光光度计(UV-vis)等手段,对涂层固化过程及各项性能进行表征

INVESTIGATION OF SALT DAMAGE IN MANGO TREES IN XIAMEN

“叶焦病”是闽南地区芒果（Ｍａｎｇｉｆｅｒａ ｉｎｄｉｃａ Ｌ．）的一种常见病．对不同地点受害植物的叶片及土壤理化指标的分析表明：①土壤酸度、总Ｎ、总Ｐ、Ｋ、Ｎａ等含量与芒果受害程度无关；②受害程度与叶片Ｃｌ、Ｋ含量、３０—４０ ｃｍ土壤Ｃｌ含量及总盐含量呈显著正相关；③造成厦门地区芒果“叶焦病”的主要原因是盐害，其中起主要作用的是Ｃｌ；④芒果是一种对盐比较敏感的植物，土壤总盐含量达０．４８９‰时仍可正常生长，高于此含量则出现受害症状．Leaf scorch in mango (Mangifera indica L.) trees was investigated in March, 1997 in 13 sites at 30-300 m from seashore of Xiamen City. Symptom of leaf scorch in shoot leaves was divided into 6 grades. Soil properties and elements in leaves were tested. The results showed that soil pH and the total N, P, K and Na contents were not related to the leaf scorch damage. The degrees of injury caused by leaf scorch were positively related to the content of Cl and K in leaves and to the Cl and salt contents in soil at 30-40 cm depth. It is concluded that the main factor resulting in leaf scorch is salt, and Cl plays an important role. Mango trees grow normally in soil under 0.489‰ salinity

PET碳酸饮料瓶结晶与流变性能研究

通过偏光透射法研究PET碳酸饮料瓶结晶分布情况,稳态与动态流变法研究PET树脂的流变性能,探讨PET瓶应力开裂的原因.结果表明:瓶身结晶分布不均匀,树脂分子量分布窄、有极高分子量存在、粘性太大易造成应力集中或应力残留,使PET碳酸饮料瓶耐应力开裂能力变差

The Flame Retardant Property of ABS/Silicone Rubber Blends

研究了十溴联苯醚/三氧化二锑(DBDPO/Sb2O3)、有机硅橡胶/含氟聚合物、有机硅橡胶/硬脂酸镁、二盐基亚磷酸铅、滑石粉对ABS燃烧性能的影响.研究结果表明:DBDPO/Sb2O3阻燃体系配合含氟聚合物对ABS/硅橡胶共混物的阻燃是有效的.当硅橡胶2PHR、含氟聚合物1PHR、添加剂DBDPO/Sb2O320PHR时,ABS的氧指数达27;二盐基亚磷酸铅对硅橡胶/硬脂酸镁阻燃ABS有较强的助阻燃作用.In this paper, the effects of DBDPO/Sb_2O_3, silicone rubber/fluorine-containing polymer, silicone rubber/magnesium stearate, dibasic lead phosphite and talcum powder on the flame retardance of ABS plastics were studied. The results demonstrated that DBDPO/Sb_2O_3 fire resistant system combined with fluorine-containing polymer was effective in improving the flame retardant property of ABS/silicone rubber blends. By adding silicone rubber 2 PHR, fluorine-containing polymer 1 PHR, additive, DBDPO/Sb_2O_3, 20 PHR, the OI value of ABS could reach 27. Dibasic lead phosphite was good flame retardant aid to ABS fire retarded with silicone rubber/magnesium stearate

EQCM and in-situ reflectance FTIR spectroscopic studies of adsorption and oxidation of methanol on Pt electrode in alkaline media

The adsorption and oxidation of methanol on Pt electrode in alkaline media have been investigated by using cyclic voltammetry, electrochemical quartz crystal microbalance (EQCM) and in-situ reflectance FTIR spectroscopy. The experimental results demonstrated that the electrooxidation of CH3OH was closely relative to solution acidity. Only one current peak of methanol oxidation in PGPS was detected at -0.09 V, which illustrated the disappearance of the second current peak due to Pt electrode passivation in alkaline media. The magnitude of the dissociative adsorbate of methanol in alkaline media is smaller than that in acidic media. The main product, such as CO2 and CO32-, was detected clearly and the reactive intermediates that were determined by FTIRS under experimental condition might be mainly HCOO- species. The EQCM studies provide quantitative results of surface mass changes during methanol oxidation, and have thrown new light in the elucidating methanol oxidation