清代科举士子在台湾的影响研究

清政府在康熙年间收复台湾,随即在台湾推行科举制,科举制的推行对正处于社会转型期的台湾意义重大。取得功名的科举士子不仅极大的提升了自己和家族的地位,与此同时也掌握了一定的经济资本。成为士绅阶层的科举士子积极参与文教活动和社会活动,影响了台湾文教和社会发展,促进了台湾地区的繁荣

Harmony Sound——Community Culture Carrier:Huayang Community Cultural Center

社区文化中心应体现“城市让生活更美好“的主题,是创造社会主义文明,提高市民素质的园地,是为社区服务的现代文化设施。同时,和谐的建筑是和谐社会的载体,该项目的建设也是改造、创建和谐社区的一个范例。Community Cultural Center should embody the theme that the city should make life better.Community Cultural Center is garden plot which creates socialistic civilization and improves the diathesis of citizen.It is modern cultural facility served for the community.At the same time,the harmonious architecture is the carrier in the harmonious society,the building is an example that the government is reconstructing and establishing the harmonious community

壁面微通道冷却对旋流燃烧室性能影响实验

为了探索微通道高效换热技术在低污染燃烧室壁面冷却中的应用,实验研究了壁面微通道冷却对模型旋流燃烧室性能的影响。结果表明:微通道结构对燃烧室热壁面具有显著的冷却效果,在雷诺数小于350时,雷诺数增加对壁面冷却有明显提升作用,在雷诺数大于350后,雷诺数的增大对冷却效果提高的促进作用减小;雷诺数增大对相同进气工况下CH*化学发光信号表征的火焰时均结构几乎不产生影响,但在个别工况下会使火焰产生黄色火星,甚至间歇地产生黄色火焰,带来不完全的燃烧;雷诺数增大会增强微通道对流换热程度,加大壁面传热速率,加剧火焰和微通道换热间的相互作用,使火焰表面发生较大的热量损失,最终造成CO排放量增加,NOx排放量降低,并使整体燃烧效率下降。国家自然科学基金(51406171);;福建省自然科学基金(2016J06011);;中央高校基本科研业务费(20720180058);;航空科学基金(20152868006

微囊藻毒素-RR对烟草细胞活力及营养生理的影响

采用0.1,1.0,10.0μg/mL的微囊藻毒素-RR(MC-RR)处理烟草BY-2悬浮细胞,测定了细胞活力、细胞内蛋白质含量、可溶性糖含量、硝态氮含量及总磷含量,并且检测了酸性磷酸酶(ACP)的活力变化情况.结果表明,中、高浓度毒素处理细胞2d后,细胞活力及蛋白质含量与对照相比均显著下降.高浓度MC-RR处理降低了胞内可溶性糖的含量,暴露2d后仅为对照的45.57%;低浓度MC-RR处理在后期增加了胞内可溶性糖含量.高浓度毒素处理细胞4d后,细胞内硝态氮含量显著低于对照;中、低浓度毒素处理细胞7d后

口服益生菌改善铝诱发的小鼠海马炎症

【目的】探讨口服益生菌能否改善铝暴露诱发的小鼠海马炎症。【方法】通过给予小鼠口服氯化铝，建立海马炎症模型，将24只8周龄雄性小鼠C57BL/6随机分成对照（CON）组、氯化铝处理（Al）组、益生菌处理（PO）组和联合处理（Al+PO）组，每组各6只，分别持续给予口服氯化铝和（或）益生菌6周。海马神经炎症的评估，采用免疫荧光染色法检测小鼠海马组织中激活的小胶质细胞（Iba-1+/CD68+）数量以及脑源性神经营养因子（BDNF）的表达量，酶联免疫吸附测定法检测血清和海马组织中白介素-1β（IL-1β）和肿瘤坏死因子-α（TNF-α）的含量。【结果】免疫荧光染色法研究结果显示：与CON组相比，Al组海马组织中Iba-1+/CD68+细胞数量显著增加（<0.01），而BDNF表达量显著减少（<0.01）；与Al组相比，Al+PO组海马组织中Iba-1+/CD68+细胞数量显著减少（<0.01），而BDNF表达量增加（<0.01）。酶联免疫吸附测定（ELISA）研究结果显示：与CON组相比，Al组血清和海马组织中的IL-1β和TNF-α含量均有显著增加（<0.01）；与Al组相比，Al+PO组血清IL-1β含量显著减少（<0.01），海马组织中的IL-1β和TNF-α含量均显著减少（<0.01）。【结论】口服益生菌可改善铝暴露诱发的小鼠海马炎症

Studies on degradation mechanism of niclosamide ethanolamine salt Ⅱ Isotopic tracing and determination of photolysis end-product

目的观察同位素示踪技术解析氯硝柳胺乙醇胺盐(nES)在水体中的稳定性及测定光解终产物CO2的变化。方法实验室配制PH5的0.05μg/Ml、PH7的0.5μg/Ml和PH9的2.5μg/MlnES溶液,采用氙灯光源作为模拟日光照射上述nES溶液,照射8、16、24、32、40、48H和72H后,分别测定nES溶液在光解管顶的气态样品,采用gASbEnCHⅡ进样针插入直接分析;液体样品则取2.5Ml注入用高纯氦吹过的密封顶空样品瓶中,用加酸泵滴加无水磷酸,30℃超声反应1H,再插入gASbEnCHⅡ进样针进行分析;与dElTAPluS/XP稳定同位素质谱仪联用测定光解产物CO2的量及碳稳定同位素。结果在氙灯光光照条件下,PH70.5μg/Ml和PH92.5μg/MlnES溶液的光解,随光照时间的增加,CO2的量也增加,并呈线性增长,72H时其产量接近nES的实际产量。同位素结果显示,随光照时间的增加,CO2的碳同位素值逐渐变负,72H时接近nES原药的碳同位素值,为-25.36±0.11,光降解已接近完全。而PH50.05μg/MlnES溶液的光解,随光照时间的增加,CO2的量也在增加,但其产量超出了nES的实际产量;同位素结果显示,随光照时间的增加,产出CO2的碳同位素值逐渐变负,但在光照16H后其产CO2的碳同位素值比nES的碳同位素值偏负。结论 nES能够在水中快速光解,终产物为CO2。Objective To analyze the stability of niclosamide ethanolamine salt(NES)in water and determine the changes of CO2,the photolysis end-product,by using the isotopic tracing technique.Methods NES was formulated into the solutions of pH 5(0.05 μg/ml),pH 7(0.5 μg/ml)and pH 9(2.5 μg/ml),respectively.The xenon gas lamp was used as the simulated sunlight.After 8,16,24,32,40,48,72 h of the illumination,the gas samples of the NES solution on the top of photolysis tube were determined by using direct insertion of GasBenchII needle.For liquid samples,2.5 ml NES solution was added into a sealed empty bottle,which was treated with high pure helium,and then anhydrous phosphoric acid was added.After ultrasonic reaction at 30 ℃ for 1 h,the GasBenchII needle was inserted for analysis.The amount of CO2 and carbon isotopic value were determined by using the GasBenchII needle combined with isotopic mass spectrometer.Results Under the illumination of xenon gas lamp,the NES solutions of pH 7 and pH 9 occurred photolysis,with the increase of illumination time,the amount of CO2 increased,showing a linear increase.At 72 h,its yield approximated to the active output of NES.The isotopic tracing results showed,with the increase of illumination time,the carbon isotope value of CO2 turned to be negative gradually,and approximately reached to the carbon isotope value(-25.36±0.11‰)of NES active ingredient at 72 h when the photolysis approximated to be completely finished.For the photolysis of pH 5 NES solution,with the increase of illumination time,the amount of CO2 increased,however,its output was more than the active output of NES.The isotopic tracing results showed,with the increase of illumination time,the carbon isotope value of CO2 turned to be negative gradually.However,after illumination for 16 h,the carbon isotope value of CO2 was more negative than that of NES.Conclusions The photolysis of NES can occur rapidly in water,and the end product is CO2.江苏省自然科学基金(BK200602);江苏省卫生厅项目(X200504

Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Chiral Carbonyl Iron Systems

手性羰基铁络合物很少被用于芳香酮的不对称氢转移氢化 .利用不同的羰基铁络合物与手性双胺双膦配体现场络合 ,形成手性胺膦铁催化体系 .考察了它们对多种芳香酮的不对称氢转移催化氢化性能 .结果表明 ,三核的手性胺膦铁簇合物是催化芳香酮不对称氢转移氢化的较好体系 .当用三核的铁簇合物 [Et3 NH] + [HFe3 (CO) 11] -体系催化 1,1 二苯基丙酮的氢化时 ,最高可获得 98%的对映选择性 .通过现场红外光谱测定 ,揣测羰基铁簇合物Fe3 (CO) 12 在催化反应过程中保持三核的簇合物的簇骼不变 .Chiral carbonyl iron systems have seldom been used in asymmetric transfer hydrogenation of aromatic ketones. In this study, new chiral iron catalytic systems were synthesized in situ from different carbonyl iron complexes with chiral diaminodiphosphine ligands, respectively. These catalytic systems have been used for the asymmetric transfer hydrogenation of various aromatic ketones under mild conditions. The results indicated that trinuclear iron complexes were the best systems for the reactions. When the [Et 3NH]+[HFe 3(CO) 11]- as catalyst was used for asymmetric reduction of 1,1-diphenylacetone, high enantioselectivity up to 98% was achieved. Monitoring the reaction in situ by infrared spectroscopy, it could be conjectured that the carbonyl iron cluster Fe 3(CO) 12 kept its trinuclear skeleton unchanged during the catalytic reaction.国家自然科学基金 (No.2 0 3730 56);; 福建省科技厅重大科技项目 (No.2 0 0 2F0 1 6);; 福建省厦门市科技局重大科技项目 (No .350 2Z2 0 0 2 1 0 4 4 )资

Effects of Cadmium Stress on Seed Germination and Seedling Growth of Dwarf Beans

为比较系统地探讨Cd2+的生物毒性,作者以水培法研究了不同浓度的Cd2+溶液对四季豆种子萌发和幼苗生长发育过程中植物外部生长指标及内部生理生化变化的影响。结果表明:当Cd2+浓度较低时,Cd2+对种子萌发及幼苗生长发育毒害作用较小,一定浓度范围内(0.05~0.5Mg/l)还有促生作用,高浓度Cd2+(5~100Mg/l)能严重抑制四季豆幼苗根及下胚轴的生长;Cd2+胁迫对四季豆幼苗体内过氧化物酶(POd),超氧化物歧化酶(SOd),过氧化氢酶(CAT)活性存在低浓度激活和高浓度抑制的效应,且同一浓度的Cd2+对四季豆幼苗POd、CAT活性的抑制作用表现为根系大于下胚轴,Cd2+浓度>0.5Mg/l时,根系SOd活性大于下胚轴中的活性;Cd2+胁迫下,四季豆下胚轴和根的丙二醛(MdA)含量增加,且根部含量大于下胚轴的量。Cd2+对矮生四季豆种苗生长发育的影响因Cd2+浓度及幼苗部位的不同而异。In order to explore the biological toxicity of Cd2+more systematically, the effects of Cd2+ on the external and internal physiological and biochemical changes in the process of dwarf beans seed germination and seedling growth were studied with hydroponic culture experiments.The results showed that when the concentration of Cd2+ at low level, the effects of Cd2+ on the seed germination and seedling growth were not significant.Seeds germination were activated at a certain extent when Cd2+ concentration ranged from 0.05mg/L to 0.5 mg/L concentrations.The roots and Hypocotyls of seedling exhibited a significant decrease in growth at higher level of Cd2+ concentrations (5～100mg/L).The activities of peroxidase (POD), superoxide dismutase (SOD), catalase (CAT)could be enhanced at low Cd2+concentrations but inhibited at higher concentration.The activities of POD, CAT were more inhibited in roots than in Hypocotyls at the same Cd2+ concentrations, while that of SOD was higher in roots than in Hypocotyls when the concentration of Cd2+ was more than 0.5mg/L.The malondialdehyde (MDA) contents were continuously increased with Cadmium exposure in both roots and Hypocotyls.The effects of Cd2+on the dwarf beans’growth were varied with the concentration of Cd2+ and the parts of plants.“2007AA10Z441”项目的资助;“07JC14025”项目的资助;“07DZ12055”项目的资