以氨燃料为介质的全生命周期储能效率估算

本文讨论了氨作为燃料使用会具备与传统化石燃料显著不同的环境效益,并进一步探讨了氨作为储能介质的特点,包括储能密度和规模大、受地理条件约束小、便于运输存储等。本文还针对目前的合成氨路线从理论分析和工业实际两个方面对合成效率进行了估算和评价。针对目前国内核能、风能、太阳能等清洁能源电力的低谷或弃电问题,建议采用以制氨的方式存储或外运,以便于在电力不足时将其用于发电。建议并评估了几条基于制氨并发电的路线,并基于现有氨燃料的发电效率计算了各路线在全生命周期内的总储能效率(25%~40%)和以电换电的效率[2.5~4.0(度/10度)]。福建省自然科学基金项目(2014J01209);;厦门大学能源学院-金隆昌氨能源及动力联合研发中心经费项目(0290K8110075);;福建省闽江学者经费项目(X170300101

Photoemissive structure in zinc sulFide

对硫化锌粉料、硫化锌半导体微晶薄膜进行了X射线光电子发射谱剖析。获得粉料、薄膜表层及表层下的电子态信息，揭示了硫化锌粉料、薄膜微结构与电致发光性能的关系: On the basis of analysis on XPS (X-ray photoelectron spectroscopy) technique the inFormation on electron states of ZnS powder, ZnS thin Film surFace and internal layer is obtained.The eFFect of the microstructure of ZnS powder and ZnS thin Film on electroluminescent characteristics is revealed.福建省自然科学基

氨燃料缓解能源安全及替代天然气的可行性分析

文章主要针对我国面临的能源安全问题及现阶段出现的北方地区\"气荒\"现象,结合氨燃料储能密度高、燃烧清洁、热值较高、易储存运输、产业基础完善、用处广泛的特点以及厦门大学的锅炉及发电机掺氨燃烧运行成功的实验结果,定量分析氨燃料可缓解能源安全问题的程度及解决\"气荒\"问题的规模与容量。分析结果表明:引入氨能源体系可以有效优化中国的能源结构,改善过度依赖能源进口的现状,解决天然气短缺的问题。福建省闽江学者经费项目(X170300101);;\n厦门大学能源学院-金融昌氨能源及动力联合研发中心经费项目(0290K8110075

C_（60）的产生与石墨晶面的关联（I）

Ｃ_（６０）的产生与石墨晶面的关联（Ｉ）谢兆雄，刘朝阳，林逢辰，王春儒，郑兰荪（厦门大学化学系固体表面物理化学国家重点实验室厦门，３６１００５）关键词Ｃ_（６０），激光溅射，石墨晶面Ｓｍａｌｌａｙ等［１］曾以激光在超声分子束喷口的喉道处蒸发石墨得到了Ｃ..

A High-Precision Method for Determining the FBG Peak Wavelength Shift Based on FBG Actual Reflection Spectrum Match

针对目前光纤布拉格光栅(fbg)解调方案中采用低分辨率CCd测量fbg峰值波长时存在的问题,提出一种采用基于fbg实际反射谱构建基函数匹配CCd测量获得的有限测量点确定fbg峰值波长偏移量的新方法。分别在理论和实测上对这种方法的有效性和可行性进行了研究,证明这种采用fbg实际反射谱函数匹配有限测量数据的方法比采用特定函数拟合测量数据的方法能够更准确地获得fbg峰值波长的偏移量。实现了在CCd采样点数少、光谱分辨率较低的情况下对fbg峰值波长偏移量的高精度确定,有效地提高了实际工程应用中基于低成本CCd解调fbg峰值波长及其微小偏移量的准确性。Referring to the problems in using low-resolution charge coupled device(CCD) to measure fiber Bragg grating(FBG) peak wavelength,a high-precision method for determining the FBG peak wavelength shift by matching basis function based on the FBG actual reflection and sampling data measured by CCD is proposed.The effectiveness and feasibility of the new method are studied theoretically and experimentally.It is proved that compared with fitting sampling data by specific functions,the matching method based on FBG actual reflection spectrum can determine FBG peak wavelength shift more accurately.In the case of few sampling data and low resolution of CCD measurement,the high-precision determination of FBG peak wavelength shift is achieved.The accuracy of demodulation of FBG peak wavelength shift using low-cost CCD in the practical applications is improved effectively.国家自然科学基金(61077031);国家质检总局科技计划项目(2010IK077)资助课

STUDY ON THE CONSTRUCTION AND IMMUNOLOGY CHARACTERISITCS of SIX-VA-LENT FUSION TOXIN of FOOD POISONING-BORNE BACTERIA

[目的]构建4种食源性致病菌融合毒素基因及重组表达载体,制备六联融合毒素的血清抗体。[方法]采用柔性lInkEr序列(g-g-g-g-S)对目的基因进行串联(HblA-VT1b-SEA-VT2b-bOnTAHC-SEb),构建重组表达质粒PET-22b(+)-f6并在E.COlI bl21中进行表达,将表达蛋白纯化后免疫豚鼠制备血清抗体,利用ElISA和琼脂扩散试验验证抗体的特异性与敏感性。[结果]成功构建了重组表达质粒PET-22b(+)-f6并在E.COlI bl21中成功表达,37℃表达蛋白主要以包涵体形式存在(表达量10.2%),基因序列全长3384bP,编码1127个氨基酸,蛋白分子量为127205,测序结果与设计序列一致性为100%。ElISA和琼脂扩散试验表明,融合毒素f6与4种食源性致病菌有良好的反应原性,与多种非目标菌不反应。[结论]成功构建了多联融合毒素基因的表达质粒及制备了抗血清,为利用融合毒素的方法检测食源性致病菌,进而建立食源性致病菌广谱、快速的检测方法奠定基础。[Objective] To construct toxin including fusion toxin gene from food poisoning bacteria and its recombinant expression vector,and then prepare serum antibody of Six-valent fusion toxin.[Methods] Six gene(HblA—VT1B—SEA— VT2B—BoNTaHc—SEB)fragments were connected by SOE-PCR via linker sequence encoding five amino acids(G-G-G-G-S),the recombination expression plasmid pET-22b(+)-F6 was constructed and expressed in E.coli BL21.The expression proteinum was purified,and the blood serum was prepared by the immune cobaya,The specificity and sensitivity of antibody were verified by the ELISA and agar diffusion reaction.[Results] The fusion gene F6(HblA—VT1B—SEA—VT2B—BoNTaHc—SEB)and re-combinant plasmid pET-22b(+)-F6 was successfully constructed.The most of the 37℃ expression proteinum showed to be cyt-orrhyctes(expreesion amounted to 10.2%).The sequence encoding the mature fusion protein of the F6 toxin gene was 3384bp,encoding 1127 amino acids.The molecular weight of recombinant fusion toxin protein was 127.205 ku.The result of sequencing was consistent with predicted gene sequences.The results of ELISA and agar diffusion reaction demonstrated that fusion gene F6 and other four kinds of food poisoning-born bacteria had favorable reactionogenicity and did not response to many other non-tar-get bacteria.[Conclusion] The expression plasmid of multi-valent fusion toxin was successful constructed and antiserum was prepared,which laid the foundation for establishing broad spectrum and rapid detection method for food poisoning bacteria by utilization of fusion toxin detection methods.国家自然基金资助项目(30671762);厦门市科技计划项目(3502Z20055009