Dynamics of tannin concentration and nutrient resorption for branchlets of Casuarina equisetifolia plantations at different ages

通过对福建省惠安县不同林龄短枝木麻黄人工林不同发育阶段小枝单宁含量及氮磷再吸收率的研究,探讨了短枝木麻黄林分发育过程中的营养保存策略。结果表明,幼龄林(5年生)成熟小枝中的总酚(TP)、可溶性缩合单宁(ECT)总缩合单宁(TCT)含量及蛋白质结合能力(PPC)显著高于成熟林(21年生)和衰老林(38年生)。随着林分发育,成熟小枝中n含量显著升高,而P含量呈降低趋势。不同发育阶段林分成熟小枝中n∶P比均大于20,且随着林龄的增加而升高。磷再吸收率(PrE)显著高于氮再吸收率(nrE),均以成熟林分最高。这表明短枝木麻黄小枝单宁含量与养分再吸收受林龄影响,其养分保存机制会随着林分生长发育的变化而进行调节。Casuarina equisetifolia is characterised by high primary productivity in coastal sandy soils,which are generally low in nutrient contents.High tannin production and nutrient resorption may be important strategies for C.equisetifolia in coastal environments.Despite the widespread planting and known ecological and physiological properties of C.equisetifolia,there is scant information about the nutrient resorption patterns and tannin concentrations for branchlets of C.equisetifolia plantations during stand development.Since plant ecophysological traits are associated with ageing,tannin content and nutrient resorption efficiency could change with stand development.Therefore,tannin level and nutrient resorption of C.equisetifolia at different developmental phases(juvenile,mature and senescent) were examined to evaluate possible nutrient conservation strategies under nutrient limitation in Huian County,Fujian Province.The results showed that total phenolics(TP) contents,which were in the order juvenile stand > senescent stand > mature stand for senescent branchlets and decreased from 218.52 to 180.49 mg / g during stand development for mature branchlets,decreased during branchlet senescence in all stands.The extractable condensed tannin contents(ECT) in mature and senescent branchlets of C.equisetifolia were juvenile stand > senescent stand > mature stand.The ECT contents of C.equisetifolia increased during branchlet senescence both in the mature and senescent stands but decreased in the juvenile stand.The protein-bound condensed tannin(PBCT) contents of branchlets increased during senescence in juvenile and mature stands and remained the same in senescent stand.The fibre-bound condensed tannins(FBCT) of branchlets increased during senescence in mature stand and did not change in juvenile and senescent stands.Total condensed tannin(TCT) followed similar pattern as ECT during stand development.Protein precipitation capacity(PPC) in mature and senescent branchlets were significantly higher in juvenile stand than in mature and senescent stands.PPC decreased during branchlet senescence in the three stands.Significant positive linear correlations were found between PPC and TP or TCT.Nitrogen(N) concentrations both in mature and senescent branchlets obviously increased during stand development.Phosphorus(P) concentrations in mature branchlets were similar in juvenile and mature stands but lower in senescent stand.Phosphorus concentrations in senescent branchlets of juvenile stand were significantly higher than those of mature and senescent stands.Nitrogen: phosphorus ratios(N ∶P ratios) of mature branchlets,were all above 20,also increased during stand development.Nitrogen resorption efficiencies(NRE) in three stands were basically below 50%,the lowest in senescent stand.Phosphorus resorption efficiencies(PRE) were above 70% with the highest in mature stand(78.08%).There were significant negative correlations between N and P concentrations in mature and senescent branchlets.Nitrogen resorption efficiency had a particular strong relationship with the N ∶P ratios of branchlets.On the other hand,PRE was not significantly related to N ∶P ratios of branchlets.There were significant correlations between TP or TCT and N or P concentrations in branchlets except for the relationship between TCT and P concentrations in senescent branchlets.The above results indicated that the tannin level,nutrient concentration and resorption were affected by stand age.C.equisetifolia could adjust their nutrient conservation with stand development at intraspecific level.国家自然科学基金项目(41201293;41176092); 国家“十一五”科技支撑计划项目(2009BADB2B0302); 国家林业局南方山地用材林培育重点实验室和福建省森林培育与林产品加工利用重点实验室资助项

Contents of Some Mineral Elements and Their Resorption Efficiencies in Casuarina equisetifolia Branchlets Across a Coastal Gradient

对福建东山赤山林场不同海岸梯度上短枝木麻黄小枝中的钾(k)、钙(CA)、镁(Mg)、钠(nA)、铁(fE)、锰(Mn)和锌(zn)元素含量及其再吸收率动态进行了研究.结果表明,海岸梯度对短枝木麻黄小枝中各元素含量及其再吸收率均具有显著影响.在各海岸梯度上,k再吸收率为正值,且基干林带的再吸收率显著低于其它样地,fE和zn为负值,CA、Mg和nA再吸收率在防护林带前沿为负值,而在后沿林为正值,Mn则相反.这表明,基干林带严重的环境胁迫显著降低了短枝木麻黄小枝的养分再吸收率.短枝木麻黄成熟小枝中的k、Mg含量与其再吸收率存在显著正相关,而nA和fE与其再吸收率存在显著负相关,其它元素与其再吸收率之间没有显著相关性.除k外,各元素在衰老小枝中的含量与相应元素再吸收率之间均存在显著负相关,表明元素再吸收程度越高,其再吸收率就越高.CA、Mg、nA和fE再吸收率之间具有显著的正相关关系(P<0.01),zn除与Mn再吸收率呈显著正相关外,与其它元素均表现为负相关,Mn则与其它元素再吸收率之间没有显著相关性.因而短枝木麻黄小枝中不同类型的养分状况对其再吸收率具有不同的影响.表5参42Contents of some mineral elements and their resorption efficiencies in Casuarina equisetifolia branchlets across a coastal gradient were studied at the Chishan Forestry Center of Dongshan County,Fujian Province,China.The results showed that the distance to coast had a significant effect on the contents of mineral elements and their resorption efficiencies.Resorption efficiencies of K element(REK) were all positive across the coastal gradient,with the lowest value found at the coastline sampling site,while Fe and Zn resorption efficiencies(REFe and REZn) were all negative across the coastal gradient.Ca,Mg and Na resorption efficiencies(RECa,REMg and RENa),which were contrary to Mn(REMn),were negative in seaward plantations and positive in inland plantations.It was suggested that the resorption efficiencies of the mineral nutrients significantly decreased with severer environmental stresses.There were also significant positive correlations between the K and Mg content and their resorption efficiencies in mature branchlets while the correlations between the Na and Fe content and their resorption efficiencies were significantly negative.In senescent branchlets,the content of all the elements and their resorption efficiencies except for K were negatively correlated.In addition,the correlation was positive between REZn and REMn,while negative between REZn and resorption efficiencies of other elements.No correlation was found between REMn and resorption efficiencies of other elements.These results showed that nutrient conditions in branchlets had different effects on their resoption efficiencies for different mineral nutrients.Tab 5,Ref 42国家“十一五”重大科技支撑计划项目(No.2009BADB2B0302)资助---

高指数晶面裸露的贵金属纳米晶体的合成

由于在高指数晶面上存在高密度的台阶位、扭结位原子等,高指数晶面裸露的贵金属纳米晶体一般表现出优越的物理化学性能,在催化、电化学等方面都有很重要的应用前景.近年来,研究人员围绕高指数晶面的制备进行了大量的工作并取得了一定进展.本文重点从合成制备方法的角度出发,结合本课题组的相关研究,系统总结了现有的有关制备高指数晶面裸露的贵金属纳米晶体的一些最新研究成果.从电化学方法、"帽"式试剂保护法、欠电位沉积原子层保护法、动力学调控、氧化刻蚀溶解再生长法以及模板法等几个方面对现有的高指数晶面裸露的贵金属纳米晶体的制备进行了总结

Growth of High-reflectivity AlN/GaN Distributed Bragg Reflectors in Blue Region

采用金属有机物化学气相沉积方法制备了蓝光波段高反射率Aln/gAn分布布拉格(dbr)反射镜。利用金相显微镜、扫描电子显微镜、原子力显微镜以及分光光度计等测量手段对样品的物理特性进行了分析表征。结果显示样品的表面有少量圆形台面结构和裂纹出现,但在其他区域,样品具有较为平整的表面。该样品在462.5 nM附近获得最大反射率99.4%,表面均方根粗糙度小至2.5 nM。分析表明,所得dbr达到了制备gAn基垂直腔面发射激光器的要求。One high-reflectivity AlN/GaN distributed Bragg reflector(DBR) in blue region was grown with the method of metalorganic chemical vapor deposition(MOCVD).perties of the sample were analyzed by using,scanning electron microscope(SEM),atomic force microscopy(AFM) and spectrophotometer.Except for the circular mesa structure and a few cracks observed on the surface,the sample showed a rather smooth surface.A peak reflectivity of 99.4% was observed around 462.5 nm and the surface roughness was as small as 2.5nm.The properties of the DBR meet the requirements of GaN-based vertical cavity surface emitting lasers(VCSEL).国家“863”计划资助项目(2006AA03Z409

MOCVD growth of high-reflectivity AlN/GaN distributed Bragg reflectors

利用金属有机物化学气相沉积(MOCVD)方法在蓝宝石c面衬底上制备出高反射率AlN/GaN分布布拉格反射镜(DBR)。利用分光光度计测量,在418 nm附近最大反射率达到99%。样品表面显微照片显示,有圆弧形缺陷和少量裂纹出现;在缺陷和裂纹以外的区域,DBR具有较为平坦的表面,其粗糙度在10μm×10μm面积上为3.3 nm左右。样品的截面扫描电镜(SEM)照片显示,DBR具有良好的周期性。对反射率和表面分析的结果表明,该样品达到了制备GaN基垂直腔面发射激光器(VCSEL)的要求。A high reflectivity AlN/GaN distributed Bragg reflector(DBR) is grown on c-plane sapphire substrate by metalorganic chemical vapor deposition(MOCVD).A peak reflectivity of 99% is observed around 418 nm by spectrophotometer.Compass-shape defects and a few cracks are observed on the surface.The surface root mean square(RMS) of roughness in the flat area is around 3.3 nm over a 10 μm×10 μm area.The cross-sectional scanning electron microscope(SEM) image reveals the good periodicity of DBR.Considering the peak reflectivity and surface morphology,the DBR can be used to fabricate GaN-based vertical cavity surface emitting laser(VCSEL).国家高技术研究“863”计划资助项目(2006AA03Z409

The evaluation of carbon sequestration potential in farmland ecosystem in Yanhe River catchment using natural ecosystem as a reference

以延河流域自然植被土壤有机碳为对照,对该区现有农田生态系统土壤固碳潜力进行评估。结果表明:影响自然植被土壤有机碳密度空间分布的环境因子有年均降雨季节变化、坡度和年均温度季节变化;而影响农田生态系统土壤有机碳密度分布的环境因素则包括年均蒸发量、年均最高温度与坡向;有机碳空间分布规律方面,延河流域南部土壤有机碳密度要明显高于北部,并且呈由北向南逐渐递增的趋势;情景模拟分析表明,延河流域坡度25&deg;以上、15&deg;~25&deg;以及15&deg;以下不同类型的耕地退耕后分别可以实现的固碳效益为90.41&times;104t、58.52&times;104t、57.55&times;104t,而整个延河流域的农田生态系统如果全部实行退耕还林(草),其固碳潜力在206.48&times;104t左右。可以看出,以土地利用调整为核心的区域固碳策略对环境改善具有重要意义

Spatial Distribution Evaluation of Biomass in Yanhe River Catchment Using Natural Ecosystem as a Reference.

研究植被的生物量分布及环境对生物量的承载状况,对于区域植被恢复规划、布局等具有重要意义。以黄土丘陵区延河流域为研究区,以自然植被为参照,利用广义相加模型(GAM,generalized additive model)及GIS空间分析技术预测了流域潜在生物量的分布格局;同时,利用遥感资料,预测出流域现有的植被生物量及其空间格局。以潜在生物量为参照,现实生物量为基础,通过空间分析,对流域环境的生物量承载状况进行评估。结果表明:在流域东南部地区,潜在生物量高于现实生物量;而在中北部,有较多的立地环境的现实生物量大于潜在生物量,超过了环境生物量的最大现实承载能力,导致人工植被在这些立地环境条件下的退化。识别这些植被,对于流域植被的改造和利用、流域植被恢复规划与布局等具有重要的应用价值

6H－SiC MOS结构电特性及其辐照效应的研究

对SiC MOS结构辐照引起的电参数退化及其电特性进行了研究。结果说