Chlorofullerenes featuring triple sequentially fused pentagons

通讯作者地址: Tan,YZ(通讯作者),Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China 电子邮件地址: [email protected], [email protected] triple sequentially fused pentagons (TSFP) motif is one of the basic subunits that could be used for constructing fullerenes, but it violates the isolated pentagon rule (IPR) and has not been found in carbon cages to date. The properties of TSFP-incorporating fullerenes are thus poorly explored both theoretically and experimentally. Reported herein are four chlorinated derivatives of three different fullerene cages, all with the TSFP motif. X-ray crystallographic analyses indicate that the molecular strain inherent to the pentagon adjacency of a TSFP is significantly relieved upon exohedral chlorination, leaving one of the four pentagon fusion sites unsaturated and rendering the present derivatives chiral. This unique reactivity, in stark contrast to that of previously reported non-IPR fullerenes containing double fused pentagons or triple directly fused pentagons, can be rationalized by density functional theory calculations, and are expected to stimulate further studies of these new members of the fullerene family, both theoretically and experimentally.NNSF of China 20525103,20531050,20721001,20423002 20673088 973 Program 2007CB81530

Combustion Synthesis and Electrochemical Properties of the Small Hydrofullerene C50H10

通讯作者地址: Xie, SY (通讯作者),Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China 3. Xiamen Univ, Sch Life Sci, Xiamen 361005, Peoples R China 电子邮件地址: [email protected]; [email protected] hydrofullerene C50H10 is synthesized by low-pressure benzeneoxygen diffusion combustion. The structure of C50H10 is identified through NMR, mass spectrometry, and IR and Raman spectroscopy as a D5h symmetric closed-cage molecule with five pairs of fused pentagons stabilized by ten hydrogen atoms. UV/Vis and fluorescence spectrometric analyses disclose its optical properties as comparable with those of its chloride cousin (C50Cl10). Cyclic and square-wave voltammograms reveal that the first reduction potential of C50H10 is more negative than that of C50Cl10 as well as C60, with implications for the utilization of C50H10 as a promising electron acceptor for photovoltaic applications.973 projects 2011CB935901 NSFC 21031004 21021061 2077310

Study on One Part Blocked Polyurethane-Ag Conductive Adhesive

通讯作者: [email protected][中文文摘]以封闭型聚氨酯为基体、三羟甲基丙烷(TMP)为固化剂,制备了单组份银粉导电胶,并研究其性能.该聚氨酯基体由2,4-甲苯二异氰酸酯(TDI)、TMP和少量聚乙二醇进行缩聚,并与己内酰胺反应而得.在基体中添加TMP固化剂、银粉和二氧化硅并充分搅拌后制得单组份导电胶.通过红外光谱、剪切强度和电阻率的测定对产物进行了表征,结果表明,70℃下TMP、TDI的加成反应需要时间为4~4.5 h,与己内酰胺的封闭反应时间为3~4 h;银粉的质量分数为75%时产物性能最好;加入少量二氧化硅能够提高导电胶的剪切强度,但电阻率会随之升高.[英文文摘]The preparation and properties of one-component Ag powder conductive adhesive which consisted of TMP-TDI adduct as matrix and TMP as hardener were studied.TMP-TDI adduct was synthesized by TMP,TDI and PEG.Then the prepolymer was blocked by caprolactam to get blocked polyurethane.Hardener,Ag powder and fumed silica were added to the polyurethane to prepare one-component conductive adhesive through agitating well.The products were characterized by FTIR,moreover,their shear strength and electrical resistivity were measured respectively. The results demonstrated that the addition reaction of TMP and TDI needed 4~4.5 h, while the blocked reaction needed 3~ 4 h. The optimum mass fraction of Ag powder was 75%. Employing fumed silica to the conductive adhesive reinforced the shear strength and elect rical resistivity

VISUAL-MOTOR CONTROL IN MENTALLY RETARDED CHILDREN

该研究探讨了弱智儿童视觉-动作控制能力。弱智儿童被试30人,平均年龄13.5岁,平均智商53.9。实验结果与正常人的结果作了比较。结果显示,弱智儿童的视觉-动作控制能力只相当五六岁正常儿童的水平,远落后于正常中青年及老年的水平。这表明,智力缺陷与发展水平对人的视觉-动作控制能力有明显影响

STUDY OF MENTAL ROTATION IN MENTALLY RETARDED CHILDREN

该研究探讨了一组9-12岁弱智儿童的“心理旋转”能力,该组儿童平均年龄10.1岁,平均智商(IQ)53.8(中度智力残疾)。研究结果与正常儿童(均龄8岁)作了比较。结果显示,弱智儿童的心理旋转能力明显较之正常儿童为差,智力缺陷对视觉图形空间定向能力(心理旋转)有着明显的影响。但无论弱智儿童或是正常儿童的结果均未发现性别差异

STUDY OF MENTAL ROTATION IN MENTALLY RETARDED CHILDREN

该研究探讨了一组9-12岁弱智儿童的“心理旋转”能力,该组儿童平均年龄10.1岁,平均智商(IQ)53.8(中度智力残疾)。研究结果与正常儿童(均龄8岁)作了比较。结果显示,弱智儿童的心理旋转能力明显较之正常儿童为差,智力缺陷对视觉图形空间定向能力(心理旋转)有着明显的影响。但无论弱智儿童或是正常儿童的结果均未发现性别差异

VISUAL-MOTOR CONTROL IN MENTALLY RETARDED CHILDREN

该研究探讨了弱智儿童视觉-动作控制能力。弱智儿童被试30人,平均年龄13.5岁,平均智商53.9。实验结果与正常人的结果作了比较。结果显示,弱智儿童的视觉-动作控制能力只相当五六岁正常儿童的水平,远落后于正常中青年及老年的水平。这表明,智力缺陷与发展水平对人的视觉-动作控制能力有明显影响