Paleostress and kinematic evolution of the orogen-parallel NW-SE striking faults in the NW External Dinarides of Slovenia unraveled by mesoscale fault-slip data anaysis

The late Eocene to Recent dynamics of the NW External Dinarides in Slovenia are described. The study is focused on the orogen-parallel NW-SE striking family of faults, which represent the main source of seismic hazard in the NW External Dinarides today. Approximately 1700 fault-slip datasets were collected at 70 locations and used for palaeostress analysis. Structural relationships observed in the field, allowed the construction of a relative chronology between the documented fault and shear joint sets, facilitating the reconstruction of their kinematic evolution and the chronology of palaeostress phases. Four post-Palaeocene stress tensor groups are documented corresponding to four distinct tectonic phases. The first phase is marked by NE-SW directed compression attributed to Late Eocene top-to-SW thrusting of External Dinarides. The second phase is characterized by NE-SW oriented tension, documented by normal slips recorded on NW-SE striking faults. This tension is interpreted as an expression of the Early to Middle Miocene back-arc extension in the Pannonian basin system that also affected the studied part of the External Dinarides. The third phase is manifested by approximately E-W oriented compression with approximately N-S oriented tension in a strike-slip stress regime, causing sinistral reactivation of NW-SE trending faults. Geodynamically, this phase can be correlated with the Late Miocene short pulse of E-W directed compression, documented in parts of the Pannonian basin system. The youngest phase is characterized by approximately N-S oriented compression and approximately E-W oriented tension in a strike-slip stress regime, which caused dextral reactivation of NW-SE striking faults. This phase correlates with the recent inversive/transpressive phase, well-established from seismological data.</p

Kinematic and paleostress evolution of the NW-SE trending "dinaric" faults in the northwestern external Dinarides

The main regional structures in the Dinarides where accumulated lithospheric stress has been relaxed are NW-SE trending Dinaric faults. The research involves kinematic and dynamic analysis of fault-slip data on the territory of the NW External Dinarides, including Middle Triassic to Middle Miocene strata.\ud Four major Tertiary-Quaternary tectonic phases have been documented. Paleostress analysis of fault-slip data shows general stress orientations, which have been correlated by relevant mesoscopic scale deformations. Relative chronology of tectonic phases is based on field observations of structural relationships. Tectonic phases have been placed in wider geodynamic context.\ud The oldest phase is characterized by NE-SW directed compression in compressional stress regime, which has been attributted to Paleogene thrusting of the External Dinarides. The second phase is characterized by NE-SW oriented tension in extensional stress regime, which can be attributed to an influence of Middle Miocene extension in the Pannonian basin. The third phase is marked by E-W compression with N-S oriented tension in strike-slip stress regime, which could reflect cessation of subduction processes in Carpathians. The fourth phase shows N-S oriented compression with E-W oriented tension in strike-slip stress regime, which coincides with recent stress state of the region. The Triassic and Jurassic stress regimes have been evaluated according to the orientation of observed extensional structures.\ud The structural model of NW External Dinarides teritory has been suggested according to the obtained results, which could be an usefull basis for the assessment of earthquake hazard, geomechanic rock stability and hydrogeological aquifer characteristics of the area

Use of steel slag for the synthesis of belite-sulfoaluminate clinker

Belite-sulfoaluminate (BCSA) cements are low-carbon mineral binders, which require low energy consumption and allow the incorporation of various secondary raw materials in the clinker raw meal. In this study two types of unprocessed steel slags, coming from stainless steel production, were incorporated in the BCSA clinkers. The clinker phase composition, clinker reactivity, and the compressive strength of the cement were studied to evaluate the possible use of the slag in BCSA clinkers. The cement clinkers were synthesized by using natural raw materials, white titanogypsum, mill scale, as well as two different steel slags: (i) EAF S slag, which is a by-product of melting the recycled steel scrap in an electric arc furnace, and (ii) la dle slag as a by-product of the processes of secondary metallurgy, in various quantities. Raw mixtures with two different targeted phase compositions varying in belite, calcium sulfoaluminate and ferrite phases were sintered at 1250 °C. Clinker phases were determined by Rietveld quantitative phase analysis, while their distribution, morphology and incorporation of foreign ions in the phases were studied by SEM/EDS analysis. The clinker reactivity was determined by isothermal calorimetry. BCSA cements were prepared by adding titanogypsum. The compressive strength of the cement pastes was determined after 7 days of hydration. The presence of a predicted major clinker phases was confirmed by Rietveld analysis, however periclase was also detected. Microscopy revealed subhedral grains of belite and euhedral grains of calcium sulfoaluminate phases, while ferrite occurred as an interstitial phase. The results showed differences in the microstructure and reactivity of the clinker and cement, which can be attributed to varying amounts of ettringite due to different slag type

Manual for use of Al-containing residues in low-carbon mineral binders

Our society can no longer be imagined without its modern infrastructure, which is inevitably based on the use of various mineral and metallic materials and requires a high energy consumption. Parallel to the production of materials, as well as the production of electricity, huge amounts of various industrial and mining residues (waste/by-product) are generated and many of them are sent to landfill. The European Union (EU) aims to increase resource efficiency and the supply of ”secondary raw materials“ through recycling [1], inventory of waste from extractive industries [2], and waste prevention, waste re-use and material recycling [3]. Much of the industrial and mining waste is enriched with aluminium (Al) and therefore has a potential to replace natural sources of Al in mineral binders with a high Al demand. However, the use of industrial residue in mineral binders requires an extensive knowledge of its chemical composition, including potential hazardous components (e.g. mercury), mineral composition, organic content, radioactivity and physical properties (moisture content, density, etc.). This manual addresses the legislative aspects, governing the use of secondary raw materials in construction products, description of the most common Al-containing industrial and mining residue (bauxite deposits, red mud, ferrous slag, ash and some other by products from industry), potentiality for their reutilisation and its economic aspects, potential requirements/barriers for the use of secondary raw materials in the cement industry and a description of belite-sulfoaluminate cements, which are a promising solution for implementing the circular economy through the use of large amounts of landfilled Al-rich industrial residue and mining waste cement clinker raw mixture. This manual was prepared by partners of the RIS-ALiCE project. It provides a popular content, which targets relevant stakeholders as well as the wider society. Moreover, it offers education material for undergraduate, master and PhD students.Other links: [http://www.zag.si/dl/manual-alice.pdf

Neogene block rotation inside the dextral fault zone at the Adriatic-European collision zone: reexamination of existing results

The study focused on the post-Middle-Miocene stress analysis within the dextral strike-slip zone of the Dinaric fault system in the collision zone between the European plate, the Adria microplate and the Pannonian Domain. Block rotations were studied by re-examination of available paleostress data and their spatial distribution. The results are in agreement with the existing block model of the area, indicating CCW rotations within blocks between the main strike-slip faults in which rotation angle increases from W to E. The improved kinematic model, which is proposed in this study, will contribute to the knowledge on the kinematics within the complex collision zones and improve the seismic hazard models

Use of geomorphological indicators for the detection of active faults in southern part of Ljubljana moor, Slovenia

In order to detect recently tectonically active faults, Stream Length-gradient (SL) index and a newly developed method of river gradient analysis were made for three rivers. Two methods were used on the southern part of Ljubljana moor, where rivers cross dextral (right-lateral) faults with Dinaric orientation (NW-SE). Watercourse profiles were analysed first, using a »classic«, well established method of SL index. However, this method didn't yield useful results since almost no variability in SL indexes were observed. Additionally, a second newly developed method pointed on the anomalies, which might correspond to the areas of active surface uplift and subsidence as a consequence of active tectonic movements. We compared determined anomalies with the fault lines plotted on the Basic geological map 1 : 100.000 and with the data of radar measurements of vertical movements by PSInSAR method. In this way five potentially active faults, areas of contraction and areas of extension were determined. The results of this research can be used as complementary information for the construction of tectonic model of Ljubljana field and Ljubljana moor

Building of the Al-Containing secondary raw materials registry for the production of low CO2 mineral binders in South-Eastern European region

The bottleneck in the process for increasing production of low CO2 mineral binders, based on BCSA (belite sulfoaluminate) clinkers, is the availability of Al-rich raw materials. For that purpose, a new registry of Al-containing secondary mineral residues (industrial and mine waste) has been developed and is presented in this paper. The methodology of creating the registry consists of three main steps: Gathering ideas, consolidation of ideas, and implementation. In order to achieve this, the following methodology was adopted: Analysis of similar registries by potential end-users and seeking potential solutions and tools to be used, and conducting 3 rounds of stakeholder consultations via workshops in order to determine crucial parameters and features the registry needs to contain. The key discussion points were about which data the registry needs to contain, who shall be the potential users, and what are the stakeholderʼs expectations from the registryʼs portal. Potential individual registry variables were identified as being relevant/irrelevant or available/unavailable, and potential solutions for the registrys sustainability were explored. Each Al-rich waste/residue data entry is divided into 10 slots, describing legal status, location, quantities, chemical (REE included), mineralogical, physical and radiological properties, life-cycle assessment, additional data, and data relevancy. The registry will act as a matchmaking tool between producers/holders of Al-rich secondary raw materials and potential producers of cement clinkers

A contribution to better understanding of structural characteristics and tectonic phases of the Boč region, Periadriatic Fault Zone

The aim of this study was to determine properties of the tectonic contact between Permian/Mesozoic limestones and less competent Miocene clastites on the northeastern foothill of the Boč Mt. Because fault planes signifiantly mark the relief, this contact was studied by a detailed structural mapping, which showed that the Boč Mt. is limited by subvertical faults in its northeastern part. To ensure that mapped subvertical contact is compatible with regional geodynamics of the area, additionally paleostress analysis of fault-slip data was performed. Four individual paleostress tensor groups were documented in a wider Boč area and compared by published structural data from the border zone between Alps, Dinarides and Pannonian Basin. The oldest paleostress tensor group (Phase 1) is likely of Lower and Middle Miocene age and indicates SW-NE extension accommodated by W-E to WNW-ESE striking normal faults. Phase 2 can be correlated with Middle to Late Miocene NW-SE to WNWESE directed extension accommodated by NNE-SSW striking normal faults. Phase 3 is correlated with Late Miocene W-E directed contraction accommodated by N-S striking sinistral faults and NNE-SSW to NE-SW striking dextral faults. The youngest paleostress tensor group (Phase 4) fis well with Pliocene to Quaternary NNW-SSE to N-S directed contraction accommodated by NW-SE to W-E striking dextral faults and NE-SW striking reverse faults. Since the documented paleostress phases fis well with the geodynamic processes of the Alps-Dinarides-Carpathians territory the subvertical border in the northeastern part of Boč Mt. seems to be an acceptable structural solution. The study is important because the study area is located at interaction zone between two major Alpine fault systems: the Periadriatic and the Lavanttal faults

Microstructural characteristics of belite–sulfoaluminate cement clinkers with bottom ash

The incorporation mechanism of impurities derived from raw materials into a belite-sulfoaluminate cement clinker with bottom ash was investigated in two raw mixtures. Alkalis lowered the sintering temperature by 50 °C. Ti stabilized β belite and prevented the formation of γ-belite. Sodalite solid solution showed an incomplete substitution of Si by Al. At a higher Ti content ferrite solid solution trended towards perovskite composition. Although calcium sulfoaluminate only fully developted at 1300 °C, the clinkers sintered at 1200 °C were the most reactive, as the presence of anhydrite at 1200 °C accelerated early hydration. Clinker reactivity decreased with an increase in sintering temperature

Metal content in street dust as a reflection of atmospheric dust emissions from coal power plants, metal smelters, and traffic

Resuspended street dust is a source of inhalable particles in urban environments. Despite contaminated street dust being a possible health risk factor for local population, little is known about the contribution of atmospheric dust emissions and other factors to the content of toxic metals in street dust. The impact of smelting, traffic, and power plants on metal contaminates in street dust is the focus of street dust sampling at 46 locations in the Witbank area (Republic of South Africa). This area is characterized by numerous openpit coal mines in the Karoo coal basin, which provides a cheap source of energy to numerous metallurgical smelters and ironworks and supplies coal to the coal-fired power plants located nearby. Street dustwas collected on asphalt or concrete surfaces with hard plastic brushes, avoiding collecting of possible sand, soil, or plant particles. Chemical analysis was done on the <0.125 mm fraction using inductively coupled plasma mass spectrometry subsequent to total digestion. Exceptionally high concentrations of metals were detected with concentrations of Fe reaching 17.7 %, Cr 4.3 %, Mn 2 %, Ni 366 mg/kg, and V 4,410 mg/kg. Factor analysis indicates three sources for the pollution. Road traffic which contributes to the high concentrations of Cu, Pb, Sb, and Sn, with the highest impacts detected in the town of Witbank. The second source is associated with the metal smelting industry, contributing to Fe, Co, Mn, and Vemissions. The highest factor scores were observed around four metallurgical smelter operations, located in the Ferrobank, Highveld, and Clewer industrial areas. Impact of vanadium smelter to street dust composition could still be detected some 20 km away from the sources. Exceptionally high concentrations of Cr were observed in four samples collected next to the Ferrobank industrial area, despite Cr not being loaded in factor 2. The last source of the pollution is most probably fly ash associated with the coal-fired power plants and fly ash dumps. Elements which are associated with this source are Al, Sr, and Li. This factor is abundant in the coal mining part of the study area.http://link.springer.com/journal/1135