32 research outputs found
Detection mechanism for ferroelectric domain boundaries with lateral force microscopy
The contrast mechanism for the visualization of ferroelectric domain
boundaries with lateral force microscopy is generally assumed to be caused by
mechanical deformation of the sample due to the converse piezoelectric effect.
We show, however, that electrostatic interactions between the charged tip and
the electric fields arising from the surface polarization charges dominate the
contrast mechanism. This explanation is sustained by quantitative analysis of
the measured forces as well as by comparative measurements on different
materials
Electrostatic topology of ferroelectric domains in YMnO
Trimerization-polarization domains in ferroelectric hexagonal YMnO were
resolved in all three spatial dimensions by piezoresponse force microscopy.
Their topology is dominated by electrostatic effects with a range of 100 unit
cells and reflects the unusual electrostatic origin of the spontaneous
polarization. The response of the domains to locally applied electric fields
explains difficulties in transferring YMnO into a single-domain state. Our
results demonstrate that the wealth of non-displacive mechanisms driving
ferroelectricity that emerged from the research on multiferroics are a rich
source of alternative types of domains and domain-switching phenomena
Lateral Signals in Piezoresponse Force Microscopy at Domain Boundaries of Ferroelectric Crystals
In piezoresponse force microscopy a lateral signal at the domain boundaries
is occasionally observed. In recent years, a couple of experiments have been
reported and varying explanations for the origin of this lateral signal have
been proposed. Additionally, elaborated theoretical modeling for this
particular issue has been carried out. Here we present experimental data
obtained on different crystallographic cuts of , ,
and single crystals. We could thereby rule out some of the
explanations proposed so far, introduce another possible mechanism, and
quantitatively compare our results to the existing modeling
Impact of elasticity on the piezoresponse of adjacent ferroelectric domains investigated by scanning force microscopy
As a consequence of elasticity, mechanical deformations of crystals occur on
a length scale comparable to their thickness. This is exemplified by applying a
homogeneous electric field to a multi-domain ferroelectric crystal: as one
domain is expanding the adjacent ones are contracting, leading to clamping at
the domain boundaries. The piezomechanically driven surface corrugation of
micron-sized domain patterns in thick crystals using large-area top electrodes
is thus drastically suppressed, barely accessible by means of piezoresponse
force microscopy
Depth resolution of Piezoresponse force microscopy
Given that a ferroelectric domain is generally a three dimensional entity, the determination of its area as well as its depth is mandatory for full characterization. Piezoresponse force microscopy (PFM) is known for its ability to map the lateral dimensions of ferroelectric domains with high accuracy. However, no depth profile information has been readily available so far. Here, we have used ferroelectric domains of known depth profile to determine the dependence of the PFM response on the depth of the domain, and thus effectively the depth resolution of PFM detection
Contrast Mechanisms for the Detection of Ferroelectric Domains with Scanning Force Microscopy
We present a full analysis of the contrast mechanisms for the detection of
ferroelectric domains on all faces of bulk single crystals using scanning force
microscopy exemplified on hexagonally poled lithium niobate. The domain
contrast can be attributed to three different mechanisms: i) the thickness
change of the sample due to an out-of-plane piezoelectric response (standard
piezoresponse force microscopy), ii) the lateral displacement of the sample
surface due to an in-plane piezoresponse, and iii) the electrostatic tip-sample
interaction at the domain boundaries caused by surface charges on the
crystallographic y- and z-faces. A careful analysis of the movement of the
cantilever with respect to its orientation relative to the crystallographic
axes of the sample allows a clear attribution of the observed domain contrast
to the driving forces respectively.Comment: 8 pages, 8 figure