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Electrostatic topology of ferroelectric domains in YMnO3_3

Abstract

Trimerization-polarization domains in ferroelectric hexagonal YMnO3_3 were resolved in all three spatial dimensions by piezoresponse force microscopy. Their topology is dominated by electrostatic effects with a range of 100 unit cells and reflects the unusual electrostatic origin of the spontaneous polarization. The response of the domains to locally applied electric fields explains difficulties in transferring YMnO3_3 into a single-domain state. Our results demonstrate that the wealth of non-displacive mechanisms driving ferroelectricity that emerged from the research on multiferroics are a rich source of alternative types of domains and domain-switching phenomena

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