Comparison of Pedestrian Fundamental Diagram Across Cultures

The relation between speed and density is connected with every self-organization phenomenon of pedestrian dynamics and offers the opportunity to analyze them quantitatively. But even for the simplest systems, like pedestrian streams in corridors, this fundamental relation isn't completely understood. Specifications of this characteristic in guidelines and text books differ considerably reflecting the contradictory database and the controversial discussion documented in the literature. In this contribution it is studied whether cultural influences and length of the corridor can be the causes for these deviations. To reduce as much as possible unintentioned effects, a system is chosen with reduced degrees of freedom and thus the most simple system, namely the movement of pedestrians along a line under closed boundary conditions. It is found that the speed of Indian test persons is less dependent on density than the speed of German test persons. Surprisingly the more unordered behaviour of the Indians is more effective than the ordered behaviour of the Germans. Without any statistical measure one cannot conclude about whether there are differences or not. By hypothesis test it is found quantitatively that these differences exist, suggesting cultural differences in the fundamental diagram of pedestrians.Comment: 12 pages, 7 figure

Electrophilicity Equalization Principle

A new electronic structure principle, viz., the principle of electrophilicity equalization is proposed. An analytical justification as well as a numerical support for the same is provided.Comment: 9 pages, 2 table

Nucleophilicity/Electrophilicity Excess in Analyzing Molecular Electronics

Intramolecular electron transfer capability of all metal aromatic and anti-aromatic aluminum cluster compounds is studied in terms of density functional theory based global and local reactivity descriptors. This study will provide important inputs towards the fabrication of the material required for molecular electronics.Comment: 21 pages, 6 figures, 13 table