Moisture conditions in coated wood panels during 18 months natural weathering at five sites in Europe

Wood moisture content of coated panels of Scots pine sapwood was recorded during 18 months natural weathering in Vienna by logging electric resistance and temperature near the surface. Eight coating systems with various film thicknesses were used, including three solvent borne alkyd stains, three water borne acrylic stains and two water borne acrylic paints. At five sites in Europe wood moisture content of panels coated with three solvent borne alkyd stains, a brow acrylic stain and a white opaque acrylic paint was recorded weekly by changes in panel mass. Fluctuations in wood moisture content were influenced by the film thickness, moisture protection and colour of the coating systems used. Degradation phenomena led to decreasing moisture protection of less durable coating systems over time of exposure. Differences between the exposure sites were relatively low, except the site in the UK where moisture conditions were higher

UV Degradation of the Optical Properties of Acrylic for Neutrino and Dark Matter Experiments

UV-transmitting (UVT) acrylic is a commonly used light-propagating material in neutrino and dark matter detectors as it has low intrinsic radioactivity and exhibits low absorption in the detectors' light producing regions, from 350 nm to 500 nm. Degradation of optical transmittance in this region lowers light yields in the detector, which can affect energy reconstruction, resolution, and experimental sensitivities. We examine transmittance loss as a result of short- and long-term UV exposure for a variety of UVT acrylic samples from a number of acrylic manufacturers. Significant degradation peaking at 343 nm was observed in some UVT acrylics with as little as three hours of direct sunlight, while others exhibited softer degradation peaking at 310 nm over many days of exposure to sunlight. Based on their measured degradation results, safe time limits for indoor and outdoor UV exposure of UVT acrylic are formulated.Comment: 13 pages, 6 figures, 3 tables; To be submitted to Journal of Instrumentatio

Long-Term Testing and Properties of Acrylic for the Daya Bay Antineutrino Detectors

The Daya Bay reactor antineutrino experiment has recently measured the neutrino mixing parameter sin22{\theta}13 by observing electron antineutrino disappearance over kilometer-scale baselines using six antineutrino detectors at near and far distances from reactor cores at the Daya Bay nuclear power complex. Liquid scintillator contained in transparent target vessels is used to detect electron antineutrinos via the inverse beta-decay reaction. The Daya Bay experiment will operate for about five years yielding a precision measurement of sin22{\theta}13. We report on long-term studies of poly(methyl methacrylate) known as acrylic, which is the primary material used in the fabrication of the target vessels for the experiment's antineutrino detectors. In these studies, acrylic samples are subjected to gaseous and liquid environmental conditions similar to those experienced during construction, transport, and operation of the Daya Bay acrylic target vessels and detectors. Mechanical and optical stability of the acrylic as well as its interaction with detector liquids is reported.Comment: 17 pages, 13 figures Submitted to JINS

Acrylic purification and coatings

Radon (Rn) and its decay daughters are a well-known source of background in direct WIMP detection experiments, as either a Rn decay daughter or an alpha particle emitted from a thin inner surface layer of a detector could produce a WIMP-like signal. Different surface treatment and cleaning techniques have been employed in the past to remove this type of contamination. A new method of dealing with the problem has been proposed and used for a prototype acrylic DEAP-1 detector. Inner surfaces of the detector were coated with a layer of ultra pure acrylic, meant to shield the active volume from alphas and recoiling nuclei. An acrylic purification technique and two coating techniques are described: a solvent-borne (tested on DEAP-1) and solvent-less (being developed for the full scale DEAP-3600 detector).Comment: Proceedings of Topical Workshop on Low Radioactivity Techniques (LRT 2010), SNOLAB, Sudbury, Canada, Aug 28-29, 201

Phase Behavior of Polyelectrolyte Block Copolymers in Mixed Solvents

We have studied the phase behavior of the poly(n-butyl acrylate)-b-poly(acrylic acid) block copolymer in a mixture of two miscible solvents, water and tetrahydrofuran (THF). The techniques used to examine the different polymers, structures and phases formed in mixed solvents were static and dynamic light scattering, small-angle neutron scattering, nuclear magnetic resonance and fluorescence microscopy. By lowering the water/THF mixing ratio X, the sequence unimers, micron-sized droplets, polymeric micelles was observed. The transition between unimers and the micron-sized droplets occurred at X = 0.75, whereas the microstructuration into core-shell polymeric micelles was effective below X = 0.4. At intermediate mixing ratios, a coexistence between the micron-sized droplets and the polymeric micelles was observed. Combining the different aforementioned techniques, it was concluded that the droplet dispersion resulted from a solvent partitioning that was induced by the hydrophobic blocks. Comparison of poly(n-butyl acrylate) homopolymers and poly(n-butyl acrylate)-b-poly(acrylic acid) block copolymers suggested that the droplets were rich in THF and concentrated in copolymers and that they were stabilized by the hydrophilic poly(acrylic acid) moieties.Comment: 11 pages, 12 figures, to appear in Macromolecule

Bubble Rise Phenomena Through Newtonian & Non-Newtonian Fluids

The characteristics of bubble rise phenomenon in three liquids were investigated and are reported here. The experimental rig consists of two transparent cylindrical columns – one a polycarbonate tube of 125 mm diameter and the other an acrylic tube of 400 mm diameter. The rig also consists of a lifting device designed to hold a video camera for taking bubble images. Water and two non-Newtonian fluids (0.025% and 0.045% by weight of polyacrylamide solutions) were used in this study. The smaller polycarbonate tube was used to study the velocity and the drag coefficient under vacuum. The bigger acrylic tube was used to study the influence of the size of bubbles

Development of battery separator material process Interim report

Dose rate of irradiation grafting for polyethylene film with acrylic aci

Silver-Zinc Battery Separator Material Development

Ethylene/acrylic acid separators for silver zinc battery application

Development of battery separator material process Quarterly report, 2 Jul. - 30 Sep. 1969

Battery separator materials from acrylic acid grafting solution with polyethylene film effect