A Pedagogical Intrinsic Approach to Relative Entropies as Potential Functions of Quantum Metrics: the qq-zz Family

The so-called $q$-z-\textit{R\'enyi Relative Entropies} provide a huge two-parameter family of relative entropies which includes almost all well-known examples of quantum relative entropies for suitable values of the parameters. In this paper we consider a log-regularized version of this family and use it as a family of potential functions to generate covariant $(0,2)$ symmetric tensors on the space of invertible quantum states in finite dimensions. The geometric formalism developed here allows us to obtain the explicit expressions of such tensor fields in terms of a basis of globally defined differential forms on a suitable unfolding space without the need to introduce a specific set of coordinates. To make the reader acquainted with the intrinsic formalism introduced, we first perform the computation for the qubit case, and then, we extend the computation of the metric-like tensors to a generic $n$-level system. By suitably varying the parameters $q$ and $z$, we are able to recover well-known examples of quantum metric tensors that, in our treatment, appear written in terms of globally defined geometrical objects that do not depend on the coordinates system used. In particular, we obtain a coordinate-free expression for the von Neumann-Umegaki metric, for the Bures metric and for the Wigner-Yanase metric in the arbitrary $n$-level case.Comment: 50 pages, 1 figur

Bayesian estimates of free energies from nonequilibrium work data in the presence of instrument noise

The Jarzynski equality and the fluctuation theorem relate equilibrium free energy differences to non-equilibrium measurements of the work. These relations extend to single-molecule experiments that have probed the finite-time thermodynamics of proteins and nucleic acids. The effects of experimental error and instrument noise have not previously been considered. Here, we present a Bayesian formalism for estimating free-energy changes from non-equilibrium work measurements that compensates for instrument noise and combines data from multiple driving protocols. We reanalyze a recent set of experiments in which a single RNA hairpin is unfolded and refolded using optical tweezers at three different rates. Interestingly, the fastest and farthest-from-equilibrium measurements contain the least instrumental noise, and therefore provide a more accurate estimate of the free energies than a few slow, more noisy, near-equilibrium measurements. The methods we propose here will extend the scope of single-molecule experiments; they can be used in the analysis of data from measurements with AFM, optical, and magnetic tweezers.Comment: 8 page

Homogenization of degenerate cross-diffusion systems

Two-scale homogenization limits of parabolic cross-diffusion systems in a heterogeneous medium with no-flux boundary conditions are proved. The heterogeneity of the medium is reflected in the diffusion coefficients or by the perforated domain. The diffusion matrix is of degenerate type and may be neither symmetric nor positive semi-definite, but the diffusion system is assumed to satisfy an entropy structure. Uniform estimates are derived from the entropy production inequality. New estimates on the equicontinuity with respect to the time variable ensure the strong convergence of a sequence of solutions to the microscopic problems defined in perforated domains

Self-attracting self-avoiding walk

This article is concerned with self-avoiding walks (SAW) on $\mathbb{Z}^{d}$ that are subject to a self-attraction. The attraction, which rewards instances of adjacent parallel edges, introduces difficulties that are not present in ordinary SAW. Ueltschi has shown how to overcome these difficulties for sufficiently regular infinite-range step distributions and weak self-attractions. This article considers the case of bounded step distributions. For weak self-attractions we show that the connective constant exists, and, in $d\geq 5$, carry out a lace expansion analysis to prove the mean-field behaviour of the critical two-point function, hereby addressing a problem posed by den Hollander

The Nonequilibrium Thermodynamics of Small Systems

The interactions of tiny objects with their environment are dominated by thermal fluctuations. Guided by theory and assisted by micromanipulation tools, scientists have begun to study such interactions in detail.Comment: PDF file, 13 pages. Long version of the paper published in Physics Toda