A service-oriented approach to embedded component-based manufacturing automation

This thesis is focused on the application of Component-Based (CB) technology to shop oor devices using a Service Oriented Architecture (SOA) and Web Services (WS) for the purpose of realising future generation agile manufacturing systems. The environment of manufacturing enterprises is now characterised by frequently changing market demands, time-to-market pressure, continuously emerging new technologies and global competition. Under these circumstances, manufacturing systems need to be agile and automation systems need to support this agility. More speci cally, an open, exible automation environment with plug and play connectivity is needed. Technically, this requires the easy connectivity of hardware devices and software components from di erent vendors. Functionally, there is a need of interoperability and integration of control functions on di erent hierarchical levels ranging from eld level to various higher level applications such as process control and operations management services. [Continues.

ReSCon '12, Research Student Conference: Book of Abstracts

The fifth SED Research Student Conference (ReSCon2012) was hosted over three days, 18-20 June 2012, in the Hamilton Centre at Brunel University. The conference consisted of 130 oral and 70 poster presentations, based on the high quality and diverse research being conducted within the School of Engineering and Design by postgraduate research students. The conference is held annually, and ReSCon plays a key role in contributing to research and innovations within the School

Biosensors

A biosensor is defined as a detecting device that combines a transducer with a biologically sensitive and selective component. When a specific target molecule interacts with the biological component, a signal is produced, at transducer level, proportional to the concentration of the substance. Therefore biosensors can measure compounds present in the environment, chemical processes, food and human body at low cost if compared with traditional analytical techniques. This book covers a wide range of aspects and issues related to biosensor technology, bringing together researchers from 11 different countries. The book consists of 16 chapters written by 53 authors. The first four chapters describe several aspects of nanotechnology applied to biosensors. The subsequent section, including three chapters, is devoted to biosensor applications in the fields of drug discovery, diagnostics and bacteria detection. The principles behind optical biosensors and some of their application are discussed in chapters from 8 to 11. The last five chapters treat of microelectronics, interfacing circuits, signal transmission, biotelemetry and algorithms applied to biosensing

Internet of Things Applications - From Research and Innovation to Market Deployment

The book aims to provide a broad overview of various topics of Internet of Things from the research, innovation and development priorities to enabling technologies, nanoelectronics, cyber physical systems, architecture, interoperability and industrial applications. It is intended to be a standalone book in a series that covers the Internet of Things activities of the IERC – Internet of Things European Research Cluster from technology to international cooperation and the global "state of play".The book builds on the ideas put forward by the European research Cluster on the Internet of Things Strategic Research Agenda and presents global views and state of the art results on the challenges facing the research, development and deployment of IoT at the global level. Internet of Things is creating a revolutionary new paradigm, with opportunities in every industry from Health Care, Pharmaceuticals, Food and Beverage, Agriculture, Computer, Electronics Telecommunications, Automotive, Aeronautics, Transportation Energy and Retail to apply the massive potential of the IoT to achieving real-world solutions. The beneficiaries will include as well semiconductor companies, device and product companies, infrastructure software companies, application software companies, consulting companies, telecommunication and cloud service providers. IoT will create new revenues annually for these stakeholders, and potentially create substantial market share shakeups due to increased technology competition. The IoT will fuel technology innovation by creating the means for machines to communicate many different types of information with one another while contributing in the increased value of information created by the number of interconnections among things and the transformation of the processed information into knowledge shared into the Internet of Everything. The success of IoT depends strongly on enabling technology development, market acceptance and standardization, which provides interoperability, compatibility, reliability, and effective operations on a global scale. The connected devices are part of ecosystems connecting people, processes, data, and things which are communicating in the cloud using the increased storage and computing power and pushing for standardization of communication and metadata. In this context security, privacy, safety, trust have to be address by the product manufacturers through the life cycle of their products from design to the support processes. The IoT developments address the whole IoT spectrum - from devices at the edge to cloud and datacentres on the backend and everything in between, through ecosystems are created by industry, research and application stakeholders that enable real-world use cases to accelerate the Internet of Things and establish open interoperability standards and common architectures for IoT solutions. Enabling technologies such as nanoelectronics, sensors/actuators, cyber-physical systems, intelligent device management, smart gateways, telematics, smart network infrastructure, cloud computing and software technologies will create new products, new services, new interfaces by creating smart environments and smart spaces with applications ranging from Smart Cities, smart transport, buildings, energy, grid, to smart health and life. Technical topics discussed in the book include: • Introduction• Internet of Things Strategic Research and Innovation Agenda• Internet of Things in the industrial context: Time for deployment.• Integration of heterogeneous smart objects, applications and services• Evolution from device to semantic and business interoperability• Software define and virtualization of network resources• Innovation through interoperability and standardisation when everything is connected anytime at anyplace• Dynamic context-aware scalable and trust-based IoT Security, Privacy framework• Federated Cloud service management and the Internet of Things• Internet of Things Application

Novel polymeric and oligomeric materials for organic electronic devices

Die enormen Fortschritte im Bereich der organischen Elektronik in den letzten Jahrzehnten haben zur Entwicklung effizienter optoelektronischer Bauelemente geführt wie z. B. organische Leuchtdioden (OLEDs), organische Feldeffekttransistoren (OFETs) und organische Photovoltaikzellen (OPV). Darüber hinaus ermöglichen halbleitende Polymere die Herstellung kostengünstiger, großflächiger elektronischer Bauelemente mit Hilfe von Niedertemperatur Lösungsverfahren auf flexiblen Substraten. Der erste Teil dieser Arbeit befasste sich mit der Entwicklung von Host-Materialien für die emittierende Schicht (EML) von OLEDs. Effiziente Host-Materialien sollten bestimmte Eigenschaften aufweisen, z. B. eine hohe Triplett-Energie, einen hohen und ausgeglichenen Ladungsträgertransport, geeignete Grenzorbitalniveaus, die mit denen der Nachbarschichten übereinstimmen, und morphologische Stabilität. Zu diesem Zweck wurden Polymere auf Carbazolbasis mit einer elektronenziehenden Gruppe (EWG) an verschiedenen Stellen der Kette entworfen und durch Suzuki Kupplung synthetisiert. Die Polymere wurden chemisch und optisch charakterisiert, bevor sie nach Dotierung mit Tris(2-phenylpyridin)iridium(III) (Ir(ppy)3) in eine funktionierende grüne OLED eingebaut wurden. Zusätzlich wurden die Ladungstransporteigenschaften durch die Herstellung von Einzelträgergeräte untersucht. Der zweite Teil widmete sich der Herstellung von Halbleitermaterialien für OFET Anwendungen. Nach einem neuartigen Moleküldesign wurde eine Reihe von Verbindungen auf der Basis von Diketopyrrolopyrrol (DPP) und Thiophen durch Stille-Kupplung und phosphinfreie direkte Heteroarylierung synthetisiert. Dieses molekulare Design erwies sich als flexibel für die Synthese neuartiger Derivate durch Modifikation der Endgruppen. Die Korrelation zwischen Struktur und Morphologie wurde ebenfalls untersucht. Die Mobilität der Ladungsträger, welche von der chemischen Struktur und Morphologie des Halbleiters beeinflusst wird, ist einer der wichtigsten Parameter eines OFET. Daher wurden die erhaltenen Materialien mit niedriger Bandlücke in Transistoren verschiedener Architekturen integriert, die durch Lösungsverfahren wie Spin-Coating und Scherbeschichtung hergestellt wurden. Die Mobilität sowie andere OFET-Parameter wurden im p- und n-Typ-Betrieb gemessen.:1 Theoretical background 1.1 Introduction 1.2 Organic semiconductors 1.3 Organic Light Emitting Diodes 1.3.1 Physics of OLEDs 1.3.2 Solution processable OLEDs 1.3.3 Polymer Light-Emitting Diodes 1.4 Organic Field-Effect Transistors 1.4.1 Device operation 1.4.2 Ambipolar transistors 1.5 Synthesis of π-conjugated polymers 1.6 Characterisation methods 1.6.1 Chemical structure characterisation 1.6.2 Optical characterisation 1.6.3 Morphology and microstructure 2 Motivation and aim 3 Results and discussion 3.1 Polymers for ambipolar semiconductors 3.1.1 Molecular design 3.1.2 (N-carbazole)triphenylphosphine oxide polymers 3.1.3 Bis(carbazol-3-yl)triphenylphosphine oxide polymers 3.1.4 ((Carbazol-3-yl)phenoxy)hexyl diphenylphosphinate polymers 3.1.5 ((Phenothiazin-10-yl)phenyl)diphenylphosphine oxide polymers 3.1.6 Device integration 3.1.7 Summary 3.2 DPP based molecules for OFETs 3.2.1 Molecular design 3.2.2 DBT-I series 3.2.3 DBT-II 3.2.4 Device integration 3.2.5 Summary 4 Conclusions and outlook 5 Experimental part 6 Supporting Information 7 BibliographyStaggering progress in the field of organic electronics over the past decades has led to the development of efficient optoelectronic devices, such as organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs)and organic photovoltaic cells (OPV). Moreover, semiconducting polymers enable the fabrication of low-cost, large-area electronic devices using low-temperature solution-processing methodologies on flexible substrates. The first part of this thesis focused on the development of host materials for the emitting layer (EML) of an OLED. Efficient hosts should possess a number of properties, such as high triplet energy, good and balanced charge-carrier transport, suitable frontier orbital levels that match those of the neighbouring layers, and morphological stability. To this end, carbazole-based polymers featuring an electron-withdrawing group (EWG) at different positions of the chain were designed and synthesised by Suzuki coupling. Chemical and optical characterisations of the polymers were performed prior to their incorporation into a functioning green OLED upon doping with tris(2-phenylpyridine)iridium(III) (Ir(ppy)3). Additionally, the charge-transport properties were studied through the fabrication of single-carrier devices. The second part was dedicated to the production of semiconductor materials for OFET applications. Following a novel molecular design, a series of compounds based on diketopyrrolopyrrole (DPP) and thiophene were synthesised by Stille coupling and phosphine-free direct heteroarylation. This molecular design was proven to be flexible for the synthesis of novel derivatives by modification of the end-groups. The correlation between structure and morphology was also studied. Mobility, influenced by the chemical structure and morphology of the semiconductor, is one of the most important parameters of an OFET. Thus, the obtained low bandgap materials were integrated into devices of different architectures, fabricated by solution processing methodologies, such as spin coating and shear coating, and the mobility, as well as other OFET parameters, were measured in p- and n-type operation.:1 Theoretical background 1.1 Introduction 1.2 Organic semiconductors 1.3 Organic Light Emitting Diodes 1.3.1 Physics of OLEDs 1.3.2 Solution processable OLEDs 1.3.3 Polymer Light-Emitting Diodes 1.4 Organic Field-Effect Transistors 1.4.1 Device operation 1.4.2 Ambipolar transistors 1.5 Synthesis of π-conjugated polymers 1.6 Characterisation methods 1.6.1 Chemical structure characterisation 1.6.2 Optical characterisation 1.6.3 Morphology and microstructure 2 Motivation and aim 3 Results and discussion 3.1 Polymers for ambipolar semiconductors 3.1.1 Molecular design 3.1.2 (N-carbazole)triphenylphosphine oxide polymers 3.1.3 Bis(carbazol-3-yl)triphenylphosphine oxide polymers 3.1.4 ((Carbazol-3-yl)phenoxy)hexyl diphenylphosphinate polymers 3.1.5 ((Phenothiazin-10-yl)phenyl)diphenylphosphine oxide polymers 3.1.6 Device integration 3.1.7 Summary 3.2 DPP based molecules for OFETs 3.2.1 Molecular design 3.2.2 DBT-I series 3.2.3 DBT-II 3.2.4 Device integration 3.2.5 Summary 4 Conclusions and outlook 5 Experimental part 6 Supporting Information 7 Bibliograph

Fabricate 2020

Fabricate 2020 is the fourth title in the FABRICATE series on the theme of digital fabrication and published in conjunction with a triennial conference (London, April 2020). The book features cutting-edge built projects and work-in-progress from both academia and practice. It brings together pioneers in design and making from across the fields of architecture, construction, engineering, manufacturing, materials technology and computation. Fabricate 2020 includes 32 illustrated articles punctuated by four conversations between world-leading experts from design to engineering, discussing themes such as drawing-to-production, behavioural composites, robotic assembly, and digital craft