On the mechanisms of wetting characteristics modification for selected metallic materials by means of high power diode laser radiation

This work elucidates and analyses the factors responsible for modifications to the wettability characteristics of metallic materials after high power diode laser (HPDL) treatment. It was found that interaction of EN3 and EN8 mild steel with HPDL radiation resulted in the wettability characteristics of the mild steels altering to various degrees depending upon the laser processing parameters. Such changes in the wettability characteristics of the mild steels were found to be due essentially to: (i) modifications to the surface roughness; (ii) changes in the surface O2 content and (iii) the increase in the polar component of the surface energy. All of these factors were seen to influence the wettability characteristics of the mild steels, however, the degree of influence exerted by each was found to differ. Work was therefore conducted to isolate each of these influential factors, thereby allowing the magnitude of their influence to be determined. This analysis revealed that surface roughness was the primary influential factor governing changes in and hence the wettability characteristics of the mild steels. Surface energy, by way of microstructural changes, was also shown to influence to a lesser extent changes in the wettability characteristics, whilst surface O2 content, by way of process gas, was found to play a minor role in inducing changes in the wettability characteristics of the mild steels

Carbon steel wettability characteristics enhancement for improved enamelling using a 1.2 kW high power diode laser

High-power diode laser (HPDL) surface treatment of a common engineering carbon steel(EN8) was found to effect significant changes to the wettability characteristics of the metal. These modifications have been investigated in terms of the changes in the surface roughness of the steel, the presence of any surface melting, the polar component of the steel surface energy and the relative surface oxygen content of the steel. The morphological and wetting characteristics of the mild steel and the enamel were determined using optical microscopy, scanning electron microscopy (SEM), X-ray photoemission spectroscopy (XPS), energy-dispersive X-ray (EDX) analysis and wetting experiments by the sessile drop technique. This work has shown that HPDL radiation can be used to alter the wetting characteristics of carbon steel so as to facilitate improved enamelling

Wetting and bonding characteristics of selected liquid-metals with a high power diode laser treated alumina bioceramic

Changes in the wettability characteristics of an alumina bioceramic occasioned by high power diode laser (HPDL) surface treatment were apparent from the observed reduction in the contact angle. Such changes were due to the HPDL bringing about reductions the surface roughness, increases in the surface O2 content and increases in the polar component of the surface energy. Additionally, HPDL treatment of the alumina bioceramic surface was found to effect an improvement in the bonding characteristics by increasing the work of adhesion. An electronic approach was used to elucidate the bonding characteristics of the alumina bioceramic before and after HPDL treatment. It is postulated that HPDL induced changes to the alumina bioceramic produced a surface with a reduced bandgap energy which consequently increased the work of adhesion by increasing the electron transfer at the metal/oxide interface and thus the metal-oxide interactions. Furthermore, it is suggested that the increase in the work of adhesion of the alumina bioceramic after HPDL treatment was due to a correlation existing between the wettability and ionicity of the alumina bioceramic; for it is believed that the HPDL treated surface is less ionic in nature than the untreated surface and therefore exhibits better wettability characteristics

On the predominant mechanisms active during the high power diode laser modification of the wettability characteristics of an SiO2/Al2O3-based ceramic material

The mechanisms responsible for modifications to the wettability characteristics of a SiO2/Al2O3-based ceramic material in terms of a test liquid set comprising of human blood, human blood plasma, glycerol and 4-octonol after high power diode laser (HPDL) treatment have been elucidated. Changes in the contact angle, , and hence the wettability characteristics of the SiO2/Al2O3-based ceramic were attributed primarily to: modifications to the surface roughness of the ceramic resulting from HPDL interaction which accordingly effected reductions in ; the increase in the surface O2 content of the ceramic after HPDL treatment; since an increase in surface O2 content intrinsically brings about a decrease in , and vice versa and the increase in the polar component of the surface energy, due to the HPDL induced surface melting and resolidification which consequently created a partially vitrified microstructure that was seen to augment the wetting action. However, the degree of influence exerted by each mechanism was found to differ markedly. Isolation of each of these mechanisms permitted the magnitude of their influence to be qualitatively determined. Surface energy, by way of microstructural changes, was found to be by far the most predominant element governing the wetting characteristics of the SiO2/Al2O3-based ceramic. To a much lesser extent, surface O2 content, by way of process gas, was also seen to influence to a changes in the wettability characteristics of the SiO2/Al2O3-based ceramic, whilst surface roughness was found to play a minor role in inducing changes in the wettability characteristics

Fracture surface characteristics of off-axis composites

The fracture surface characteristics of off-axis high-modulus graphite-fiber/epoxy composite specimens were studied, using a scanning electron microscope (SEM). The specimens were subjected to tensile loading at various angles (0 deg - 90 deg) to the fiber direction. SEM photomicrographs of the fractured surfaces revealed three different load angle regions with distinct fracture characteristics. Based on these revelations, criteria were established which can be used to characterize fracture surfaces with respect to a predominant single stress fracture mode

Characteristics of the Martian atmosphere surface layer

Elements of various terrestrial boundary layer models are extended to Mars in order to estimate sensible heat, latent heat, and momentum fluxes within the Martian atmospheric surface ('constant flux') layer. The atmospheric surface layer consists of an interfacial sublayer immediately adjacent to the ground and an overlying fully turbulent surface sublayer where wind-shear production of turbulence dominates buoyancy production. Within the interfacial sublayer, sensible and latent heat are transported by non-steady molecular diffusion into small-scale eddies which intermittently burst through this zone. Both the thickness of the interfacial sublayer and the characteristics of the turbulent eddies penetrating through it depend on whether airflow is aerodynamically smooth or aerodynamically rough, as determined by the Roughness Reynold's number. Within the overlying surface sublayer, similarity theory can be used to express the mean vertical windspeed, temperature, and water vapor profiles in terms of a single parameter, the Monin-Obukhov stability parameter. To estimate the molecular viscosity and thermal conductivity of a CO2-H2O gas mixture under Martian conditions, parameterizations were developed using data from the TPRC Data Series and the first-order Chapman-Cowling expressions; the required collision integrals were approximated using the Lenard-Jones potential. Parameterizations for specific heat and binary diffusivity were also determined. The Brutsart model for sensible and latent heat transport within the interfacial sublayer for both aerodynamically smooth and rough airflow was experimentally tested under similar conditions, validating its application to Martian conditions. For the surface sublayer, the definition of the Monin-Obukhov length was modified to properly account for the buoyancy forces arising from water vapor gradients in the Martian atmospheric boundary layer. It was found that under most Martian conditions, the interfacial and surface sublayers offer roughly comparable resistance to sensible heat and water vapor transport and are thus both important in determining the associated fluxes