25,275 research outputs found

    Biomimetic flow fields for proton exchange membrane fuel cells: A review of design trends

    Get PDF
    Bipolar Plate design is one of the most active research fields in Polymer Electrolyte Membrane Fuel Cells (PEMFCs) development. Bipolar Plates are key components for ensuring an appropriate water management within the cell, preventing flooding and enhancing the cell operation at high current densities. This work presents a literature review covering bipolar plate designs based on nature or biological structures such as fractals, leaves or lungs. Biological inspiration comes from the fact that fluid distribution systems found in plants and animals such as leaves, blood vessels, or lungs perform their functions (mostly the same functions that are required for bipolar plates) with a remarkable efficiency, after millions of years of natural evolution. Such biomimetic designs have been explored to date with success, but it is generally acknowledged that biomimetic designs have not yet achieved their full potential. Many biomimetic designs have been derived using computer simulation tools, in particular Computational Fluid Dynamics (CFD) so that the use of CFD is included in the review. A detailed review including performance benchmarking, time line evolution, challenges and proposals, as well as manufacturing issues is discussed.Ministerio de Ciencia, Innovación y Universidades ENE2017-91159-EXPMinisterio de Economía y Competitividad UNSE15-CE296

    Nonlinear predictive control for durability enhancement and efficiency improvement in a fuel cell power system

    Get PDF
    © . This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/In this work, a nonlinear model predictive control (NMPC) strategy is proposed to improve the efficiency and enhance the durability of a proton exchange membrane fuel cell (PEMFC) power system. The PEMFC controller is based on a distributed parameters model that describes the nonlinear dynamics of the system, considering spatial variations along the gas channels. Parasitic power from different system auxiliaries is considered, including the main parasitic losses which are those of the compressor. A nonlinear observer is implemented, based on the discretised model of the PEMFC, to estimate the internal states. This information is included in the cost function of the controller to enhance the durability of the system by means of avoiding local starvation and inappropriate water vapour concentrations. Simulation results are presented to show the performance of the proposed controller over a given case study in an automotive application (New European Driving Cycle). With the aim of representing the most relevant phenomena that affects the PEMFC voltage, the simulation model includes a two-phase water model and the effects of liquid water on the catalyst active area. The control model is a simplified version that does not consider two-phase water dynamics.Peer ReviewedPostprint (author's final draft

    The State of the Art in Fuel Cell Condition Monitoring and Maintenance

    Get PDF
    Fuel cell vehicles are considered to be a viable solution to problems such as carbon emissions and fuel shortages for road transport. Proton Exchange Membrane (PEM) Fuel Cells are mainly used in this purpose because they can run at low temperatures and have a simple structure. Yet to make this technology commercially viable, there are still many hurdles to overcome. Apart from the high cost of fuel cell systems, high maintenance costs and short lifecycle are two main issues need to be addressed. The main purpose of this paper is to review the issues affecting the reliability and lifespan of fuel cells and present the state of the art in fuel cell condition monitoring and maintenance. The Structure of PEM fuel cell is introduced and examples of its application in a variety of applications are presented. The fault modes including membrane flooding/drying, fuel/gas starvation, physical defects of membrane, and catalyst poisoning are listed and assessed for their impact. Then the relationship between causes, faults, symptoms and long term implications of fault conditions are summarized. Finally the state of the art in PEM fuel cell condition monitoring and maintenance is reviewed and conclusions are drawn regarding suggested maintenance strategies and the optimal structure for an integrated, cost effective condition monitoring and maintenance management system

    Modeling and simulations of deformation and transport in PEM fuel cells

    Get PDF
    Performance degradation and durability of PEM fuel cells depend strongly upon transport and deformation characteristics of their components especially the polymer membrane. Physical properties of the membrane, such as its ionic conductivity and Young’s modulus depend on its water content, which varies significantly with operating conditions and during transients. Recent studies indicate that cyclic transients may induce hygro-thermal fatigue that leads to the ultimate failure of the membrane shortening its lifetime, and thus, hindering the reliable use PEM fuel cells for automotive applications. In this work, we present two-dimensional simulations and analysis of coupled deformation and transport in PEM fuel cells. A two-dimensional cross-section of anode and cathode gas diffusion layers, and the membrane sandwiched between them is modeled using Maxwell-Stefan equations in gas diffusion layers, Biot’s poroelasticity and Darcy’s law for deformation and water transport in the membrane and Ohm’s law for ionic currents in the membrane and electric currents in the gas diffusion layers. Steady-state deformation and transport of water in the membrane, transient responses to step changes in load and relative humidity of the anode and cathode are obtained from simulation experiments, which are conducted by means of a commercial finite-element package, COMSOL Multiphysics

    A two-domain elevator mechanism for sodium/proton antiport

    Get PDF
    Sodium/proton (Na+/H+) antiporters, located at the plasma membrane in every cell, are vital for cell homeostasis1. In humans, their dysfunction has been linked to diseases, such as hypertension, heart failure and epilepsy, and they are well-established drug targets2. The best understood model system for Na+/H+ antiport is NhaA from Escherichia coli1, 3, for which both electron microscopy and crystal structures are available4, 5, 6. NhaA is made up of two distinct domains: a core domain and a dimerization domain. In the NhaA crystal structure a cavity is located between the two domains, providing access to the ion-binding site from the inward-facing surface of the protein1, 4. Like many Na+/H+ antiporters, the activity of NhaA is regulated by pH, only becoming active above pH 6.5, at which point a conformational change is thought to occur7. The only reported NhaA crystal structure so far is of the low pH inactivated form4. Here we describe the active-state structure of a Na+/H+ antiporter, NapA from Thermus thermophilus, at 3 Å resolution, solved from crystals grown at pH 7.8. In the NapA structure, the core and dimerization domains are in different positions to those seen in NhaA, and a negatively charged cavity has now opened to the outside. The extracellular cavity allows access to a strictly conserved aspartate residue thought to coordinate ion binding1, 8, 9 directly, a role supported here by molecular dynamics simulations. To alternate access to this ion-binding site, however, requires a surprisingly large rotation of the core domain, some 20° against the dimerization interface. We conclude that despite their fast transport rates of up to 1,500 ions per second3, Na+/H+ antiporters operate by a two-domain rocking bundle model, revealing themes relevant to secondary-active transporters in general
    • …
    corecore