A simple approach to the correlation of rotovibrational states in four-atomic molecules

The problem of correlation between quantum states of four-atomic molecules in different geometrical configurations is reviewed in detail. A general, still simple rule is obtained which allows one to correlate states of a linear four-atomic molecule with those of any kind of non-linear four-atomic molecule.Comment: 16 pages (+8 figures), Postscript (ready to print!

CAR: A MATLAB Package to Compute Correspondence Analysis with Rotations

Correspondence analysis (CA) is a popular method that can be used to analyse relationships between categorical variables. Like principal component analysis, CA solutions can be rotated both orthogonally and obliquely to simple structure without affecting the total amount of explained inertia. We describe a MATLAB package for computing CA. The package includes orthogonal and oblique rotation of axes. It is designed not only for advanced users of MATLAB but also for beginners. Analysis can be done using a user-friendly interface, or by using command lines. We illustrate the use of CAR with one example.

Quantization of the conformal arclength functional on space curves

By a conformal string in Euclidean space is meant a closed critical curve with non-constant conformal curvatures of the conformal arclength functional. We prove that (1) the set of conformal classes of conformal strings is in 1-1 correspondence with the rational points of the complex domain $\{q\in \mathbb{C} \,:\, 1/2 0,\,\, |q| < 1/\sqrt{2}\}$ and (2) any conformal class has a model conformal string, called symmetrical configuration, which is determined by three phenomenological invariants: the order of its symmetry group and its linking numbers with the two conformal circles representing the rotational axes of the symmetry group. This amounts to the quantization of closed trajectories of the contact dynamical system associated to the conformal arclength functional via Griffiths' formalism of the calculus of variations.Comment: 24 pages, 6 figures. v2: final version; minor changes in the exposition; references update

Fusion process of Lennard-Jones clusters: global minima and magic numbers formation

We present a new theoretical framework for modelling the fusion process of Lennard-Jones (LJ) clusters. Starting from the initial tetrahedral cluster configuration, adding new atoms to the system and absorbing its energy at each step, we find cluster growing paths up to the cluster sizes of up to 150 atoms. We demonstrate that in this way all known global minima structures of the LJ-clusters can be found. Our method provides an efficient tool for the calculation and analysis of atomic cluster structure. With its use we justify the magic number sequence for the clusters of noble gas atoms and compare it with experimental observations. We report the striking correspondence of the peaks in the dependence on cluster size of the second derivative of the binding energy per atom calculated for the chain of LJ-clusters based on the icosahedral symmetry with the peaks in the abundance mass spectra experimentally measured for the clusters of noble gas atoms. Our method serves an efficient alternative to the global optimization techniques based on the Monte-Carlo simulations and it can be applied for the solution of a broad variety of problems in which atomic cluster structure is important.Comment: 47 pages, MikTeX, 17 figure

On subgroups of minimal topological groups

A topological group is minimal if it does not admit a strictly coarser Hausdorff group topology. The Roelcke uniformity (or lower uniformity) on a topological group is the greatest lower bound of the left and right uniformities. A group is Roelcke-precompact if it is precompact with respect to the Roelcke uniformity. Many naturally arising non-Abelian topological groups are Roelcke-precompact and hence have a natural compactification. We use such compactifications to prove that some groups of isometries are minimal. In particular, if U_1 is the Urysohn universal metric space of diameter 1, the group Iso(U_1) of all self-isometries of U_1 is Roelcke-precompact, topologically simple and minimal. We also show that every topological group is a subgroup of a minimal topologically simple Roelcke-precompact group of the form Iso(M), where M is an appropriate non-separable version of the Urysohn space.Comment: To appear in Topology and its Applications. 39 page

Factors affecting the operation of laser-triggered gas switch (LTGS) with multi-electrode spark gap

Multi-electrode spark switches can be used for switching applications at elevated voltages or for command triggering. Symmetrical field graded electrodes allow the electrical stress across individual gaps to be controlled, thus maximising the hold off voltage and reducing switch pre-fire. The paper considers some aspects of multielectrode switch design and their influence on switching behavior. Non-symmetrical, uni-directional electrode topologies can be employed with advantages over traditional symmetrical design. The choice of working gas and gas pressure can influence switching performance in terms of delay-time and jitter. Transient analysis of switch characteristics has been undertaken in order to understand multi-electrode switching