Intensified processes for FAME production from waste cooking oil: a technological review

This article reviews the intensification of fatty acid methyl esters (FAME) production from waste cooking oil (WCO) using innovative process equipment. In particular, it addresses the intensification of WCO feedstock transformation by transesterification, esterification and hydrolysis reactions. It also discusses catalyst choice and product separation. FAME production can be intensified via the use of a number of process equipment types, including as cavitational reactors, oscillatory baffled reactors, microwave reactors, reactive distillation, static mixers and microstructured reactors. Furthermore, continuous flow equipment that integrate both reaction and separation steps appear to be the best means for intensifying FAME production. Heterogeneous catalysts have also shown to provide attractive results in terms of reaction performance in certain equipment, such as microwave reactors and reactive distillation

Analysis of current middleware used in peer-to-peer and grid implementations for enhancement by catallactic mechanisms

This deliverable describes the work done in task 3.1, Middleware analysis: Analysis of current middleware used in peer-to-peer and grid implementations for enhancement by catallactic mechanisms from work package 3, Middleware Implementation. The document is divided in four parts: The introduction with application scenarios and middleware requirements, Catnets middleware architecture, evaluation of existing middleware toolkits, and conclusions. -- Die Arbeit definiert Anforderungen an Grid und Peer-to-Peer Middleware Architekturen und analysiert diese auf ihre Eignung für die prototypische Umsetzung der Katallaxie. Eine Middleware-Architektur für die Umsetzung der Katallaxie in Application Layer Netzwerken wird vorgestellt.Grid Computing

Towards Autonomic Service Provisioning Systems

This paper discusses our experience in building SPIRE, an autonomic system for service provision. The architecture consists of a set of hosted Web Services subject to QoS constraints, and a certain number of servers used to run session-based traffic. Customers pay for having their jobs run, but require in turn certain quality guarantees: there are different SLAs specifying charges for running jobs and penalties for failing to meet promised performance metrics. The system is driven by an utility function, aiming at optimizing the average earned revenue per unit time. Demand and performance statistics are collected, while traffic parameters are estimated in order to make dynamic decisions concerning server allocation and admission control. Different utility functions are introduced and a number of experiments aiming at testing their performance are discussed. Results show that revenues can be dramatically improved by imposing suitable conditions for accepting incoming traffic; the proposed system performs well under different traffic settings, and it successfully adapts to changes in the operating environment.Comment: 11 pages, 9 Figures, http://www.wipo.int/pctdb/en/wo.jsp?WO=201002636

Effect of surfactants on liquid side mass transfer coefficients

In the present paper, the effect of liquid properties (surfactants) on bubble generation phenomenon, interfacial area and liquid side mass transfer coefficient was investigated. The measurements of surface tension (static and dynamic methods), of Critical Micelle Concentration (CMC) and of characteristic adsorption parameters such as the surface coverage ratio at equilibrium (se) were performed to understand the effects of surfactants on the mass transfer efficiency. Tap water and aqueous solutions with surfactants (cationic and anionic) were used as liquid phases and an elastic membrane with a single orifice as gas sparger. The bubbles were generated into a small-scale bubble column. The local liquid side mass transfer coefficient (kL) was obtained from the volumetric mass transfer coefficient (kLa) and the interfacial area (a) was deduced from the bubble diameter (DB), the bubble frequency (fB) and the terminal bubble rising velocity (UB). Only the dynamic bubble regime was considered in this work (ReOR = 150 - 1000 and We = 0.002 - 4). This study has clearly shown that the presence of surfactants affects the bubble generation phenomenon and thus the interfacial area (a) and the different mass transfer parameters, such as the volumetric mass transfer coefficient (kLa) and the liquid-side mass transfer coefficient (kL). Whatever the operating conditions, the new kLa determination method has provided good accuracy without assuming that the liquid phase is perfectly mixed as in the classical method. The surface coverage ratio (se) proves to be crucial for predicting the changes of kL in aqueous solutions with surfactants