Imatge d’espectroscòpia Raman i quimiometria per investigar documents forenses relacionats amb accions delictives com línies creuades i obliteració

Treballs Finals de Grau de Química, Facultat de Química, Universitat de Barcelona, Any: 2022, Tutores: Mónica Marro Sánchez, Anna de Juan CapdevilaDocument forgery is a serious crime followed by judicial authorities. The most common cases of fraud in handwritten documents are related to character modification or text deletion, known as falsifications through crossed lines and obliterations, respectively. The use of destructive and subjective techniques in the last decades has hindered forensic investigations. This is the reason why this work proposes a non-destructive, quick, objective, and trustworthy analytical technique for forensic detection of fraud in handwritten documents, based on the combination of hyperspectral Raman imaging with the image unmixing method Multivariate Curve Resolution – Alternating Least Squares (MCR-ALS). The beginning of the research consisted of investigating the potential of Raman spectroscopy to distinguish commercial blue inks. Ink differentiation using Raman spectroscopy has proven to be very satisfactory for inks of different brands and typologies. Hence, the next step was the acquisition of Raman images in simulated cases of document falsification using confocal microscopy. The distribution maps and spectral signatures obtained for every ink in these forgeries applying spectral preprocessing and MCR-ALS have been very satisfactory, proving that the used analytical techniques are appropriate and allow obtaining detailed information regarding the distribution of inks throughout the paper in any written document. It has been observed that the nature of inks leads to different interactions in the crossed strokes and in the ink distribution on the paper. The chronological order of ink strokes application has been correctly solved in almost all crossed lines studied cases, except in a reported case of inks of a particular brand. Obliterated texts have been satisfactorily recovered, irrespective of the ink typology applied over them. We have proven that fast Raman imaging operates correctly to detect obliterations and that an increase of spatial resolution allows recovering complicated and small characters very accurately

Computer Aided Multi-Data Fusion Dismount Modeling

Recent research efforts strive to address the growing need for dismount surveillance, dismount tracking and characterization. Current work in this area utilizes hyperspectral and multispectral imaging systems to exploit spectral properties in order to detect areas of exposed skin and clothing characteristics. Because of the large bandwidth and high resolution, hyperspectral imaging systems pose great ability to characterize and detect dismounts. A multi-data dismount modeling system where the development and manipulation of dismount models is a necessity. This thesis demonstrates a computer aided multi-data fused dismount model, which facilitates studies of dismount detection, characterization and identification. The system is created by fusing: pixel mapping, signature attachment, and pixel mixing algorithms. The developed multi-data dismount model produces simulated hyperspectral images that closely represent an image collected by a hyperspectral imager. The dismount model can be modified to fit the researcher\u27s needs. The multi-data model structure allows the employment of a database of signatures acquired from several sources. The model is flexible enough to allow further exploitation, enhancement and manipulation. The multi-data dismount model developed in this effort fulfills the need for a dismount modeling tool in a hyperspectral imaging environment

DETECTION OF GRANULATION TISSUE FOR HEALING ASSESSMENT OF CHRONIC ULCERS

Wounds that fail to heal within an expected period develop into ulcers that cause severe pain and expose patients to limb amputation. Ulcer appearance changes gradually as ulcer tissues evolve throughout the healing process. Dermatologists assess the progression of ulcer healing based on visual inspection of ulcer tissues, which is inconsistent and subjective. The ability to measure objectively early stages of ulcer healing is important to improve clinical decisions and enhance the effectiveness of the treatment. Ulcer healing is indicated by the growth of granulation tissue that contains pigment haemoglobin that causes the red colour of the tissue. An approach based on utilising haemoglobin content as an image marker to detect regions of granulation tissue on ulcers surface using colour images of chronic ulcers is investigated in this study. The approach is utilised to develop a system that is able to detect regions of granulation tissue on ulcers surface using colour images of chronic ulcers

Deteção remota multiespectral e hiperespetral como fonte de conhecimento no sector português da Faixa Piritosa Ibérica

ABSTRACT: Remote sensing is an invaluable tool to increase geological and mining knowledge, due to its screening view and variable discrimination and identification capabilities of the target materials. In this study an overview of remote sensing research developed and ongoing within the Portuguese sector of the Iberian Pyrite Belt (PSIPB) since 2000 is given. Multispectral and hyperspectral datasets were processed using hybrid methods, related both to general and detailed characterization, to: 1) support geological, mineral and hydrothermal mapping, 2) generate products derived from multivariate analysis and band ratios, 3) enhance correlation with radiometric data, 4) provide elements for environmental assessment concerning mining activity, 5) map Acid Mine Drainage (AMD) based on spectral field signatures, 6) quantify AMD based on high correlation mineralogical mapping, and 7) monitor AMD. The results highlight the importance of the quantitative digital support given by remote sensing tools within the Portuguese Sector of the Iberian Pyrite Belt (PSIPB), ruled by georesource exploitation in different stages of the Mine Lyfe Cycle.RESUMO: A deteção remota é uma ferramenta valiosa para aumentar o conhecimento geológico e mineiro, devido à visão sinótica e à capacidade variável de discriminação e identificação dos materiais-alvo. Neste trabalho dá-se uma visão geral da investigação através dos trabalhos de deteção remota desenvolvidos e em curso no Setor Português da Faixa Piritosa Ibérica (SPFPI) desde 2000. Os dados multiespectrais e hiperespectrais foram processados usando métodos híbridos quer para a sua caracterização geral quer detalhada para: 1) apoiar a cartografia geológica, de mineralizações e sistemas hidrotermais, 2) gerar produtos de análise multivariada e rácios de bandas, 3) melhorar a correlação com dados radiométricos 4) fornecer elementos para avaliação ambiental em áreas mineiras, 5) cartografar a drenagem ácida de mina (DAM) com assinaturas espectrais de campo, 6) quantificar a DAM através de cartografia mineralógica de alta correlação, e 7) monitorizar a DAM. Destaca-se a importância do suporte digital quantitativo dado por ferramentas de deteção remota no SPFPI, regido pela exploração de georrecursos em diferentes fases do Ciclo de Vida das Minas.info:eu-repo/semantics/publishedVersio

Mapping and Assessing Impacts of Land Use and Land Cover Change by Means of Advanced Remote Sensing Approach:: Mapping and Assessing Impacts of Land Use and Land Cover Change by Means of Advanced Remote Sensing Approach:: A case Study of Gash Agricultural Scheme, Eastern Sudan

Risks and uncertainties are unavoidable in agriculture in Sudan, due to its dependence on climatic factors and to the imperfect nature of the agricultural decisions and policies attributed to land cover and land use changes that occur. The current study was conducted in the Gash Agricultural Scheme (GAS) - Kassala State, as a semi-arid land in eastern Sudan. The scheme has been established to contribute to the rural development, to help stability of the nomadic population in eastern Sudan, particularly the local population around the Gash river areas, and to facilitate utilizing the river flood in growing cotton and other cash crops. In the last decade, the scheme production has declined, because of drought periods, which hit the region, sand invasion and the spread of invasive mesquite trees, in addition to administrative negligence. These have resulted also in poor agricultural productivity and the displacement of farmers away from the scheme area. Recently, the scheme is heavily disturbed by human intervention in many aspects. Consequently, resources of cultivated land have shrunk and declined during the period of the study, which in turn have led to dissatisfaction and increasing failure of satisfying increasing farmer’s income and demand for local consumption. Remote sensing applications and geospatial techniques have played a key role in studying different types of hazards whether they are natural or manmade. Multi-temporal satellite data combined with ancillary data were used to monitor, analyze and to assess land use and land cover (LULC) changes and the impact of land degradation on the scheme production, which provides the managers and decision makers with current and improved data for the purposes of proper administration of natural resources in the GAS. Information about patterns of LULC changes through time in the GAS is not only important for the management and planning, but also for a better understanding of human dimensions of environmental changes at regional scale. This study attempts to map and assess the impacts of LULC change and land degradation in GAS during a period of 38 years from 1972-2010. Dry season multi-temporal satellite imagery collected by different sensor systems was selected such as three cloud-free Landsat (MSS 1972, TM 1987 and ETM+ 1999) and ASTER (2010) satellite imagery. This imagery was geo-referenced and radiometrically and atmospherically calibrated using dark object subtraction (DOS). Two approaches of classification (object-oriented and pixel-based) were applied for classification and comparison of LULC. In addition, the study compares between the two approaches to determine which one is more compatible for classification of LULC of the GAS. The pixel-based approach performed slightly better than the object-oriented approach in the classification of LULC in the study area. Application of multi-temporal remote sensing data proved to be successful for the identification and mapping of LULC into five main classes as follows: woodland dominated by dense mesquite trees, grass and shrubs dominated by less dense mesquite trees, bare and cultivated land, stabilized fine sand and mobile sand. After image enhancement successful classification of imagery was achieved using pixel and object based approaches as well as subsequent change detection (image differencing and change matrix), supported by classification accuracy assessments and post-classification. Comparison of LULC changes shows that the land cover of GAS has changed dramatically during the investigated period. It has been discovered that more significant of LULC change processes occurred during the second studied period (1987 to 1999) than during the first period (1972-1987). In the second period nearly half of bare and cultivated lands was changed from 41372.74 ha (20.22 %) in 1987 to 28020.80 ha (13.60 %) in 1999, which was mainly due to the drought that hit the region during the mentioned period. However, the results revealed a drastic loss of bare and cultivated land, equivalent to more than 40% during the entire period (1972-2010). Throughout the whole period of study, drought and invasion of both mesquite trees and sand were responsible for the loss of more than 40% of the total productive lands. Change vector analysis (CVA) as a useful approach was applied for estimating change detection in both magnitude and direction of change. The promising approach of multivariate alteration detection (MAD) and subsequent maximum autocorrelation factor (MAD/MAF) transformation was used to support change detection via assessment of maximum correlation between the transformed variates and the specific original image bands related to specific land cover classes. However, both CVA and MAD/MAD strongly prove the fact that bare and cultivated land have dramatically changed and decreased continuously during the studied period. Both CVA and MAD/MAD demonstrate adequate potentials for monitoring, detecting, identifying and mapping the changes. Moreover, this research demonstrated that CVA and MAD/MAF are superior in providing qualitative details about the nature of all kinds of change. Vegetation indices (VI) such as normalized difference vegetation index (NDVI), soil-adjusted vegetation index (SAVI), modified adjusted vegetation index (MSAVI) and grain soil index (GSI) were applied to measure the quantitative characterization of temporal and spatial vegetation cover patterns and change. All indices remain very sensitive to structure variation of LULC. The results reveal that the NDVI is more effective for detecting the amount and status of the vegetation cover in the study area than SAVI, MSAVI and GSI. Therefore, it can be stated that NDVI can be used as a response variable to identify drought disturbance and land degradation in semi-arid land such as the GAS area. Results of detecting vegetation cover observed by using SAVI were found to be more reasonable than using MSAVI, although MSAVI reduces the background of bare soil better than SAVI. GSI proves high efficiency in determining the different types of surface soils, and producing a change map of top soil grain size, which is useful in assessment of land degradation in the study area. The linkage between socio-economic data and remotely sensed data was applied to determine the relationships between the different factors derived and to analyze the reasons for change in LULC and land degradation and its effects in the study area. The results indicate a strong relationship between LULC derived from remotely sensed data and the influencing socioeconomic variables. The results obtained from analyzing socioeconomic data confirm the findings of remote sensing data analysis, which assure that the decline and degradation of agricultural land is a result of further spread of mesquite trees and of increased invasion of sand during the study period. High livestock density and overgrazing, drought, invasion of sand, spread of invasive mesquite trees, overexploitation of land, improper management, and population growth were considered as the main direct factors responsible for degradation in the study area

Multispectral and hyperspectral remote sensing as a source of knowledge in the Portuguese sector of the Iberian Pyrite Belt

ABSTRACT: Remote sensing is an invaluable tool to increase geological and mining knowledge, due to its screening view and variable discrimination and identification capabilities of the target materials. In this study an overview of remote sensing research developed and ongoing within the Portuguese sector of the Iberian Pyrite Belt (PSIPB) since 2000 is given. Multispectral and hyperspectral datasets were processed using hybrid methods, related both to general and detailed characterization, to: 1) support geological, mineral and hydrothermal mapping, 2) generate products derived from multivariate analysis and band ratios, 3) enhance correlation with radiometric data, 4) provide elements for environmental assessment concerning mining activity, 5) map Acid Mine Drainage (AMD) based on spectral field signatures, 6) quantify AMD based on high correlation mineralogical mapping, and 7) monitor AMD. The results highlight the importance of the quantitative digital support given by remote sensing tools within the Portuguese Sector of the Iberian Pyrite Belt (PSIPB), ruled by georesource exploitation in different stages of the Mine Lyfe Cycle.RESUMO: A deteção remota é uma ferramenta valiosa para aumentar o conhecimento geológico e mineiro, devido à visão sinótica e à capacidade variável de discriminação e identificação dos materiais-alvo. Neste trabalho dá-se uma visão geral da investigação através dos trabalhos de deteção remota desenvolvidos e em curso no Setor Português da Faixa Piritosa Ibérica (SPFPI) desde 2000. Os dados multiespectrais e hiperespectrais foram processados usando métodos híbridos quer para a sua caracterização geral quer detalhada para: 1) apoiar a cartografia geológica, de mineralizações e sistemas hidrotermais, 2) gerar produtos de análise multivariada e rácios de bandas, 3) melhorar a correlação com dados radiométricos 4) fornecer elementos para avaliação ambiental em áreas mineiras, 5) cartografar a drenagem ácida de mina (DAM) com assinaturas espectrais de campo, 6) quantificar a DAM através de cartografia mineralógica de alta correlação, e 7) monitorizar a DAM. Destaca-se a importância do suporte digital quantitativo dado por ferramentas de deteção remota no SPFPI, regido pela exploração de georrecursos em diferentes fases do Ciclo de Vida das Minas

Photometry of the Globular Cluster NGC 5466: Red Giants and Blue Stragglers

We present wide-field BVI photometry for about 11,500 stars in the low-metallicity cluster NGC 5466. We have detected the red giant branch bump for the first time, although it is at least 0.2 mag fainter than expected relative to the turnoff. The number of red giants (relative to main sequence turnoff stars) is in excellent agreement with stellar models from the Yonsei-Yale and Teramo groups, and slightly high compared to Victoria-Regina models. This adds to evidence that an abnormally large ratio of red giant to main-sequence stars is not correlated with cluster metallicity. We discuss theoretical predictions from different research groups and find that the inclusion or exclusion of helium diffusion and strong limit Coulomb interactions may be partly responsible. We also examine indicators of dynamical history: the mass function exponent and the blue straggler frequency. NGC 5466 has a very shallow mass function, consistent with large mass loss and recently-discovered tidal tails. The blue straggler sample is significantly more centrally concentrated than the HB or RGB stars. We see no evidence of an upturn in the blue straggler frequency at large distances from the center. Dynamical friction timescales indicate that the stragglers should be more concentrated if the cluster's present density structure has existed for most of its history. NGC 5466 also has an unusually low central density compared to clusters of similar luminosity. In spite of this, the specific frequency of blue stragglers that puts it right on the frequency -- cluster M_V relation observed for other clusters.Comment: 51 pages, 21 figures, 1 electronic table, accepted to Ap