Improving optimal control of grid-connected lithium-ion batteries through more accurate battery and degradation modelling

The increased deployment of intermittent renewable energy generators opens up opportunities for grid-connected energy storage. Batteries offer significant flexibility but are relatively expensive at present. Battery lifetime is a key factor in the business case, and it depends on usage, but most techno-economic analyses do not account for this. For the first time, this paper quantifies the annual benefits of grid-connected batteries including realistic physical dynamics and nonlinear electrochemical degradation. Three lithium-ion battery models of increasing realism are formulated, and the predicted degradation of each is compared with a large-scale experimental degradation data set (Mat4Bat). A respective improvement in RMS capacity prediction error from 11\% to 5\% is found by increasing the model accuracy. The three models are then used within an optimal control algorithm to perform price arbitrage over one year, including degradation. Results show that the revenue can be increased substantially while degradation can be reduced by using more realistic models. The estimated best case profit using a sophisticated model is a 175% improvement compared with the simplest model. This illustrates that using a simplistic battery model in a techno-economic assessment of grid-connected batteries might substantially underestimate the business case and lead to erroneous conclusions

Development of a simulation-based decision support tool for renewable energy integration and demand-supply matching

This paper describes a simulation-based decision support tool, MERIT, which has been developed to assist in the assessment of renewable energy systems by focusing on the degree of match achievable between energy demand and supply. Models are described for the prediction of the performance of PV, wind and battery technologies. These models are based on manufacturers' specifications, location-related parameters and hourly weather data. The means of appraising the quality of match is outlined and examples are given of the application of the tool at the individual building and community levels

Thermal modeling of industrial-scale vanadium redox flow batteries in high-current operations

A cell-resolved model that simulates the dynamic thermal behavior of a Vanadium Redox Flow Battery during charge and discharge is presented. It takes into account, at a cell level, the reversible entropic heat of the electrochemical reactions, irreversible heat due to overpotentials, self-discharge reactions due to ion crossover, and shunt current losses. The model accounts for the heat transfer between cells and toward the environment, the pump hydraulic losses and the heat transfer of piping and tanks. It provides the electrolyte temperature in each cell, at the stack inlet and outlet, along the piping and in the tanks. Validation has been carried out against the charge/discharge measurements from a 9kW/27kWh VRFB test facility. The model has been applied to study a VRFB with the same stack but a much larger capacity, operating at \uf0b1400 A for 8 h, in order to identify critical thermal conditions which may occur in next-generation industrial VRFB stacks capable to operating at high current density. The most critical condition has been found at the end a long discharge, when temperatures above 50\ub0C appeared, possibly resulting in \u3016VO\u3017_2^+ precipitation and battery faults. These results call for heat exchangers tailored to assist high-power VRFB systems

Techno-Economic Analysis and Optimal Control of Battery Storage for Frequency Control Services, Applied to the German Market

Optimal investment in battery energy storage systems, taking into account degradation, sizing and control, is crucial for the deployment of battery storage, of which providing frequency control is one of the major applications. In this paper, we present a holistic, data-driven framework to determine the optimal investment, size and controller of a battery storage system providing frequency control. We optimised the controller towards minimum degradation and electricity costs over its lifetime, while ensuring the delivery of frequency control services compliant with regulatory requirements. We adopted a detailed battery model, considering the dynamics and degradation when exposed to actual frequency data. Further, we used a stochastic optimisation objective while constraining the probability on unavailability to deliver the frequency control service. Through a thorough analysis, we were able to decrease the amount of data needed and thereby decrease the execution time while keeping the approximation error within limits. Using the proposed framework, we performed a techno-economic analysis of a battery providing 1 MW capacity in the German primary frequency control market. Results showed that a battery rated at 1.6 MW, 1.6 MWh has the highest net present value, yet this configuration is only profitable if costs are low enough or in case future frequency control prices do not decline too much. It transpires that calendar ageing drives battery degradation, whereas cycle ageing has less impact.Comment: Submitted to Applied Energ

A H2 PEM fuel cell and high energy dense battery hybrid energy source for an urban electric vehicle

Electric vehicles are set to play a prominent role in addressing the energy and environmental impact of an increasing road transport population by offering a more energy efficient and less polluting drive-train alternative to conventional internal combustion engine (ICE) vehicles. Given the energy (and hence range) and performance limitations of electro-chemical battery storage systems, hybrid systems combining energy and power dense storage technologies have been proposed for vehicle applications. The paper discusses the application of a hydrogen fuel cell as a range extender for an urban electric vehicle for which the primary energy source is provided by a high energy dense battery. A review of fuel cell systems and automotive drive-train application issues are discussed, together with an overview of the battery technology. The prototype fuel cell and battery component simulation models are presented and their performance as a combined energy/power source assessed for typical urban and sub-urban driving scenario

A Review of Lithium-Ion Battery Models in Techno-economic Analyses of Power Systems

The penetration of the lithium-ion battery energy storage system (BESS) into the power system environment occurs at a colossal rate worldwide. This is mainly because it is considered as one of the major tools to decarbonize, digitalize, and democratize the electricity grid. The economic viability and technical reliability of projects with batteries require appropriate assessment because of high capital expenditures, deterioration in charging/discharging performance and uncertainty with regulatory policies. Most of the power system economic studies employ a simple power-energy representation coupled with an empirical description of degradation to model the lithium-ion battery. This approach to modelling may result in violations of the safe operation and misleading estimates of the economic benefits. Recently, the number of publications on techno-economic analysis of BESS with more details on the lithium-ion battery performance has increased. The aim of this review paper is to explore these publications focused on the grid-scale BESS applications and to discuss the impacts of using more sophisticated modelling approaches. First, an overview of the three most popular battery models is given, followed by a review of the applications of such models. The possible directions of future research of employing detailed battery models in power systems' techno-economic studies are then explored

A Comparative Study on the Influence of DC/DC-Converter Induced High Frequency Current Ripple on Lithium-Ion Batteries

Modern battery energy systems are key enablers of the conversion of our energy and mobility sector towards renewability. Most of the time, their batteries are connected to power electronics that induce high frequency current ripple on the batteries that could lead to reinforced battery ageing. This study investigates the influence of high frequency current ripple on the ageing of commercially available, cylindrical 18,650 lithium-ion batteries in comparison to identical batteries that are aged with a conventional battery test system. The respective ageing tests that have been carried out to obtain numerous parameters such as the capacity loss, the gradient of voltage curves and impedance spectra are explained and evaluated to pinpoint how current ripple possibly affects battery ageing. Finally, the results suggest that there is little to no further influence of current ripple that is severe enough to stand out against ageing effects due to the underlying accelerated cyclic ageing