A review of the importance of recycling lithium-ion batteries for lithium, in view of impending electric vehicle industry

Automobile electrification is one the technological developments, that will commence an earth friendly transport system, by mitigating emissions and hopefully lead to a less fossil fuel dependent society. With commercial success attained by models like Nissan’s leaf and Chevy’s Volt, the consumer market looks promising to assimilate vehicle electrification. At present these technologies include HEVs (hybrid electric vehicles), PHEVs (plug-in hybrid electric vehicles), EVs (complete electric vehicles). A closer look at these technologies will lead us to one of the crucial components of electric vehicles, the “batteries”. This component decides one of the key performance factors which is the energy storage and usage, which means it is the basis for public acceptability. The lithium-ion battery chemistries are chosen to fulfill this requirement. Although lithium constitutes of a small fraction of the complete battery weight, still its contin-ued availability in future is debated among many resource analysts

Model Predictive Control Strategies for Advanced Battery Management Systems

Consumer electronics, wearable and personal health devices, power networks, microgrids, and hybrid electric vehicles (HEVs) are some of the many applications where Lithium-ion (Li-ion) batteries are employed. From a manufacturer point of view, the optimal design and management of such electrochemical accumulators are important aspects for ensuring safe and profitable operations. The adoption of mathematical models can support the achievement of the best performance, while saving time and money. In the literature, all the models used to describe the behavior of a Li-ion battery belong to one of the two following families: (i) Equivalent Circuit Models (ECMs), and (ii) Electrochemical Models (EMs). While the former family represents the battery dynamics by means of electrical circuits, the latter resorts to first principles laws of modeling. As a first contribution, this Thesis provides a thorough investigation of the pseudo-two-dimensional (P2D) Li-ion battery EM. In particular, the objectives are to provide: (i) a detailed description of the model formulation, (ii) the Li-ION SIMulation BAttery (LIONSIMBA) toolbox as a finite volume Matlab implementation of the P2D model, for design, simulation, and control of Li-ion cells or battery packs, (iii) a validation of the proposed tool with respect to the COMSOL MultiPhysics commercial software and the Newman's DUALFOIL code, and (iv) some demonstrative simulations involving thermal dynamics, a hybrid charge-discharge cycle emulating the throttle of an HEV, and a battery pack of series connected cells. The second contribution is related to the development of several charging strategies for Advanced Battery Management Systems (ABMSs), where predictive approaches are employed to attain optimal control. Model Predictive Control (MPC) refers to a particular family of control algorithms that, according to a mathematical model, predicts the future behavior of a plant, while considering inputs and outputs constraints. According to this paradigm, in this Thesis different ABMSs strategies have been developed, and their effectiveness shown through simulations. Due to the complexity of the P2D model, its inclusion within an MPC context could prevent the online application of the control algorithm. For this reason, different approximations of the P2D dynamics are proposed and their MPC formulations carefully explained. In particular, finite step response, autoregressive exogenous, piecewise affine, and linear time varying approximations are presented. For all the aforementioned reformulations, the closed-loop performance are evaluated considering the P2D implementation of LIONSIMBA as the real plant. The closed-loop simulations highlight the suitability of the MPC paradigm to be employed for the development of the future ABMSs. In fact, its ability to predict the future behavior of the cell while considering operating constraints can help in preventing possible safety issues and improving the charging performance. Finally, the reliability and efficiency of the proposed Matlab toolbox in simulating the P2D dynamics, support the idea that LIONSIMBA can significantly contribute in the advance of the battery field.Consumer electronics, wearable and personal health devices, power networks, microgrids, and hybrid electric vehicles (HEVs) are some of the many applications where Lithium-ion (Li-ion) batteries are employed. From a manufacturer point of view, the optimal design and management of such electrochemical accumulators are important aspects for ensuring safe and profitable operations. The adoption of mathematical models can support the achievement of the best performance, while saving time and money. In the literature, all the models used to describe the behavior of a Li-ion battery belong to one of the two following families: (i) Equivalent Circuit Models (ECMs), and (ii) Electrochemical Models (EMs). While the former family represents the battery dynamics by means of electrical circuits, the latter resorts to first principles laws of modeling. As a first contribution, this Thesis provides a thorough investigation of the pseudo-two-dimensional (P2D) Li-ion battery EM. In particular, the objectives are to provide: (i) a detailed description of the model formulation, (ii) the Li-ION SIMulation BAttery (LIONSIMBA) toolbox as a finite volume Matlab implementation of the P2D model, for design, simulation, and control of Li-ion cells or battery packs, (iii) a validation of the proposed tool with respect to the COMSOL MultiPhysics commercial software and the Newman's DUALFOIL code, and (iv) some demonstrative simulations involving thermal dynamics, a hybrid charge-discharge cycle emulating the throttle of an HEV, and a battery pack of series connected cells. The second contribution is related to the development of several charging strategies for Advanced Battery Management Systems (ABMSs), where predictive approaches are employed to attain optimal control. Model Predictive Control (MPC) refers to a particular family of control algorithms that, according to a mathematical model, predicts the future behavior of a plant, while considering inputs and outputs constraints. According to this paradigm, in this Thesis different ABMSs strategies have been developed, and their effectiveness shown through simulations. Due to the complexity of the P2D model, its inclusion within an MPC context could prevent the online application of the control algorithm. For this reason, different approximations of the P2D dynamics are proposed and their MPC formulations carefully explained. In particular, finite step response, autoregressive exogenous, piecewise affine, and linear time varying approximations are presented. For all the aforementioned reformulations, the closed-loop performance are evaluated considering the P2D implementation of LIONSIMBA as the real plant. The closed-loop simulations highlight the suitability of the MPC paradigm to be employed for the development of the future ABMSs. In fact, its ability to predict the future behavior of the cell while considering operating constraints can help in preventing possible safety issues and improving the charging performance. Finally, the reliability and efficiency of the proposed Matlab toolbox in simulating the P2D dynamics, support the idea that LIONSIMBA can significantly contribute in the advance of the battery field