Multipurpose High Frequency Electron Spin Resonance Spectrometer for Condensed Matter Research

We describe a quasi-optical multifrequency ESR spectrometer operating in the 75-225 GHz range and optimized at 210 GHz for general use in condensed matter physics, chemistry and biology. The quasi-optical bridge detects the change of mm wave polarization at the ESR. A controllable reference arm maintains a mm wave bias at the detector. The attained sensitivity of 2x10^10 spin/G/(Hz)1/2, measured on a dilute Mn:MgO sample in a non-resonant probe head at 222.4 GHz and 300 K, is comparable to commercial high sensitive X band spectrometers. The spectrometer has a Fabry-Perot resonator based probe head to measure aqueous solutions, and a probe head to measure magnetic field angular dependence of single crystals. The spectrometer is robust and easy to use and may be operated by undergraduate students. Its performance is demonstrated by examples from various fields of condensed matter physics.Comment: submitted to Journal of Magnetic Resonanc

Time-domain Brillouin scattering assisted by diffraction gratings

Absorption of ultrashort laser pulses in a metallic grating deposited on a transparent sample launches coherent compression/dilatation acoustic pulses in directions of different orders of acoustic diffraction. Their propagation is detected by the delayed laser pulses, which are also diffracted by the metallic grating, through the measurement of the transient intensity change of the first order diffracted light. The obtained data contain multiple frequency components which are interpreted by considering all possible angles for the Brillouin scattering of light achieved through the multiplexing of the propagation directions of light and coherent sound by the metallic grating. The emitted acoustic field can be equivalently presented as a superposition of the plane inhomogeneous acoustic waves, which constitute an acoustic diffraction grating for the probe light. Thus, the obtained results can also be interpreted as a consequence of probe light diffraction by both metallic and acoustic gratings. The realized scheme of time-domain Brillouin scattering with metallic grating operating in reflection mode provides access to acoustic frequencies from the minimal to the maximal possible in a single experimental configuration for the directions of probe light incidence and scattered light detection. This is achieved by monitoring of the backward and forward Brillouin scattering processes in parallel. Applications include measurements of the acoustic dispersion, simultaneous determination of sound velocity and optical refractive index, and evaluation of the samples with a single direction of possible optical access.Comment: 21 pages, 4 figures, 1 tabl

Neutronics Studies on the NIST Reactor Using the GA LEU fuel

The National Bureau of Standards Reactor (NBSR) located on the National Institute of Standards and Technology (NIST) Gaithersburg campus, is currently underway of fuel conversion from high enriched uranium (HEU) fuel to low enriched uranium (LEU) fuel. One particular challenging part of the conversion of the NBSR is the high average flux level (2.5×1014 n/cm2-s) required to maintain experimental testing capabilities of the reactor, without significant changes to the external structures of the reactor. Recently the General Atomics (GA) Training Research Isotopes General Atomics (TRIGA) fuel has shown some promising features as a LEU candidate for the high performance research reactors such as the NBSR. The GA fuel has a long history of success in conversion of research reactors since it was developed in 1980s. The UZrH compound in the GA fuel has seen success in long term TRIGA reactors, and is a proven safe LEU alternative. This study performs a neutronics evaluation of the TRIGA fuel under the schema of the NBSR’s heavy conversion requirements in order to examine whether the TRIGA fuel is a viable option for conversion of the NBSR. To determine the most optimal path of conversion, we performed a feasibility study with particular regard to the fuel dimensions, fuel rod configurations, cladding, as well as fuel structure selection. Based on the outcome of the feasibility study, an equilibrium core is then generated following the NBSR’s current fuel management schema. Key neutronics performance characteristics including flux distribution, power distribution, control rod (i.e., shim arms) worth, as well as kinetics parameters of the equilibrium core are calculated and evaluated. MCNP6, a Monte Carlo based computational modeling software was intensively used to aid in these calculations. The results of this study will provide important insight on the effectiveness of conversion, as well as determine the viability of the conversion from HEU to LEU using the GA fuel

Effect of the matrix behavior on the damage of ethylene–propylene glass fiber reinforced composite subjected to high strain rate tension

This study investigates the origin of the strain rate effect on the mechanical behavior of a discontinuous glass fiber reinforced ethylene–propylene copolymer (EPC) matrix composite. This kind of composite materials are commonly used for automotive functional and structural applications. To this aim, a multi-scale experimental approach is developed. The deformation processes and the damage mechanisms observed at the microscopic scale are related to the material mechanical properties at the macroscopic scale. Tensile tests up to failure and specific interrupted tensile tests have been optimized and performed for high strain rates up to 200 s 1 to quantify the strain rate effect at different scales. High speed tensile tests have also been performed on the pure copolymer matrix. The threshold and the kinetic of damage have been quantified at both microscopic and macroscopic scales. Experimental results show that the composite behavior is strongly strain-rate dependent. The multi-scale analysis leads to the conclusion that the strain rate effect on the damage behavior of the EPC matrix composite is mainly due to the viscous behavior of the EPC matrix. SEM observations and analysis show that a localized deformation in the interface zone around fibers occurs at high strain rates and directly affects the visco-damage behavior. It is established that when the strain rate increases, the local deformation zone around the fibers behaves like a dissipation zone. Consequently, the damage initiation is delayed and the related kinetic is reduced with respect to the quasi-static loading case

Effect of the matrix behavior on the damage of ethylene–propylene glass fiber reinforced composite subjected to high strain rate tension

This study investigates the origin of the strain rate effect on the mechanical behavior of a discontinuous glass fiber reinforced ethylene–propylene copolymer (EPC) matrix composite. This kind of composite materials are commonly used for automotive functional and structural applications. To this aim, a multi-scale experimental approach is developed. The deformation processes and the damage mechanisms observed at the microscopic scale are related to the material mechanical properties at the macroscopic scale. Tensile tests up to failure and specific interrupted tensile tests have been optimized and performed for high strain rates up to 200 s 1 to quantify the strain rate effect at different scales. High speed tensile tests have also been performed on the pure copolymer matrix. The threshold and the kinetic of damage have been quantified at both microscopic and macroscopic scales. Experimental results show that the composite behavior is strongly strain-rate dependent. The multi-scale analysis leads to the conclusion that the strain rate effect on the damage behavior of the EPC matrix composite is mainly due to the viscous behavior of the EPC matrix. SEM observations and analysis show that a localized deformation in the interface zone around fibers occurs at high strain rates and directly affects the visco-damage behavior. It is established that when the strain rate increases, the local deformation zone around the fibers behaves like a dissipation zone. Consequently, the damage initiation is delayed and the related kinetic is reduced with respect to the quasi-static loading case

TRADE COSTS, TRADE BALANCES AND CURRENT ACCOUNTS: AN APPLICATION OF GRAVITY TO MULTILATERAL TRADE

In this paper we test the well-known hypothesis of Obstfeld and Rogoff (2000) that trade costs are the key to explaining the so-called Feldstein-Horioka puzzle. Our approach has a number of novel features. First, we focus on the interrelationship between trade costs, the trade account and the Feldstein-Horioka puzzle. Second, we use the gravity model to estimate the effect of trade costs on bilateral trade and, third, we show how bilateral trade can be used to draw inferences about desired trade balances and desired intertemporal trade. Our econo-metric results provide strong support for the Obstfeld and Rogoff hypothesis and we are also able to reconcile our results with the so-called home bias puzzle.Feldstein-Horioka puzzle; trade costs; gravity model; home bias puzzle; current account; trade balance