Effect of resin thickness, and curing time on the micro-hardness of bulk-fill resin composites

Background: Bulk-fill resin composite has been introduced, their manufacturers claimed that they can be applied in bulks of 4mm, without necessitating a prolonged curing time, or a light curing unit with increased irradiance. Thus this study was conducted to evaluate the effect of resin thickness, and curing time on the micro-hardness of two bulk -fill resin composites; Tetric Evo-Ceram [TE], and X-trafil [XF]. Material and Methods: 120 cylindrical specimens were prepared, and divided into 24 groups (n=5/group), representing the two bulk-fill resin composites, three different material thicknesses (2, 3 and 4 mm) and the four curing times used in the study (10, 20, 40, and 60 seconds). The specimens were light-cured from the top surface only. Specimens were stored in light proof containers in complete darkness at 37°C for 24 hours. Micro-hardness test was conducted on both top and bottom surfaces using Vickers micro-hardness tester with 500 g load and a dwell time of 15 seconds. Data were statistically analyzed by Four-way ANOVA of Variance. The significance level was set at P ≤ 0.05. Pearson Correlation used to determine significant correlations between mean micro-hardness (top) and (bottom) surfaces. Results: Four way-ANOVA shows that different tested materials produce a statistically significant effect on mean micro-hardness (VHN) at p ≤0.001, while thickness, curing time, and surface revealed statistically non significant effect on mean micro-hardness (VHN) at p ≥0.05. [XF] (92.01±3.15 VHN) showed statistically significant higher mean micro-hardness than [TE] (54.13±4.96 VHN). Pearson Correlation revealed that there was a significant direct correlation between micro-hardness (bottom) and mean micro-hardness (top) (mm), r = 0.985, p (2-tailed) ≤0.001. Conclusions: Within the limitations of this study, the bulk-fill resin composites used in this study can be placed and cured properly in the 4 mm bul

The effect of different insertion techniques on the depth of cure and vickers surface micro-hardness of two bulk-fill resin composite materials

The aim of this study was to evaluate the Vickers surface micro-hardness and the depth of cure of two bulk-fill resin composites and one incremental-fill resin composite. Two Bulk-fill dental resin composites (X-tra Fil, Voco; Sonic-FillTM 2, Kerr Corporation) and an incremental-fill dental resin composite (Filtek™ Z250 XT, 3M ESPE) were used. Sixty cylindrical specimens of 4 mm thickness were prepared using split Teflon moulds. Specimens were divided into six groups (n=10) according to the type of the material used and according to the insertion technique applied (bulk or incremental). Prepared specimens were stored dry in complete darkness at 37°C for 24 hours. All specimens were tested for their Vickers surface micro-hardness, on their top and bottom surfaces. The depth of cure of the tested specimens was assessed by calculating the hardness ratio for each specimen. The Vickers surface micro-hardness and depth of cure data were analyzed for normality using Kolmogorov-Smirnov and Shapiro-Wilk tests. Independent sample-t test was used to compare between two groups while One-way ANOVA was used to compare between more than two groups. Significant difference in the Vickers surface micro-hardness and depth of cure values was demonstrated among the tested materials (P<0.0001). X-tra Fil recorded the highest mean Vickers micro-hardness value (94.05±1.05). Bulk-fill dental resin composites X-tra Fil and Sonic-Fill showed 0.980±0.005 and 0.921±0.020 depth of cure values (bottom/top hardness ratio) respectively while Z250 XT recorded 0.776±0.141. X-tra Fil showed highest Vickers surface micro-hardness values on both top and bottom surfaces, whether inserted in increments or bulk. Both bulk-fill resin composites showed higher depth of cure for both insertion techniques

Thermal stability of laser treated die material for semi-solid metal forming

This paper presents laser surface modification work performed to improve the lifetime of die materials. Die material AISI H13, with typical hardness in the range of 42 to 48 HRC, offers high wear and corrosion resistance. However the cyclic high temperature conditions along with exposure to high viscosity molten metal in semi-solid forming cause the die to wear and crack with resultant shortened die lifetime. In this study, the thermal stability of die material at elevated temperature was investigated through micro-hardness testing and a metallographic study. AISI H13 samples were laser glazed using CO2 continuous wave mode laser with 10.6 μm wavelength. Samples were attached to a specially designed rotating chuck to enable it to be rotated at speeds up to 1500 rpm and allow flat surface glazing to take place. The micro-hardness was measured for as-glazed samples and annealed samples which were held at temperatures ranging from 550oC to 800oC with 50oC intervals. The metallographic study conducted examined the formation of three zones at different depths which were the glazed zone, the heat affected zone and the substrate. As a result of rapid heating and cooling from the laser glazing process, a metallic glass layer was developed which exhibited an average micro-hardness of 900 HV when exposed to 3.34E+10 W/m2 laser irradiance within a range of 0.0011 to 0.0018 s exposure time. Crystallization in glazed zone increased as the annealing temperature increased. As the annealing temperature reached above approximately 600oC, the micro-hardness decreased to approximately 600 HV (equivalent to approx. 54 HRC) due to local crystallization. These findings show potential direct application of glazed dies for non-ferrous semi-solid forming and the requirement for thermal barrier protection for application at higher temperatures

Porosity and Micro-Hardness of Shrouded Plasma Sprayed Titanium Coatings

Titanium and its alloys are often used as key materials for corrosion protection. A promising approach to optimize both mechanical properties and corrosion resistance is the use of coating technologies. In this paper, shrouded plasma spray was used as a useful technology to produce low oxide containing titanium coatings. A solid shroud was used to plasma spray titanium coatings to reduce the oxide content. The titanium coatings were assessed by optical microscope, scanning electron microscopy and Vickers microhardness testing. The results showed that the shrouded titanium coatings exhibited an enhanced microstructure. The presence of the shroud and shroud gas flow led to a significant reduction in coating porosity because the reduction in air entrainment with the shroud resulted in better heating of the particles. The shrouded titanium coatings had a lower value of Vickers microhardness and a relative lower standard deviation than the air plasma sprayed titanium coatings

Porosity and Micro-Hardness of Shrouded Plasma Sprayed Titanium Coatings

Titanium and its alloys are often used as key materials for corrosion protection. A promising approach to optimize both mechanical properties and corrosion resistance is the use of coating technologies. In this paper, shrouded plasma spray was used as a useful technology to produce low oxide containing titanium coatings. A solid shroud was used to plasma spray titanium coatings to reduce the oxide content. The titanium coatings were assessed by optical microscope, scanning electron microscopy and Vickers microhardness testing. The results showed that the shrouded titanium coatings exhibited an enhanced microstructure. The presence of the shroud and shroud gas flow led to a significant reduction in coating porosity because the reduction in air entrainment with the shroud resulted in better heating of the particles. The shrouded titanium coatings had a lower value of Vickers microhardness and a relative lower standard deviation than the air plasma sprayed titanium coatings

Residual stress relaxation and surface hardness of a 2024-t351 aluminium alloy

For design it is generally important to consider the residual stress relaxation. In the study for this contribution, 2024 T351 Aluminium alloy specimens were shot peened at three different shot peening intensities, followed by fatigue tests for two loads. Fatigue tests were divided into two stages. The residual stresses and micro-hardness were measured at initial and after each cyclic load for the three shot peening intensities and the two aforementioned sets of loads. The results showed that the residual stresses and micro-hardness of the specimens were decreased. Moreover, the relaxation depended on the fatigue load amplitude. Residual stress relaxation reached 54% of the initial residual stress while the micro-hardness relaxation reached 39% of the initial micro-hardness. Most of the residual stress relaxation occurred during the first cycle. The relaxation of the initial residual stress is severe when there is low shot peening intensity and high applied load, and the reduction of the micro-hardness is depending on the residual stress relaxation

Response of A356 to warm rotary forming and subsequent T6 heat treatment

The through-process microstructural effects in A356 subjected to rotary forming at elevated temperatures have been investigated. Macro and micro-hardness testing have been used extensively to track changes in the material from the as-cast state to as-formed, and T6 heat treated. Targeted thermal treatments have been used to isolate the effects of mechanical deformation through comparative measurements. These measurements include macro and micro hardness measurements, Energy-dispersive X-ray analysis and examination of eutectic-Si particle size and morphology. The results indicate that the as-cast material is stable up to approximately 144{\deg}C, with the rotary formed material exhibiting decreased macrohardness in-line with the time spent at elevated temperature. Post heat treatment, there was a significant decrease in hardness with increased levels of deformation. Results indicate that precipitation hardening is not appreciably affected by rotary forming, and the principal cause for the drop in hardness with deformation is due to the condition of Al-Si eutectic phase.Comment: 26 pages, 13 figure

Tribocorrosion Properties of PEO Coatings Produced on AZ91 Magnesium Alloy with Silicate- or Phosphate-Based Electrolytes

In this work, the tribocorrosion behavior of plasma electrolytic oxidation (PEO)-coated AZ91 samples was studied. In particular, two different coatings were produced and compared. One was obtained with an alkaline electrolyte containing sodium phosphate, whereas the other one was produced with an alkaline electrolyte containing sodium silicate. The coatings were characterized with SEM-EDS and XRD techniques, and after the tribocorrosion tests, the wear scars were analyzed with SEM-EDS. The tribocorrosion behavior was evaluated measuring the OCP during a pin on disk test performed in an aggressive environment. Moreover, potentiodynamic polarization and electrochemical impedance spectroscopy tests were performed, to evaluate the corrosion resistance of the different samples in the absence of wear phenomena. The behavior of all the PEO-treated specimens was compared with the one of the untreated sample. A remarkable increase in the tribocorrosion performances after the PEO treatments was observed. Moreover, the samples obtained with the electrolyte containing silicates showed higher tribocorrosion performances