Beam-Size Invariant Spectropolarimeters Using Gap-Plasmon Metasurfaces

Metasurfaces enable exceptional control over the light with surface-confined planar components, offering the fascinating possibility of very dense integration and miniaturization in photonics. Here, we design, fabricate and experimentally demonstrate chip-size plasmonic spectropolarimeters for simultaneous polarization state and wavelength determination. Spectropolarimeters, consisting of three gap-plasmon phase-gradient metasurfaces that occupy 120{\deg} circular sectors each, diffract normally incident light to six predesigned directions, whose azimuthal angles are proportional to the light wavelength, while contrasts in the corresponding diffraction intensities provide a direct measure of the incident polarization state through retrieval of the associated Stokes parameters. The proof-of-concept 96-{\mu}m-diameter spectropolarimeter operating in the wavelength range of 750-950nm exhibits the expected polarization selectivity and high angular dispersion. Moreover, we show that, due to the circular-sector design, polarization analysis can be conducted for optical beams of different diameters without prior calibration, demonstrating thereby the beam-size invariant functionality. The proposed spectropolarimeters are compact, cost-effective, robust, and promise high-performance real-time polarization and spectral measurements

Semiconductor Metasurfaces for Surface-enhanced Raman Scattering

Semiconductor-based surface-enhanced Raman spectroscopy (SERS) substrates, as a new frontier in the field of SERS, are hindered by their poor electromagnetic field confinement, and weak light-matter interaction. Metasurfaces, a class of 2D artificial materials based on the electromagnetic design of nanophotonic resonators, enable strong electromagnetic field enhancement and optical absorption engineering for a wide range of semiconductor materials. However, the engineering of semiconductor substrates into metasurfaces for improving SERS activity remains underexplored. Here, we develop an improved SERS metasurface platform that leverages the combination of titanium oxide (TiO2) and the emerging physical concept of optical bound states in the continuum (BICs) to boost the Raman emission. Moreover, fine-tuning of BIC-assisted resonant absorption offers a pathway for maximizing the photoinduced charge transfer effect (PICT) in SERS. We achieve ultrahigh values of BIC-assisted electric field enhancement (|E/E0|^2 ~ 10^3), challenging the preconception of weak electromagnetic (EM) field enhancement on semiconductor SERS substrates. Our BIC-assisted TiO2 metasurface platform offers a new dimension in spectrally-tunable SERS with earth-abundant and bio-compatible semiconductor materials, beyond the traditional plasmonic ones

Trends in Nanophotonics-Enabled Optofluidic Biosensors

Optofluidic sensors integrate photonics with micro/nanofluidics to realize compact devices for the label-free detection of molecules and the real-time monitoring of dynamic surface binding events with high specificity, ultrahigh sensitivity, low detection limit, and multiplexing capability. Nanophotonic structures composed of metallic and/or dielectric building blocks excel at focusing light into ultrasmall volumes, creating enhanced electromagnetic near-fields ideal for amplifying the molecular signal readout. Furthermore, fluidic control on small length scales enables precise tailoring of the spatial overlap between the electromagnetic hotspots and the analytes, boosting light-matter interaction, and can be utilized to integrate advanced functionalities for the pre-treatment of samples in real-world-use cases, such as purification, separation, or dilution. In this review, the authors highlight current trends in nanophotonics-enabled optofluidic biosensors for applications in the life sciences while providing a detailed perspective on how these approaches can synergistically amplify the optical signal readout and achieve real-time dynamic monitoring, which is crucial in biomedical assays and clinical diagnostics

Metasurfaces for Advanced Sensing and Diagnostics

Interest in sensors and their applications is rapidly evolving, mainly driven by the huge demand of technologies whose ultimate purpose is to improve and enhance health and safety. Different electromagnetic technologies have been recently used and achieved good performances. Despite the plethora of literature, limitations are still present: limited response control, narrow bandwidth, and large dimensions. MetaSurfaces, artificial 2D materials with peculiar electromagnetic properties, can help to overcome such issues. In this paper, a generic tool to model, design, and manufacture MetaSurface sensors is developed. First, their properties are evaluated in terms of impedance and constitutive parameters. Then, they are linked to the structure physical dimensions. Finally, the proposed method is applied to realize devices for advanced sensing and medical diagnostic applications: glucose measurements, cancer stage detection, water content recognition, and blood oxygen level analysis. The proposed method paves a new way to realize sensors and control their properties at will. Most importantly, it has great potential to be used for many other practical applications, beyond sensing and diagnostic

CMOS compatible metamaterial absorbers for hyperspectral medium wave infrared imaging and sensing applications

We experimentally demonstrate a CMOS compatible medium wave infrared metal-insulator-metal (MIM) metamaterial absorber structure where for a single dielectric spacer thickness at least 93% absorption is attained for 10 separate bands centred at 3.08, 3.30, 3.53, 3.78, 4.14, 4.40, 4.72, 4.94, 5.33, 5.60 μm. Previous hyperspectral MIM metamaterial absorber designs required that the thickness of the dielectric spacer layer be adjusted in order to attain selective unity absorption across the band of interest thereby increasing complexity and cost. We show that the absorption characteristics of the hyperspectral metamaterial structures are polarization insensitive and invariant for oblique incident angles up to 25° making them suitable for practical implementation in an imaging system. Finally, we also reveal that under TM illumination and at certain oblique incident angles there is an extremely narrowband Fano resonance (Q < 50) between the MIM absorber mode and the surface plasmon polariton mode that could have applications in hazardous/toxic gas identification and biosensing