Development and optimization of zeolite synthesis route from natural koalin for adsorption of dyes

Synthesis of zeolite using kaolin as the main source of alumina and silica has been identified as a novel zeolite production process, which could reduce the cost of using the synthetic reagents and the high energy consumption. A low grade kaolin was used for studying the most suitable synthesis route and operating parameters for producing a high yield and pure phase zeolite. The study adopted the alkaline activation and microwave assisted heating as modification techniques of the conventional hydrothermal synthesis process. Calcination and crystallization proceses were identified as the bottleneck operations within the process. Hence, this study employed 2k factorial design of experiment to study the relationship of metakaolinization temperature of 600 – 800 oC with calcination time of 1 – 5 hours. And that of crystallization time of 9 – 16 hours with aging treatment time of 12 – 36 hours. Central Composite Design (CCD) is used for optimization with axial and center point for factors evaluation towards the responses; yield percent (%) and crystallinity (%) for crystallization process. Based on the Response Surface Methodology (RSM), with desirability value of 98.67 %, the significant parametric aging condition is 27 hours and crystallization time is 9 hours were suggested to yield an optimum product for 80.47 yield percent and 76.92 crystallinity. Three confirmation runs were performed based on the suggested optimum parameter and the calculated error value was found to be below 10 %. The synthesized zeolite-A from the confirmation runs was characterized through XRD. The results were then corroborated with the analytical results from SEM, BET and FTIR. The activity of the synthesized zeolite A was confirmed by a structural refinement analysis, that identified the product as a member of the cubic crystalline systems, belonging to a Fm3c space group with lattice cubic structure values where

CleanTX Analysis on the Smart Grid

The utility industry in the United States has an opportunity to revolutionize its electric grid system by utilizing emerging software, hardware and wireless technologies and renewable energy sources. As electricity generation in the U.S. increases by over 30% from today’s generation of 4,100 Terawatt hours per year to a production of 5,400 Terawatt hours per year by 2030, a new type of grid is necessary to ensure reliable and quality power. The projected U.S. population increase and economic growth will require a grid that can transmit and distribute significantly more power than it does today. Known as a Smart Grid, this system enables two- way transmission of electrons and information to create a demand-response system that will optimize electricity delivery to consumers. This paper outlines the issues with the current grid infrastructure, discusses the economic advantages of the Smart Grid for both consumers and utilities, and examines the emerging technologies that will enable cleaner, more efficient and cost- effective power transmission and consumption.IC2 Institut

Implementing Operations Support Systems in E-Health Based Systems

Information and communication technologies have been introduced in different dimensions of the health care. e-Health is the use of advanced communications technologies such as the Internet, portable, wireless and other sophisticated devices to support health care delivery and education. It has the potentials of improving the efficiency of health care delivery globally. With the increasing demand for information at the point of care, health care providers could explore the advances provided by mobile technologies and the increasing capabilities, compactness and pervasiveness of computing devices to adopt operations supports systems (OSS) in e-Health based systems in order to provide efficient services and enhance their performances. In this paper, we present, the development and implementation of operations supports in e- Health based systems. The system promises to deliver greater productivity for health care practitioner

Lessons Learned and Next Steps in Energy Efficiency Measurement and Attribution: Energy Savings, Net to Gross, Non-Energy Benefits, and Persistence of Energy Efficiency Behavior

This white paper examines four topics addressing evaluation, measurement, and attribution of direct and indirect effects to energy efficiency and behavioral programs: Estimates of program savings (gross); Net savings derivation through free ridership / net to gross analyses; Indirect non-energy benefits / impacts (e.g., comfort, convenience, emissions, jobs); and, Persistence of savings

InterCloud: Utility-Oriented Federation of Cloud Computing Environments for Scaling of Application Services

Cloud computing providers have setup several data centers at different geographical locations over the Internet in order to optimally serve needs of their customers around the world. However, existing systems do not support mechanisms and policies for dynamically coordinating load distribution among different Cloud-based data centers in order to determine optimal location for hosting application services to achieve reasonable QoS levels. Further, the Cloud computing providers are unable to predict geographic distribution of users consuming their services, hence the load coordination must happen automatically, and distribution of services must change in response to changes in the load. To counter this problem, we advocate creation of federated Cloud computing environment (InterCloud) that facilitates just-in-time, opportunistic, and scalable provisioning of application services, consistently achieving QoS targets under variable workload, resource and network conditions. The overall goal is to create a computing environment that supports dynamic expansion or contraction of capabilities (VMs, services, storage, and database) for handling sudden variations in service demands. This paper presents vision, challenges, and architectural elements of InterCloud for utility-oriented federation of Cloud computing environments. The proposed InterCloud environment supports scaling of applications across multiple vendor clouds. We have validated our approach by conducting a set of rigorous performance evaluation study using the CloudSim toolkit. The results demonstrate that federated Cloud computing model has immense potential as it offers significant performance gains as regards to response time and cost saving under dynamic workload scenarios.Comment: 20 pages, 4 figures, 3 tables, conference pape

VoIP Regulation in Canada

The CRTC recently released Regulatory Framework for Voice Communication Services using Internet Protocol (Decision 2005-28), Telecom Decision CRTC 2005-28, setting out the details of the appropriate regulatory regime applicable to the provision of VoIP services. We present a brief overview of Decision 2005-28, we then consider the positions of incumbents and competitors, and finally we comment on the above interventions in light of the economic theory of regulation and the theory of strategic competition. We conclude that the predominant model underlying the positions not only of the CRTC but also of the parties involved, including the firms themselves, both the incumbents and the new entrants, and their respective business consultants, do not stand the test of modern economic theory. Le CRTC a récemment publié la décision Cadre de réglementation régissant les services de communication vocale sur protocole Internet (Décision 2005-28) dans laquelle il fixe les paramètres du régime de réglementation qui régira la fourniture des services VoIP. Nous présentons d’abord un aperçu de la Décision 2005-28 ainsi que les positions des entreprises de services locaux titulaires et des nouveaux concurrents. Finalement, nous commentons ces interventions à la lumière de la théorie économique de la réglementation et de la théorie de la concurrence stratégique. Nous concluons que le modèle dominant sur lequel s’appuient non seulement la position du CRTC, mais également celles des parties intéressées, y compris les entreprises elles-mêmes, les entreprises de services locaux titulaires et les nouveaux concurrents, et leurs conseillers d’affaire, ne résiste pas à l’analyse économique moderne.regulation, strategic competition, telecommunications, VoIP, concurrence stratégique, réglementation, télécommunication VoIP