Casimir force calculations near the insulator-conductor transition in gold thin films

We present theoretical calculations of the Casimir force for Au thin films near the insulator-conductor transition that has been observed experimentally. The dielectric function of the Au thin films is described by the Drude-Smith model. The parameters needed to model the dielectric function such as the relaxation time, plasma frequency and the backscattering constant depend on the thickness of the film. The Casimir force decreases as the film thickness decreases until it reaches a minimum after which the force increases again. The minimum of the force coincides with the critical film thickness where a percolation conductor-insulator occurs.Comment: 5 figures, 1 tabl

Direct Experimental Evidence of the Statistical Nature of the Electron Gas in Superconducting Films

In an Nb film an alternate electrical current is partitioned at a Y-shaped obstacle into two splitted beams. The intensity-fluctuation correlation of the two beams (cross-correlation) and the intensity- fluctuation correlation of one beam (auto-correlation) are measured within a low-frequency bandwidth as a function of the incident beam intensity, at temperatures T above or below the temperature Tc of the superconductive transition. The results of these measurements reveal the statistical nature of the electron gas in the normal film and in the superconducting film. The conceptual scheme of the present experiment is a version of the Hanbury Brown and Twiss (HBT) experiment, here adopted for a gas of particles in a solid

Progress towards Bell-type polarization experiment with thermal neutrons

Experimental tests of Bell-type inequalities distinguishing between quantum mechanics and local realistic theories remain of considerable interest if performed on massive particles, for which no conclusive result has yet been obtained. Only two-particle experiments may specifically test the concept of spatial nonlocality in quantum theory, whereas single-particle experiments may generally test the concept of quantum noncontextuality. Here we have performed the first Bell-type experiment with a beam of thermal-neutron pairs in the singlet state of spin, as originally suggested by J. S. Bell. These measurements confirm the quantum-theoretical predictions, in agreement with the results of the well-known polarization experiments carried out on optical photons years ago

Casimir torque between nanostructured plates

We investigate in detail the Casimir torque induced by quantum vacuum fluctuations between two nanostructured plates. Our calculations are based on the scattering approach and take into account the coupling between different modes induced by the shape of the surface which are neglected in any sort of proximity approximation or effective medium approach. We then present an experimental setup aiming at measuring this torque.Comment: 7 pages, 7 figure

Corrosion Inhibition of AA2024-T3 by Vanadates

The speciation of vanadate solutions and the resultinginhibition of oxygen reduction and corrosion of AA2024-T3 wereinvestigated. 51V NMR is very useful for assessing vanadatespeciation. Clear metavanadate solutions contain nodecavanadate, which forms whenever the pH was decreased by theaddition of acid. Orange decavanadate solutions contain nomonovanadate, even when the pH is adjusted to high values.Monovanadate is a potent inhibitor in contrast to decavanadate. Inhibition by monovanadate seems to result from an adsorptionmechanism rather than reduction. Monovanadate effectivelyprotects S phase particles. Aging of high-pH decavanadatesolutions does not improve the inhibition performance or resultin complete depolymerization of the decavanadate

Rotational Excitation Spectroscopy with the STM through Molecular Resonances

We investigate the rotational properties of molecular hydrogen and its isotopes physisorbed on the surfaces of graphene and hexagonal boron nitride ($h$-BN), grown on Ni(111), Ru(0001), and Rh(111), using rotational excitation spectroscopy (RES) with the scanning tunneling microscope. The rotational thresholds are in good agreement with $\Delta J=2$ transitions of freely spinning para-H$_2$ and ortho-D$_2$ molecules. The line shape variations in RES for H$_2$ among the different surfaces can be traced back and naturally explained by a resonance mediated tunneling mechanism. RES data for H$_2$/$h$-BN/Rh(111) suggests a local intrinsic gating on this surface due to lateral variations in the surface potential. An RES inspection of H$_2$, HD, and D$_2$ mixtures finally points to a multi molecule excitation, since either of the three $J=0\rightarrow2$ rotational transitions are simultaneously present, irrespective of where the spectra were recorded in the mixed monolayer

Large temperature dependence of the Casimir force at the metal-insulator transition

The dependence of the Casimir force on material properties is important for both future applications and to gain further insight on its fundamental aspects. Here we derive a general theory of the Casimir force for low-conducting compounds, or poor metals. For distances in the micrometer range, a large variety of such materials is described by universal equations containing a few parameters: the effective plasma frequency, dissipation rate of the free carriers, and electric permittivity in the infrared range. This theory can also describe inhomogeneous composite materials containing small regions with different conductivity. The Casimir force for mechanical systems involving samples made with compounds that have a metal-insulator transition shows an abrupt large temperature dependence of the Casimir force within the transition region, where metallic and dielectric phases coexist.Comment: 23 pages, 9 figure