Physical-layer Network Coding for Cooperative Wireless Networks

As a newly-emerged paradigm in the networking techniques, physical-layer network coding (PNC) [1, 5] takes advantage of the superimposition of the electromagnetic waves, and embraces the interference which was typically deemed as harmful, by performing exclusive-or mapping. Therefore, the spectral efficiency is utilized, which in turn boosts the network throughput. In the classical 2-way relay channel (2-WRC), PNC only spends two channel uses for the bi-directional data exchange. However, one challenge for such a paradigm is that the singular fading states in the uplink of 2-WRC, might result in ambiguity for decoding the network coded symbol. One major focus of this thesis is to address the fading issue for PNC in the 2-WRC. Another fundamental challenge for PNC is to extend the PNC from the 2-WRC to a multi-user network such as the multi-way relay channel (M-WRC) or the hierarchical wireless network (HWN). To tackle these two fundamental challenges of PNC, several solutions are proposed in this thesis, which are summarized as follows: First, we introduce two efficient fading correction strategies, i.e., the rotationally-invariant coded modulation and the soft-bit correction. Second, a novel multilevel coded linear PNC scheme with extended mapping for the Rayleigh fading 2-WRC is proposed. Third, we design a new type of linear PNC for the Rayleigh fading 2-WRC, based on rings. We refer to such design as linear PNC over the hybrid finite ring. Fourth, we redesign PNC for the HWN, which facilitates the multi-user data exchange. To combat the co-channel interference introduced by multi-user data exchange, two efficient interference exploitation strategies based on network coding are proposed: 1) PNC with joint decoding; and 2) analogue network coding with interference-aware maximum likelihood detection. Finally, we propose a multilevel coded LPNC for the data exchange in the M-WRC

Antioxidant and DPPH-Scavenging Activities of Compounds and Ethanolic Extract of the Leaf and Twigs of Caesalpinia bonduc L. Roxb.

Antioxidant effects of ethanolic extract of Caesalpinia bonduc and its isolated bioactive compounds were evaluated in vitro. The compounds included two new cassanediterpenes, 1α,7α-diacetoxy-5α,6β-dihydroxyl-cass-14(15)-epoxy-16,12-olide (1)and 12α-ethoxyl-1α,14β-diacetoxy-2α,5α-dihydroxyl cass-13(15)-en-16,12-olide(2); and others, bonducellin (3), 7,4’-dihydroxy-3,11-dehydrohomoisoflavanone (4), daucosterol (5), luteolin (6), quercetin-3-methyl ether (7) and kaempferol-3-O-α-L-rhamnopyranosyl-(1Ç2)-β-D-xylopyranoside (8). The antioxidant properties of the extract and compounds were assessed by the measurement of the total phenolic content, ascorbic acid content, total antioxidant capacity and 1-1-diphenyl-2-picryl hydrazyl (DPPH) and hydrogen peroxide radicals scavenging activities.Compounds 3, 6, 7 and ethanolic extract had DPPH scavenging activities with IC50 values of 186, 75, 17 and 102 μg/ml respectively when compared to vitamin C with 15 μg/ml. On the other hand, no significant results were obtained for hydrogen peroxide radical. In addition, compound 7 has the highest phenolic content of 0.81±0.01 mg/ml of gallic acid equivalent while compound 8 showed the highest total antioxidant capacity with 254.31±3.54 and 199.82±2.78 μg/ml gallic and ascorbic acid equivalent respectively. Compound 4 and ethanolic extract showed a high ascorbic acid content of 2.26±0.01 and 6.78±0.03 mg/ml respectively.The results obtained showed the antioxidant activity of the ethanolic extract of C. bonduc and deduced that this activity was mediated by its isolated bioactive compounds