Second-Order Occlusion-Aware Volumetric Radiance Caching

We present a second-order gradient analysis of light transport in participating media and use this to develop an improved radiance caching algorithm for volumetric light transport. We adaptively sample and interpolate radiance from sparse points in the medium using a second-order Hessian-based error metric to determine when interpolation is appropriate. We derive our metric from each point's incoming light field, computed by using a proxy triangulation-based representation of the radiance reflected by the surrounding medium and geometry. We use this representation to efficiently compute the first- and second-order derivatives of the radiance at the cache points while accounting for occlusion changes. We also propose a self-contained two-dimensional model for light transport in media and use it to validate and analyze our approach, demonstrating that our method outperforms previous radiance caching algorithms both in terms of accurate derivative estimates and final radiance extrapolation. We generalize these findings to practical three-dimensional scenarios, where we show improved results while reducing computation time by up to 30\% compared to previous work

Efficient Methods for Computational Light Transport

En esta tesis presentamos contribuciones sobre distintos retos computacionales relacionados con transporte de luz. Los algoritmos que utilizan información sobre el transporte de luz están presentes en muchas aplicaciones de hoy en día, desde la generación de efectos visuales, a la detección de objetos en tiempo real. La luz es una valiosa fuente de información que nos permite entender y representar nuestro entorno, pero obtener y procesar esta información presenta muchos desafíos debido a la complejidad de las interacciones entre la luz y la materia. Esta tesis aporta contribuciones en este tema desde dos puntos de vista diferentes: algoritmos en estado estacionario, en los que se asume que la velocidad de la luz es infinita; y algoritmos en estado transitorio, que tratan la luz no solo en el dominio espacial, sino también en el temporal. Nuestras contribuciones en algoritmos estacionarios abordan problemas tanto en renderizado offline como en tiempo real. Nos enfocamos en la reducción de varianza para métodos offline,proponiendo un nuevo método para renderizado eficiente de medios participativos. En renderizado en tiempo real, abordamos las limitacionesde consumo de batería en dispositivos móviles proponiendo un sistema de renderizado que incrementa la eficiencia energética en aplicaciones gráficas en tiempo real. En el transporte de luz transitorio, formalizamos la simulación de este tipo transporte en este nuevo dominio, y presentamos nuevos algoritmos y métodos para muestreo eficiente para render transitorio. Finalmente, demostramos la utilidad de generar datos en este dominio, presentando un nuevo método para corregir interferencia multi-caminos en camaras Timeof- Flight, un problema patológico en el procesamiento de imágenes transitorias.n this thesis we present contributions to different challenges of computational light transport. Light transport algorithms are present in many modern applications, from image generation for visual effects to real-time object detection. Light is a rich source of information that allows us to understand and represent our surroundings, but obtaining and processing this information presents many challenges due to its complex interactions with matter. This thesis provides advances in this subject from two different perspectives: steady-state algorithms, where the speed of light is assumed infinite, and transient-state algorithms, which deal with light as it travels not only through space but also time. Our steady-state contributions address problems in both offline and real-time rendering. We target variance reduction in offline rendering by proposing a new efficient method for participating media rendering. In real-time rendering, we target energy constraints of mobile devices by proposing a power-efficient rendering framework for real-time graphics applications. In transient-state we first formalize light transport simulation under this domain, and present new efficient sampling methods and algorithms for transient rendering. We finally demonstrate the potential of simulated data to correct multipath interference in Time-of-Flight cameras, one of the pathological problems in transient imaging.<br /

Isophotonic reactor for the precise determination of quantum yields in gas, liquid, and multi-phase photoreactions

Photocatalytic processes are an emerging field with a multitude of potential applications ranging from waste and wastewater treatment over fine chemical production to artificial photosynthesis. Knowing the quantum yield in a photoreaction is thereby essential to both, the selection of suitable photocatalysts and the design of optimized photoreactors. Nevertheless, the precise determination of quantum yields as function of the operating conditions is still a challenge without standardized and reliable procedures and apparatuses. Herein a novel approach for the accurate determination of quantum yields based on a tailored, 3D-printable photoreactor and 3D optical modelling is reported. Besides wavelength, temperature, and reactant concentration control, the unique optical design of an isophotonic reactor enables the control of the local volumetric rate of photon absorption to be homogeneous throughout the reaction volume. The validity of the approach is demonstrated by determining the quantum yield of the standard potassium ferrioxalate actinometer. Further, the adaptability to any gas, liquid, or multi-phase photoreaction is outlined by showcasing the ability of the approach with an exemplary aerogel-supported titania-based methanol reforming photocatalyst. The revealed subtlety and complex nature of the quantum yield in the methanol reforming system highlights the need for meticulous analysis and standardization of the determination of quantum yields and thereby underlines the value of the proposed approach. Software tools and print files provided alongside the publication facilitate adaptation and further development of the approach by researchers in the field