29,164 research outputs found
Metaphors of London fog, smoke and mist in Victorian and Edwardian Art and Literature
Julian Wolfreys has argued that after 1850 writers employed stock images of the city without allowing them to transform their texts. This thesis argues, on the contrary, that metaphorical uses of London fog were complex and subtle during the Victorian and Edwardian periods, at least until 1914. Fog represented, in particular, formlessness and the dissolution of boundaries. Examining the idea of fog in literature, verse, newspaper accounts and journal articles, as well as in the visual arts, as part of a common discourse about London and the state of its inhabitants, this thesis charts how the metaphorical appropriation of this idea changed over time. Four of Dickens's novels are used to track his use of fog as part of a discourse of the natural and unnatural in individual and society, identifying it with London in progressively more negative terms. Visual representations of fog by Constable, Turner, Whistler, Monet, Markino, O'Connor, Roberts and Wyllie and Coburn showed an increasing readiness to engage with this discourse. Social tensions in the city in the 1880s were articulated in art as well as in fiction. Authors like Hay and Barr showed the destruction of London by its fog because of its inhabitants' supposed degeneracy. As the social threat receded, apocalyptic scenarios gave way to a more optimistic view in the work of Owen and others. Henry James used fog as a metaphorical representation of the boundaries of gendered behaviour in public, and the problems faced by women who crossed them. The dissertation also examines fog and individual transgression, in novels and short stories by Lowndes, Stevenson, Conan Doyle and Joseph Conrad. After 1914, fog was no more than a crude signifier of Victorian London in literature, film and, later, television, deployed as a cliche instead of the subtle metaphorical idea discussed in this thesis
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Meaning-Making Practices of Emergent ArabicâEnglish Bilingual Kindergarten Children in Cairo
The number of British Schools in the Middle East and North Africa (MENA) region is growing. The National Curriculum of England is used by an increasing number of such schools. As well as exporting a culturally-specific curriculum, these schools usually adopt an ideology of monolingualism, thus potentially limiting communication for emergent bilinguals and failing to acknowledge the multiple ways of meaning-making.
Current studies of translanguaging are moving the focus to multimodal forms of communication as a resource for thinking and communicating (GarcĂa and Wei 2014, Wei 2018). Building on the work of Kress (1997, 2010) I explore pre-school emergent bilingualsâ wider signifying practices and create an analytical framework, which I call MMTL (multimodal translanguaging), used as a lens to illustrate meaning-making.
Valley Hill in Cairo, Egypt is a British school which encourages âEnglish-onlyâ as the medium of instruction in the kindergarten. Using a case study methodology, this research explores the meaning-making practices of eight emergent bilingual children aged 3â4 during child-initiated play, later reduced to four in the thesis to provide a detailed multimodal analysis. The principal aim is to explore their speech, gaze, gesture, and their engagement (layout/position) with artefacts during play.
The findings of this study suggest that although there is an âEnglish-onlyâ approach, these young emergent bilingual children are meaning-making in a variety of ways. Children are translanguaging but it is never in isolation from other modes of communication. Emergent bilinguals use a range of modes to mediate their understanding and communication with others. They use gesture, gaze, and artefacts alongside translingual practices to move meaning across to more accessible modes, enabling communication and understanding. The implications for schools should be to embrace such hybrid practices and for teachers to be more responsive to young childrenâs meaning-making to enable learning
3D numerical simulation of slope-flexible system interaction using a mixed FEM-SPH model
Flexible membranes are light structures anchored to the ground that protect infrastructures or dwellings from rock or soil sliding. One alternative to design these structures is by using numerical simulations. However, very few models were found until date and most of them are in 2D and do not include all their components. This paper presents the development of a numerical model combining Finite Element Modelling (FEM) with Smooth Particle Hydrodynamics (SPH) formulation. Both cylindrical and spherical failure of the slope were simulated. One reference geometry of the slope was designed and a total of 21 slip circles were calculated considering different soil parameters, phreatic level position and drainage solutions. Four case studies were extracted from these scenarios and simulated using different dimensions of the components of the system. As a validation model, an experimental test that imitates the soil detachment and its retention by the steel membrane was successfully reproduced
Structure and adsorption properties of gas-ionic liquid interfaces
Supported ionic liquids are a diverse class of materials that have been considered
as a promising approach to design new surface properties within solids for gas
adsorption and separation applications. In these materials, the surface morphology and
composition of a porous solid are modified by depositing ionic liquid. The resulting
materials exhibit a unique combination of structural and gas adsorption properties
arising from both components, the support, and the liquid. Naturally, theoretical and
experimental studies devoted to understanding the underlying principles of exhibited
interfacial properties have been an intense area of research. However, a complete
understanding of the interplay between interfacial gas-liquid and liquid-solid
interactions as well as molecular details of these processes remains elusive.
The proposed problem is challenging and in this thesis, it is approached from
two different perspectives applying computational and experimental techniques. In
particular, molecular dynamics simulations are used to model gas adsorption in films
of ionic liquids on a molecular level. A detailed description of the modeled systems is
possible if the interfacial and bulk properties of ionic liquid films are separated. In this
study, we use a unique method that recognizes the interfacial and bulk structures of
ionic liquids and distinguishes gas adsorption from gas solubility. By combining
classical nitrogen sorption experiments with a mean-field theory, we study how liquid-solid interactions influence the adsorption of ionic liquids on the surface of the porous
support.
The developed approach was applied to a range of ionic liquids that feature
different interaction behavior with gas and porous support. Using molecular
simulations with interfacial analysis, it was discovered that gas adsorption capacity
can be directly related to gas solubility data, allowing the development of a predictive
model for the gas adsorption performance of ionic liquid films. Furthermore, it was
found that this CO2 adsorption on the surface of ionic liquid films is determined by the
specific arrangement of cations and anions on the surface. A particularly important
result is that, for the first time, a quantitative relation between these structural and
adsorption properties of different ionic liquid films has been established. This link
between two types of properties determines design principles for supported ionic
liquids.
However, the proposed predictive model and design principles rely on the
assumption that the ionic liquid is uniformly distributed on the surface of the porous
support. To test how ionic liquids behave under confinement, nitrogen physisorption
experiments were conducted for microâ and mesopore analysis of supported ionic
liquid materials. In conjunction with mean-field density functional theory applied to
the lattice gas and pore models, we revealed different scenarios for the pore-filling
mechanism depending on the strength of the liquid-solid interactions.
In this thesis, a combination of computational and experimental studies provides
a framework for the characterization of complex interfacial gas-liquid and liquid-solid
processes. It is shown that interfacial analysis is a powerful tool for studying
molecular-level interactions between different phases. Finally, nitrogen sorption
experiments were effectively used to obtain information on the structure of supported
ionic liquids
Probing the Intergalactic medium properties using X-ray absorption from multiple tracers
Based on the Lambda Cold Dark Matter concordance cosmological model (ÎCDM), the majority of baryons exist in the Intergalactic medium (IGM). It is extremely challenging to observationally trace the IGM, especially at higher temperatures and low densities. Post reionisation, the vast majority of hydrogen and helium is ionized in the IGM and therefore, the observation of metals is essential for parametrising the IGM properties.
My hypothesis is that there is significant absorption in the diffuse highly ionisied IGM and that this IGM column density increases with redshift. I use X-ray absorption in multiple tracers which yields information on the total absorbing column density of the matter between the observer and the source. Clear IGM detections require tracer sources that are bright, distant, and common enough to provide a good statistical sample of IGM lines of sight (LOS). To more accurately isolate any IGM contribution to spectral absorption, I examine each tracer host type to realistically model it, in addition to using appropriate intrinsic continuum curvature models. I test the robustness of the result from a number of perspectives. I examine the impact of the key underlying assumptions that affect the column density calculations including metallicity, ionisation and location of absorption. I look for any evidence of evolution in the parameters.
In Chapters 2, 3, 4 and 5, I use gamma-ray bursts (GRBs), blazars and quasars (QSOs) to estimate IGM baryon column densities, metallicity, temperature, ionisation parameters and redshift distributions. My results for each tracer
are presented in each of the respective chapters and collectively in Chapter 5 which includes comparative analysis.
In conclusion, through the work in this thesis I demonstrate a consistent case for strong X-ray absorption in the IGM on the LOS to three different tracer types and that it is related to redshift. The results are consistent with the ÎCDM model for density, temperature and metallicity. Given these results, I would recommend that studies of distant objects should not follow the convention of assuming all X-ray absorption in excess of our Galaxy is attributed to the host galaxy, that the host is neutral and has solar metallicity. Instead, particularly at higher redshift, absorption in the IGM should be accounted for to give more accurate results for the tracer host properties
Innovation systemsâ response to changes in the institutional impulse: Analysis of the evolution of the European energy innovation system from FP7 to H2020
This study addresses how the institutional impulse developed by the European Union influenced the evolution of the European energy innovation system. Considering the contributing role of innovation systems in the development of new knowledge and technology, it can be stated that the institutional impulse achieved by the European Union through the research framework programmes creates a network of relations between entities and projects. This enables the exchange of information and expertise, which is considered a key element for innovation development. Previous studies have attempted to determine whether institutional impulse is an essential element in understanding the efficiency of innovation systems and their related research policies. However, their investigations have yielded inconclusive results. Using the CORDIS database of the European Commission, this study aims to fill this gap by assessing the European energy innovation system for two periods (2007â2013 and 2014â2020) through two of its research funding programmesâFP7 and H2020âthereby contributing to the literature in the innovation systems field. Social network analysis has been conducted to examine how changes in the institutional impulse, reflected in the new objectives in the research funding programmes, are associated with changes in the structural and topological properties of the innovation systemsâ underlying networks. The first contribution indicates that the innovation system responds to changes in the goals of funding programmes, as the taxonomy, topology, and structural properties of their underlying networks underwent modifications due to the newly proposed objectives. The second contribution shows that network properties (cohesion and centrality metrics) can explain the efficiency and effectiveness of innovation systems, drawing useful conclusions for policymakers and individual entities. This last contribution also has important policymaking implications, as it provides the basis for understanding how innovation policy goals can be achieved by changing the institutional impulse to direct the innovation system towards these objectives
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Constraints on a potential aerial biosphere on Venus: II. Ultraviolet radiation
Despite the harsh conditions in the atmosphere of Venus, the possibility for an aerial habitable zone exists. A thermal habitable zone is predicted to exist at an altitude range of 62 to 48âŻkm, above which temperatures drop below the lower thermal limit of cell growth and below which temperatures exceed the evaporation temperature. Many biocidal factors must be considered for the complete definition of an aerial habitable zone; in this study we consider the constraint specifically from the perspective of biocidal solar ultraviolet (UV) intensity in the atmosphere. We simulated the penetration of solar ultraviolet and visible light through the atmosphere using a radiative transfer model, to determine the spectral environment (and thus the UV biocidal effect) as a function of altitude in the atmosphere of Venus. At the top of the thermal aerial habitable zone (62âŻkm) the incoming solar irradiance creates a severely challenging UV environment, with extremophiles such as Deinococcus radiodurans expected to be able to endure these UV conditions for approximately 80âŻs. At an altitude of around 59âŻkm the biologically-weighted UV irradiance drops below that calculated for the Archean Earth, and continues to fall with decreasing altitude until at 54âŻkm it is less than that found currently at the surface of Earth. Crucially, longer wavelength photosynthetically active light continues to penetrate to these altitudes and below, resulting in a solar radiation environment in the venusian atmosphere below around 54âŻkm that screens biologically-damaging UV radiation yet permits the process of photosynthesis. Whilst not claiming to suggest the existence of an aerial habitable zone in general, by considering thermal conditions, ionising radiation and the UV flux environment of the venusian cloud deck alone, we define a potential habitable zone that extends from 59âŻkm to 48âŻkm. This region should form the focus of future remote and in situ astrobiological investigations of Venus
Metabolic phenotyping of opioid and psychostimulant addiction: A novel approach for biomarker discovery and biochemical understanding of the disorder.
Despite the progress in characterising the pharmacological profile of drugs of abuse, their precise biochemical impact remains unclear. The metabolome reflects the multifaceted biochemical processes occurring within a biological system. This includes those encoded in the genome but also those arising from environmental/exogenous exposures and interactions between the two. Using metabolomics, the biochemical derangements associated with substance abuse can be determined as the individual transitions from recreational drug to chronic use (dependence). By understanding the biomolecular perturbations along this time course and how they vary across individuals, metabolomics can elucidate biochemical mechanisms of the addiction cycle (dependence/withdrawal/relapse) and predict prognosis (recovery/relapse). In this review, we summarise human and animal metabolomic studies in the field of opioid and psychostimulant addiction. We highlight the importance of metabolomics as a powerful approach for biomarker discovery and its potential to guide personalised pharmacotherapeutic strategies for addiction targeted towards the individual's metabolome
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