18,190 research outputs found
Gas adsorption isotherm, pore size distribution, and free volume fraction of polymer-polymer mixed matrix membranes before and after thermal rearrangement
Producción CientíficaIn this work, CO2 adsorption at 273.15 K and N2 adsorption at 77 K of mixed matrix membranes has been studied, as a method to directly determine their fractional free volume (FFV). These membranes consist of a continuous phase of copoly(o-hydroxyamide)s (HPA) or copoly(o-hydroxyamide-amide)s (PAA) and a relatively highly porous polymer network filler (PPN1). Both the pure copolymers and the mixed matrix membranes (MMMs) have been analyzed before and after a thermal rearrangement (TR) process. The CO2 adsorption results have allowed characterizing the pore size distribution of the studied membranes in the 3–15 Å range, by using the Non-Local Density Functional Theory (NLDFT). Whereas the N2 adsorption has allowed determining the pore size distributions in the range between 20 and 250 Å. The experimental determination of the pore volume and the density allows the direct calculation of the membranes’ free volume fractions, which were in good agreement with the most usual FFV evaluation methods. In addition, part of the pore volume detected by N2 adsorption was associated with defects and poor integration of the membrane components. This correction has allowed us to make a new evaluation of the density of these materials.Gobierno de España (AEI) proyects (PID2019-109403RB-C21/AEI/10.13039/501100011033 y PID2019-109403RB-C22/AEI/10.13039/501100011033)Junta de Castilla y León - EU-FEDER (CL-EI-2021-07, UIC082
Computer program calculates and plots surface area and pore size distribution data
Computer program calculates surface area and pore size distribution of powders, metals, ceramics, and catalysts, and prints and plots the desired data directly. Surface area calculations are based on the gas adsorption technique of Brunauer, Emmett, and Teller, and pore size distribution calculations are based on the gas adsorption technique of Pierce
Gas adsorption in active carbons and the slit-pore model 1 : pure gas adsorption
We describe procedures based on the polydisperse independent ideal slit-pore model, Monte Carlo simulation and density functional theory (a 'slab-DFT') for predicting gas adsorption and adsorption heats in active carbons.A novel feature of this work is the calibration of gas-surface interactions to a high surface area carbon, rather than to a low surface area carbon as in all previous work. Our models are used to predict the adsorption of carbon dioxide, methane, nitrogen, and hydrogen up to 50 bar in several active carbons at a range of near-ambient temperatures based on an analysis of a single 293 K carbon dioxide adsorption isotherm. The results demonstrate that these models are useful for relatively simple gases at near-critical or supercritical temperatures
Optimal design of gas adsorption refrigerators for cryogenic cooling
The design of gas adsorption refrigerators used for cryogenic cooling in the temperature range of 4K to 120K was examined. The functional relationships among the power requirement for the refrigerator, the system mass, the cycle time and the operating conditions were derived. It was found that the precool temperature, the temperature dependent heat capacities and thermal conductivities, and pressure and temperature variations in the compressors have important impacts on the cooling performance. Optimal designs based on a minimum power criterion were performed for four different gas adsorption refrigerators and a multistage system. It is concluded that the estimates of the power required and the system mass are within manageable limits in various spacecraft environments
Pulsed Gas Chromatographic Separation Final Report
Feasibility of separating binary-gas mixtures based on pulsed-mode gas adsorption/desorptio
Adsorption Way of the Loss of Moon's Atmosphere
Theory on gas adsorption by lunar surface to explain loss of lunar atmospher
Modeling of gas adsorption on graphene nanoribbons
We present a theory to study gas molecules adsorption on armchair graphene
nanoribbons (AGNRs) by applying the results of \emph{ab} \emph{initio}
calculations to the single-band tight-binding approximation. In addition, the
effect of edge states on the electronic properties of AGNR is included in the
calculations. Under the assumption that the gas molecules adsorb on the ribbon
sites with uniform probability distribution, the applicability of the method is
examined for finite concentrations of adsorption of several simple gas
molecules (CO, NO, CO, NH) on 10-AGNR. We show that the states
contributed by the adsorbed CO and NO molecules are quite localized near the
center of original band gap and suggest that the charge transport in such
systems cannot be enhanced considerably, while CO and NH molecules
adsorption acts as acceptor and donor, respectively. The results of this theory
at low gas concentration are in good agreement with those obtained by
density-functional theory calculations.Comment: 7 pages, 6 figure
Adsorption of atoms and molecules upon the surface of a single crystal and chemical reactions that take place upon the surface /low energy electron diffraction/ Annual progress report, 1966-1967
Low energy electron diffraction research of chemical interactions of gases with single crystal metal surfaces, and gas adsorption on nickel and tungsten surface
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