Fuels characterization studies

Current analytical techniques used in the characterization of broadened properties fuels are briefly described. Included are liquid chromatography, gas chromatography, and nuclear magnetic resonance spectroscopy. High performance liquid chromatographic ground-type methods development is being approached from several directions, including aromatic fraction standards development and the elimination of standards through removal or partial removal of the alkene and aromatic fractions or through the use of whole fuel refractive index values. More sensitive methods for alkene determinations using an ultraviolet-visible detector are also being pursued. Some of the more successful gas chromatographic physical property determinations for petroleum derived fuels are the distillation curve (simulated distillation), heat of combustion, hydrogen content, API gravity, viscosity, flash point, and (to a lesser extent) freezing point

Future aviation fuels overview

The outlook for aviation fuels through the turn of the century is briefly discussed and the general objectives of the NASA Lewis Alternative Aviation Fuels Research Project are outlined. The NASA program involves the evaluation of potential characteristics of future jet aircraft fuels, the determination of the effects of those fuels on engine and fuel system components, and the development of a component technology to use those fuels

Advanced development: Fuels

The solar thermal fuels and chemicals program at Jet Propulsion Laboratory are described. High technology is developed and applied to displace fossil fuel (oil) use in the production/processing of valuable fuels and chemicals. The technical and economic feasibility is demonstrated to extent that enables the industry to participate and commercialize the product. A representative process, namely Furfural production with a bottoming of acetone, butanol and ethanol, is described. Experimental data from all solar production of furfural is discussed. Estimates are given to show the attractiveness of this process, considering its flexibility to be adaptable to dishes, troughs or central receivers. Peat, lignite and low rank coal processing, heavy oil stripping and innovative technologies for process diagnostics and control are mentioned as examples of current projects under intensive development

Federal Forests and the Renewable Fuel Standard

On December 19, 2007, the President signed into law the Energy Independence and Security Act of 2007 (EISA). This law (PL 110-140) includes an increase in the national Renewable Fuel Standard (RFS) mandating the production of 36 billion gallons of renewable fuels by 2022. Within the total mandate, 21 billion gallons must qualify as advanced biofuels -- fuels made from renewable biomass other than corn starch. There are additional carve-outs for biomass-based diesel and fuels made from cellulosic feedstocks, such as wood, grasses, and agricultural residues. An important component of the RFS is a series of greenhouse gas emissions screens, essential safeguards that ensure renewable fuels will meet minimum verifiable reductions in greenhouse emissions. For renewable fuels (from new facilities) to qualify under the RFS, they must achieve at least a 20 percent reduction in direct and indirect lifecycle emissions compared to equivalent petroleum fuels. Advanced fuels and cellulosic fuels are subject to a 50 percent and 60 percent emissions screen, respectively. Because of these stringent safeguards and the large quantity of fuel mandated, it is paramount that we not rule out potentially important feedstocks without valid reasons. The definition of 'renewable biomass' included in the law, however, does rule out a number of feedstocks, including thinning materials and woody residues from federal forests

Regional Development Perspectives of Production and Utilisation Renewable Fuels in Hungary

The main aim of the present article is to highlight the regional development perspectives of production and utilization renewable energy fuels in Hungary. Due to our model it is possible to examine the relations between the terms mentioned above. In the model area the most significant elements are highlighted in relation to renewable fuels and sustainability. It implies the importance of holistic approach that is crucial in these investigations. Only marginal attention is paid to the regional impacts of renewable fuels. Taking every result into account, this methodologically complex subject is possible to examine from the point of sustainability. Sustainable development can not be grasped easily, but the production and utilization of renewable fuels can be one of the tools to further the practical implementation of regional sustainability

Autoignition of fuels

An autoignition test section and a premixing fuel injector developed to determine the autoignition characteristics of a variety of aircraft fuels are described. Parametric tests to map the ignition delay characteristics of Jet-A fuel were conducted at pressures of 10, 15, 20, 25, and 30 atm, inlet air temperatures up to 900K and fuel-air equivalence ratios of 0.3, 0.5, 0.7, and 1.0. Residence times in the range of 1 to 50 msec were obtained by interchanging spool pieces to create six different mixer/vaporizer lengths (6, 23, 53, 84, 99, and 130 cm) and by testing at two different airflow rates (0.5 and 1.0 kg/sec). The resulting free-stream velocities were in the range 20 to 100 m/sec. As expected, the results indicate that the ignition delay times decrease with increasing air temperature and pressure. Also, the data show that, for lean mixtures, ignition delay times decrease with increasing equivalence ratios

Fuels research: Combustion effects overview

The effects of broadened property fuels on gas turbine combustors were assessed. Those physical and chemical properties of fuels that affect aviation gas turbine combustion were isolated and identified. Combustion sensitivity to variations in particular fuel properties were determined. Advanced combustion concepts and subcomponents that could lessen the effect of using broadened property fuels were also identified

Fossil Fuels: Oil

This lesson provides an introduction to the world oil market and the United States' dependence on it. Topics include our current usage, sources, and the political implications of acquiring oil from an international market. There is also discussion of how petroleum is created and trapped in reservoirs, and how oil companies find it. The lesson includes an activity in which students use an online game that simulates the exploration and production of petroleum. To win, they must actually 'produce' commercial quantities of oil or gas by drilling in the ground in a 8-by-8 mile plot of land with a budget of $2 million dollars. Educational levels: Undergraduate lower division, High school

Preliminary analysis of aircraft fuel systems for use with broadened specification jet fuels

An analytical study was conducted on the use of broadened specification hydrocarbon fuels in present day aircraft. A short range Boeing 727 mission and three long range Boeing 747 missions were used as basis of calculation for one-day-per-year extreme values of fuel loading, airport ambient and altitude ambient temperatures with various seasonal and climatic conditions. Four hypothetical fuels were selected; two high-vapor-pressure fuels with 35 kPa and 70 kPa RVP and two high-freezing-point fuels with -29 C and -18 C freezing points. In-flight fuel temperatures were predicted by Boeing's aircraft fuel tank thermal analyzer computer program. Boil-off rates were calculated for the high vapor pressure fuels and heating/insulation requirements for the high freezing point fuels were established. Possible minor and major heating system modifications were investigated with respect to heat output, performance and economic penalties for the high freezing point fuels

Compatibility of elastomers in alternate jet fuels

The compatibility of elastomeric compositions of known resistance to aircraft fuels was tested for potential use in Jet A type fuels obtainable from alternate sources, such as coal. Since such fuels were not available at the time, synthetic alternate fuels were prepared by adding tetralin to a petroleum based Jet A type fuel to simulate coal derived fuels which are expected to contain higher amounts of aromatic and hydroaromatic hydrocarbons. The elastomeric compounds tested were based on butadiene-acrylonitrile rubber, a castable Thiokol polysulfide rubber, and a castable fluorosilicone rubber. Batches of various cross-link densities of these rubbers were made and their chemical stress relaxation behavior in fuel, air, and nitrogen, their swelling properties, and response to mechanical testing were determined