22,854 research outputs found
Tertiary flow injection thrust vectoring system Patent
Tertiary flow injection system for thrust vectoring of propulsive nozzle flo
Flow-injection of branched polymers inside nanopores
Flexible chains (linear or branched) can be forced to enter into a narrow
capillary by using a hydrodynamic flow. Here, we correct our earlier
description of this problem by considering the progressive nature of the
suction process. We find that the critical current for penetration, , is
controlled by the entry of a single blob of the capillary size, and that its
scaling structure is the same for branched and linear chains.Comment: Submitted to Europhysics Letter
Membrane separation in flow injection analysis : Gas Diffusion
A general expression is derived for the membrane transport process in a flow-through unit as commonly used in flow injection systems. The validity of the formulae was tested for gas-diffusion membranes by using compounds with different volatilities such as ammonia, carbon dioxide and acetic acid. Several microporous hydrophobic membranes were tested. A new module design is proposed
Easily Constructed Spectroelectrochemical Cell for Batch and Flow Injection Analyses
The design and performance of an easily constructed spectroelectrochemical cell suitable for batch and flow injection measurements are described. The cell is fabricated from a commercially available 5 mm quartz cuvet and employs 60 ppi reticulated vitreous carbon as the working electrode, resulting in a reasonable compromise between optical sensitivity and thin layer electrochemical behavior. The spectroelectrochemical traits of the cell in both batch and flow modes were evaluated using aqueous ferricyanide and compare favorably to those reported previously for similar cells
Automated injection of slurry samples in flow-injection analysis
Two types of injectors are described for introducing solid samples as slurries in flow analysis systems. A time-based and a volume-based injector based on multitube solenoid pinch valves were built, both can be characterized as hydrodynamic injectors. Reproducibility of the injections of dispersed solids ( 150 Âżm) was tested with several concentrations of slurry samples up to 30 mg/ml; the injected volume was 1 ml. For both injectors dye and slurry samples could be injected with good precision (relative standard deviation for the peak area less than 2%). Peak detection was performed turbidimetrically. Data analysis and operation of the injectors were automated. The usual peristaltic pumps in flow analysis are normally not capable of handling slurries of the type investigated, therefore a valveless piston pump was used instead
Impulse/response functions of individual components of flow-injection manifolds
The dispersion behaviour of the various individual parts making up a flow-injection manifold is often difficult to establish because it is virtually impossible to obtainthe required very small injection and detection volumes. It is shown that it is possible, under suitable experimental conditions, to find the impulse/response functionof each component by means of a deconvolution process of the response functions have been established, the response function of any arrangement can be predicted by convoluting the impulse/response functions of all the individuaol parts involved. Convolution and deconvolution were done in the Fourier domain, by using a fast FT algorithm
Flow injection determination of readily assimilable nitrogen compounds during vinification
A flow injection method for the determination of readily assimilable nitrogen (r.a.n.), i.e. ammonium and aminated nitrogen, is reported. The difference in pH of the sample in the presence and absence of formaldehyde, which blocks the amino function, provides the value of r.a.n. by monitoring the changes in absorbance of bromothymol blue at 616 nm. The detection and quantification limits are 10 and 11.6 mg l-1, respectively; the reproducibility and repeatability are 3.94 mg l-1 and 1.35 mg l-1, respectively; and the sample throughput is 20 samples h-1. The method has been applied to the analysis of 120 samples of must and wine subjected to biological aging. The proposed method also provides good correlation with the reference method used in routine analysis, and it is faster and gives sufficient precision for wineries requirements
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