Polyimide foams provide thermal insulation and fire protection

Chemical reactions to produce polyimide foams for application as thermal insulation and fire prevention materials are discussed. Thermal and physical properties of the polyimides are described. Methods for improving basic formulations to produce desired qualitites are included

Parametric numerical analysis of fire-induced pressure variations in a well-confined and mechanically ventilated compartment

The investigation of a fire in a well-confined and mechanically ventilated compartment is of primary importance for the nuclear industry. In normal operating conditions, a ventilation network system is set-up to ensure confinement via an appropriate pressure cascade. In the event of a fire, the subsequent pressure build-up alters the confinement level significantly and therefore changes the level of safety of the installation. The fire-induced pressure variations depend mainly on the: (1) HRR (Heat Release Rate) history of the fire, (2) heat losses to the walls, (3) leakage area, and (4) operating conditions of the fans. A numerical parametric analysis on the latter three parameters, using the Fire Dynamics Simulator (FDS 5.5.3), have shown that a change in the initial ventilation parameters (i.e. operating conditions of the fans and/or leaks), which can be sometimes difficult to determine, may lead to substantial changes in the pressure profiles. However, only a change in the thermal boundary conditions (i.e. presence or no of insulation) produces significant changes in the gas temperature

Ageing and Temperature Influence on Polarization/Depolarization Current Behaviour of Paper Immersed in Natural Ester

Transformers play an important role in providing a reliable and efficient electricity supply and are one of the most critical equipments in electric power transmission and distribution systems. The most commonly used liquid in power transformers is mineral oil due to its low price and good properties. However the performance of mineral oil starts to be limited due to environmental consideration [1]. Natural ester insulating fluid offers fire safety, environment and insulation aging advantages over mineral oil and are found to be suitable for the use in transformer insulation system [1]. However, transformer owners require to assess the status of the cellulose insulation in transformer non-destructively. Polarization/depolarization Current (PDC) measurement [2] is one of the non-destructive techniques which have been used to achieve this aim. At the present, there are few publications about the PDC behaviour of natural ester-paper insulation, though the natural ester becomes more widely used in transformers. In this paper, the influence of ageing and temperature on the PDC behaviour of the paper immersed in natural ester and mineral oil were compared. Results show PDC technique can be used to assess the aging condition of the natural-ester paper insulation. The ageing and temperature have similar influence on the PDC behaviour of the paper immersed in natural ester and in mineral oil. The depolarization current of paper immersed in natural ester is lower than that immersed in mineral oil at the same test temperature. The depolarization current of the paper immersed in natural ester and mineral oil increase with the aging time increased. Therefore, the depolarization current can be used to indicate the aging status of natural ester-paper insulation

Improvement of fire reaction and mould growth resistance of a new bio-based thermal insulation material

In the present paper, the performance of an innovative thermal insulation rigid board is evaluated in terms of fire behaviour and fungal resistance. The board is based on vegetal pith and a natural gum (corn pith and sodium alginate) and it is completely compostable. This new composite was developed in previous work. Here boric acid, aluminium hydroxide and ammonium polyphosphate are used as fire retardants and montan wax, acetic acid and lactic acid are used as water repellent and fungicides respectively. Interactions between these different treatments is investigated. Both flaming and smouldering combustion processes of the different formulations are evaluated by small-scale techniques which include pyrolysis microcalorimetry and thermogravimetric analysis. A medium-scale device is also designed in order to study the impact of the different additives to the smouldering kinetics. Fire behaviour tests show that good improvement is obtained, both in flaming and smouldering combustion when boric acid is added. Although smouldering is not avoided in any case, the addition of 8% of boric acid or aluminium hydroxide slows down the speed of combustion propagation. The effect of the different additives on the moisture content and mould growth at 97% RH and 27 °C is analysed. Under such severe conditions none of the additives is able to prevent mould growth, with the exception of boric acid. None or marginal mould growth was observed on samples containing 8% of boric acid although moisture content was higher than the other cases.Peer ReviewedPreprin

Fire safety of steel wall systems using enhanced plasterboards

Fire safety design is important to eliminate the loss of property and lives during fire events. Gypsum plasterboard is widely used as a fire safety material in the building industry all over the world. It contains gypsum (CaSO4.2H2O) and Calcium Carbonate (CaCO3) and most importantly free and chemically bound water in its crystal structure. The dehydration of the gypsum and the decomposition of Calcium Carbonate absorb heat, which gives the gypsum plasterboard fire resistant qualities. Currently plasterboard manufacturers use additives such as vermiculite to overcome shrinkage of gypsum core and glass fibre to bridge shrinkage cracks and enhance the integrity of board during calcination and after the loss of paper facings in fires. Past research has also attempted to reduce the thermal conductivity of plasterboards using fillers. However, no research has been undertaken to enhance the specific heat of plasterboard and the points of dehydration using chemical additives and fillers. Hence detailed experimental studies of powdered samples of plasterboard mixed with chemical additives and fillers in varying proportions were conducted. These tests showed the enhancement of specific heat of plasterboard. Numerical models were also developed to investigate the thermal performance of enhanced plasterboards under standard fire conditions. The results showed that the use of these enhanced plasterboards in steel wall systems can significantly improve their fire performance. This paper presents the details of this research and the results that can be used to enhance the fire safety of steel wall systems commonly used in buildings

The York Energy Demonstration Project: Final Report

In the early to mid 1990s the UK government funded a series of demonstration projects in local authority housing designed to implement a wide range of energy saving measures which could be incorporated into modernisation programmes. This programme (the Greenhouse Programme) ran from 1991 to 1994 and funded some 183 schemes (over 50,000 dwellings) of which the York project was one. In common with many energy demonstration projects, the York Project had two main aims. The first was to confirm that the application of readily available technology could deliver significant energy benefits within the context of a routine local authority housing modernisation programme. The second was to extract lessons for the operation of future energy conscious modernisation schemes

Разработка и исследование огнезащитного покрытия на основе полых микросфер

Разработано теплоизоляционное и огнезащитное покрытие серии «ВУЛКАН» на основе полых микросфер для применения в машиностроении, строительстве, энергетике и металлургии. Определены его теплофизические свойства — теплопроводность и температуропроводность. Показана возможность использования этого покрытия в качестве теплоизоляционного и огнезащитного материала.Thermal insulation and fire retardant coating series «Volcano» based on hollow microspheres for use in engineering, construction, energy and metallurgy was developed. Thermal properties were determined. This coating may be used for insulation and fireretardant material