A Survey of the Differential Geometry of Discrete Curves

Discretization of curves is an ancient topic. Even discretization of curves with an eye toward differential geometry is over a century old. However there is no general theory or methodology in the literature, despite the ubiquitous use of discrete curves in mathematics and science. There are conflicting definitions of even basic concepts such as discrete curvature {\kappa}, discrete torsion {\tau}, or discrete Frenet frame.Comment: 19 pages, 16 figure

Mixing in turbulent jets: scalar measures and isosurface geometry

Experiments have been conducted to investigate mixing and the geometry of scalar isosurfaces in turbulent jets. Specifically, we have obtained high-resolution, high-signal-to-noise-ratio images of the jet-fluid concentration in the far field of round, liquid-phase, turbulent jets, in the Reynolds number range 4.5 × 10^3 ≤ Re ≤ 18 × 10^3, using laser-induced-fluorescence imaging techniques. Analysis of these data indicates that this Reynolds-number range spans a mixing transition in the far field of turbulent jets. This is manifested in the probability-density function of the scalar field, as well as in measures of the scalar isosurfaces. Classical as well as fractal measures of these isosurfaces have been computed, from small to large spatial scales, and are found to be functions of both scalar threshold and Reynolds number. The coverage of level sets of jet-fluid concentration in the two-dimensional images is found to possess a scale-dependent-fractal dimension that increases continuously with increasing scale, from near unity, at the smallest scales, to 2, at the largest scales. The geometry of the scalar isosurfaces is, therefore, more complex than power-law fractal, exhibiting an increasing complexity with increasing scale. This behaviour necessitates a scale-dependent generalization of power-law-fractal geometry. A connection between scale-dependent-fractal geometry and the distribution of scales is established and used to compute the distribution of spatial scales in the flow

Work functions, ionization potentials, and in-between: Scaling relations based on the image charge model

We revisit a model in which the ionization energy of a metal particle is associated with the work done by the image charge force in moving the electron from infinity to a small cut-off distance just outside the surface. We show that this model can be compactly, and productively, employed to study the size dependence of electron removal energies over the range encompassing bulk surfaces, finite clusters, and individual atoms. It accounts in a straightforward manner for the empirically known correlation between the atomic ionization potential (IP) and the metal work function (WF), IP/WF$\sim$2. We formulate simple expressions for the model parameters, requiring only a single property (the atomic polarizability or the nearest neighbor distance) as input. Without any additional adjustable parameters, the model yields both the IP and the WF within $\sim$10% for all metallic elements, as well as matches the size evolution of the ionization potentials of finite metal clusters for a large fraction of the experimental data. The parametrization takes advantage of a remarkably constant numerical correlation between the nearest-neighbor distance in a crystal, the cube root of the atomic polarizability, and the image force cutoff length. The paper also includes an analytical derivation of the relation of the outer radius of a cluster of close-packed spheres to its geometric structure.Comment: Original submission: 8 pages with 7 figures incorporated in the text. Revised submission (added one more paragraph about alloy work functions): 18 double spaced pages + 8 separate figures. Accepted for publication in PR

Depletion interactions of non-spherical colloidal particles in polymer solutions

We consider anisotropic colloidal particles immersed in a solution of long, flexible, and nonadsorbing polymers. For the dumbbell shapes of recently synthesized particles consisting of two intersecting spheres and for lens-shaped particles with spherical surfaces we calculate the isotropic and anisotropic interaction parameters that determine the immersion free energy and the orientation-dependent depletion interaction between particles that are induced by the polymers. Exact results are obtained for random-walk like (ideal) polymer chains

Enhancements to the GW space-time method

We describe the following new features which significantly enhance the power of the recently developed real-space imaginary-time GW scheme (Rieger et al., Comp. Phys. Commun. 117, 211 (1999)) for the calculation of self-energies and related quantities of solids: (i) to fit the smoothly decaying time/energy tails of the dynamically screened Coulomb interaction and other quantities to model functions, treating only the remaining time/energy region close to zero numerically and performing the Fourier transformation from time to energy and vice versa by a combination of analytic integration of the tails and Gauss-Legendre quadrature of the remaining part and (ii) to accelerate the convergence of the band sum in the calculation of the Green's function by replacing higher unoccupied eigenstates by free electron states (plane waves). These improvements make the calculation of larger systems (surfaces, clusters, defects etc.) accessible.Comment: 10 pages, 6 figure