Accelerating charging dynamics in sub-nanometer pores

Having smaller energy density than batteries, supercapacitors have exceptional power density and cyclability. Their energy density can be increased using ionic liquids and electrodes with sub-nanometer pores, but this tends to reduce their power density and compromise the key advantage of supercapacitors. To help address this issue through material optimization, here we unravel the mechanisms of charging sub-nanometer pores with ionic liquids using molecular simulations, navigated by a phenomenological model. We show that charging of ionophilic pores is a diffusive process, often accompanied by overfilling followed by de-filling. In sharp contrast to conventional expectations, charging is fast because ion diffusion during charging can be an order of magnitude faster than in bulk, and charging itself is accelerated by the onset of collective modes. Further acceleration can be achieved using ionophobic pores by eliminating overfilling/de-filling and thus leading to charging behavior qualitatively different from that in conventional, ionophilic pores

A Model for Public Fast Charging Infrastructure Needs

Plug-in electric vehicles can reduce GHG emissions although the low availability of public charging infrastructure combined with short driving ranges prevents potential users from adoption. The rollout and operation, especially of public fast charging infrastructure, is very costly. Therefore, policy makers, car manufacturers and charging infrastructure providers are interested in determining a number of charging stations that is sufficient. Since most studies focus on the placement and not on the determination of the number of charging stations, this paper proposes a model for the quantification of public fast charging points. We first analyze a large database of German driving profiles to obtain the viable share of plug-in electric vehicles in 2030 and determine the corresponding demand for fast charging events. Special focus lies on a general formalism of a queuing system for charging points. This approach allows us to quantify the capacity provided per charging point and the required quantity. Furthermore, we take a closer look on the stochastic occupancy rate of charging points for a certain service level and the distribution of the time users have to wait in the queue. When applying this model to Germany, we find about 15,000 fast charging points with 50 kW necessary in 2030 or ten fast charging point per 1,000 BEVs. When compared with existing charging data from Sweden, this is lower than the currently existing 36 fast charging points per 1,000 BEVs. Furthermore, we compare the models output of charging event distribution over the day with that of the real data and find a qualitatively similar load of the charging network, though with a small shift towards later in the day for the model

Electric Power Allocation in a Network of Fast Charging Stations

In order to increase the penetration of electric vehicles, a network of fast charging stations that can provide drivers with a certain level of quality of service (QoS) is needed. However, given the strain that such a network can exert on the power grid, and the mobility of loads represented by electric vehicles, operating it efficiently is a challenging problem. In this paper, we examine a network of charging stations equipped with an energy storage device and propose a scheme that allocates power to them from the grid, as well as routes customers. We examine three scenarios, gradually increasing their complexity. In the first one, all stations have identical charging capabilities and energy storage devices, draw constant power from the grid and no routing decisions of customers are considered. It represents the current state of affairs and serves as a baseline for evaluating the performance of the proposed scheme. In the second scenario, power to the stations is allocated in an optimal manner from the grid and in addition a certain percentage of customers can be routed to nearby stations. In the final scenario, optimal allocation of both power from the grid and customers to stations is considered. The three scenarios are evaluated using real traffic traces corresponding to weekday rush hour from a large metropolitan area in the US. The results indicate that the proposed scheme offers substantial improvements of performance compared to the current mode of operation; namely, more customers can be served with the same amount of power, thus enabling the station operators to increase their profitability. Further, the scheme provides guarantees to customers in terms of the probability of being blocked by the closest charging station. Overall, the paper addresses key issues related to the efficient operation of a network of charging stations.Comment: Published in IEEE Journal on Selected Areas in Communications July 201

Runaway electrification of friable self-replicating granular matter

We establish that the nonlinear dynamics of collisions between particles favors the charging of a insulating, friable, self-replicating granular material that undergoes nucleation, growth, and fission processes; we demonstrate with a minimal dynamical model that secondary nucleation produces a positive feedback in an electrification mechanism that leads to runaway charging. We discuss ice as an example of such a self-replicating granular material: We confirm with laboratory experiments in which we grow ice from the vapor phase in situ within an environmental scanning electron microscope that charging causes fast-growing and easily breakable palm-like structures to form, which when broken off may form secondary nuclei. We propose that thunderstorms, both terrestrial and on other planets, and lightning in the solar nebula are instances of such runaway charging arising from this nonlinear dynamics in self-replicating granular matter

Novel nonimaging solar concentrator for portable solar systems for developing countries

Portable solar chargers have been gaining popularity as a new technology to help increase electrification in rural areas in developing countries. It is a fast developing industry aiming to produce a low-cost solution for the application of off-grid solar lighting and charging of small devices to be used by the poorest and most vulnerable of society. Solar concentrators are proposed as an add-on to help further reduce costs, to increase light-output hours and to reduce charging time. So far, no suitable concentrator designs have been proposed. This paper presents a novel concept for the design of a static nonimaging concentrator, suitable for portable solar systems for developing countries. The novel concentrator design is compared with existing concentrators and its suitability for portable solar chargers, as well as its potential for further improvement, are highlighted

Vehicle charging and potential on the STS-3 mission

An electron gun with fast pulse capability was used in the vehicle charging and potential experiment carried on the OSS-1 pallet to study dielectric charging, return current mechanisms, and the techniques required to manage the electrical charging of the orbiter. Return currents and charging of the dielectrics were measured during electron beam emission and plasma characteristics in the payload bay were determined in the absence of electron beam emission. The fast pulse electron generator, charge current probes, spherical retarding potential analyzer, and the digital control interface unit which comprise the experiment are described. Results show that the thrusters produce disturbances which are variable in character and magnitude. Strong ram/wake effects were seen in the ion densities in the bay. Vehicle potentials are variable with respect to the plasma and depend upon location on the vehicle relative to the main engine nozzles, the vehicle attitude, and the direction of the geomagnetic field

Long-term evolution of broken wakefields in finite radius plasmas

A novel effect of fast heating and charging a finite-radius plasma is discovered in the context of plasma wakefield acceleration. As the plasma wave breaks, the most of its energy is transferred to plasma electrons which create strong charge-separation electric field and azimuthal magnetic field around the plasma. The slowly varying field structure is preserved for hundreds of wakefield periods and contains (together with hot electrons) up to 80% of the initial wakefield energy.Comment: 5 pages, 6 figure