Dynamic fracture process of solder/intermetallic interface in lead-free solder interconnects using cohesive zone model

Solder joint reliability (SJR) is an important requirement in electronics packaging. Most of the failures in a package are found in solder joints and interconnections. Brittle solder/intermetallic (IMC) interface fracture is the dominant failure mode in cases of impact loading and fast mechanical fatigue loading. In this study, the response of a single solder specimen subjected to cyclic shear deformation and a typical ball grid array (BGA) package undergoing board-level drop test is investigated. The finite element (FE) analysis of the single reflowed solder specimen and the BGA package is employed to understand the mechanics of the solder joints and the brittle solder/ IMC fracture process. Inelastic behavior of the solder joints is described using unified inelastic strain model (Anand model) with optimized model parameters. The brittle solder/IMC interface fracture is demonstrated using cohesive zone model (CZM). The accuracy of interface fracture description depends on the CZM model prescribed in the analysis. The CZM model is modified further to ensure better predictive capability especially in cyclic loading. FE results for single solder specimen under shear fatigue test simulation shows that the CZM parameters degraded as the number of cycles is increased. Rapid damage progression occurs at the beginning of cycle and propagated slowly for subsequent cycles. For a boardlevel drop test simulation, the critical solder joint is located the farthest away from the center of the board. The highest stress and inelastic strain are confined to a small edge region at solder/IMC interfaces. Damage initiated from the outer peripheral solder and propagated into the inner peripheral solder joint

Thermomechanical fatigue failure of interfaces in lead-free solders

The European Union Waste Electrical and Electronic Equipment Directive (WEEE) and Restriction of Hazardous Substances Directive (RoHS) banned lead from electronic systems from July 1, 2006 onwards, which has led to much interest in leadfree solders in the past years. Among several lead-free solder alternatives, SnAgCu is a widely accepted replacement due to its better creep-fatigue resistance and microstructural stability. SnAgCu has been extensively studied in the past decade, however, there are still issues to be resolved concerning solder reliability, the underlying mechanisms of thermo-mechanical fatigue failure, fatigue life predictions and the overall effect of decreasing component size, driven by the ongoing miniaturization trend. This thesis aims to scientifically contribute to this subject by a coupled experimental-numerical approach. In solder joint reliability, the bump/pad interface has a crucial role, the quality of which is determined by the metallization and interfacial defects. Solder balls, solder paste and cast eutectic SnAgCu are reflowed on Cu, Ni/Au and Cu/Ni(V)/Au metallization layers and the substrate influence on the bulk and interfacial metallurgy is examined. The damage propagation at SnAgCu soldered joints on Cu and Ni/Au substrates are investigated and microstructure related damage localization is identified as the dominant failure mechanism. Therefore, continuum damage approaches are believed to be inadequate for solder joint reliability predictions. Nano-indentation and tensile testing is used for the mechanical characterization of SnAgCu. An assessment on indentation parameters for solders is conducted and the influence of the Ag content on material properties of SnAgCu is presented. One of the main causes of ball grid array (BGA) failure is thermo-mechanical fatigue crack propagation in the solder, which is almost always observed at the bump/pad junction. Motivated by this fact, a combined experimental-numerical study on the cyclic mechanical response of SnAgCu/Ni-Au interface is conducted. In this study, damage evolution at the bond/pad interface is characterized by dedicated fatigue tests. Local deformations leading to crack propagation are simulated by separation of interfaces through a cohesive zone approach. Solder joints are tested under cyclic shear and cyclic tension for different specimen sizes and strain amplitudes. Two different damagemechanisms are observed: local deformations in the bulk and at the bonding interface. The interfacial failure mode is typically favored at a high initial stress, and a small solder volume. Crack propagation is simulated by an irreversible linear traction-separation cohesive zone law accompanied by a non-linear interfacial damage parameter. Later, tensile and shear experiments are used to characterize the cohesive zone parameters for the normal and the tangential opening, respectively. Interfacial fatigue damage in BGA solders is caused by the difference in coefficient of thermal expansion (CTE) of the materials in the package. Apart from this thermal incompatibility in the package, Sn based solders are themselves prone to thermal fatigue damage due to the intrinsic thermal anisotropy of the ß-Sn phase. Thermal fatigue causes local deformations especially at the grain boundaries. Hence, the thermal fatigue response of bulk SnAgCu is investigated as well. Bulk SnAgCu specimens are thermally cycled between -40 and 125¿C and mechanically tested afterwards in order to quantify the thermal fatigue damage. A size dependent cyclic softening behavior is observed. Test specimens are individually modeled including the microstructure and local crystallographic orientations, on the basis of orientation imaging scans (OIM). Both thermal cycling and tensile testing are imposed as boundary conditions. Reproducing the experimental results in the simulations, parameters of a cohesive zone based intergranular fatigue damagemodel are identified. Finally, the intergranular damage law characterized in this study is combined with the bump/pad interfacial damage law, and a 2Dmicrostructure-incorporated fatigue life prediction tool is established. Using this tool, it is shown that the failure mode of a soldered joint depends extensively on its geometry. The model presented above is extended to 3D for a more complete description of the problem. To provide the microstructural input, a database containing OIM scans of several SnAgCu solder balls is constructed. A missing constituent in the model so far, interfacial defects, i.e. voids, are examined statistically using newly manufactured BGA packages, revealing information on their size, position and frequency. Combining all the data collected, i.e. material properties, microstructure, defects, local damage laws, a 3D slice model from a BGA package is constructed. The slice model contains a single solder ball connecting the board and the chip. A series of case studies is created using experimental input such as different microstructures and initial defects allowing a statistical analysis. Fatigue life of these models are predicted and the results are validated by failure distribution analyses of BGA packages provided by the industry. Here the critical solder ball assumption is made: if a solder ball fails, the electrical circuit of the BGA package is open, thus the package fails. Setting a critical damage value for the interfaces accumulating fatigue damage, a good agreement with the experiments and simulations is obtained. It is seen that microstructural modeling allows to predict and understand the scatter in the solder ball fatigue life observed in reality. Finally, the effect of solder ball size and geometry on interconnect reliability is dis cussed on the basis of numerical analyses. For this purpose, a geometry factor and a microstructure factor is defined, and their influence on damage evolution is discusse

Thermomechanical fatigue failure of interfaces in lead-free solders

The European Union Waste Electrical and Electronic Equipment Directive (WEEE) and Restriction of Hazardous Substances Directive (RoHS) banned lead from electronic systems from July 1, 2006 onwards, which has led to much interest in leadfree solders in the past years. Among several lead-free solder alternatives, SnAgCu is a widely accepted replacement due to its better creep-fatigue resistance and microstructural stability. SnAgCu has been extensively studied in the past decade, however, there are still issues to be resolved concerning solder reliability, the underlying mechanisms of thermo-mechanical fatigue failure, fatigue life predictions and the overall effect of decreasing component size, driven by the ongoing miniaturization trend. This thesis aims to scientifically contribute to this subject by a coupled experimental-numerical approach. In solder joint reliability, the bump/pad interface has a crucial role, the quality of which is determined by the metallization and interfacial defects. Solder balls, solder paste and cast eutectic SnAgCu are reflowed on Cu, Ni/Au and Cu/Ni(V)/Au metallization layers and the substrate influence on the bulk and interfacial metallurgy is examined. The damage propagation at SnAgCu soldered joints on Cu and Ni/Au substrates are investigated and microstructure related damage localization is identified as the dominant failure mechanism. Therefore, continuum damage approaches are believed to be inadequate for solder joint reliability predictions. Nano-indentation and tensile testing is used for the mechanical characterization of SnAgCu. An assessment on indentation parameters for solders is conducted and the influence of the Ag content on material properties of SnAgCu is presented. One of the main causes of ball grid array (BGA) failure is thermo-mechanical fatigue crack propagation in the solder, which is almost always observed at the bump/pad junction. Motivated by this fact, a combined experimental-numerical study on the cyclic mechanical response of SnAgCu/Ni-Au interface is conducted. In this study, damage evolution at the bond/pad interface is characterized by dedicated fatigue tests. Local deformations leading to crack propagation are simulated by separation of interfaces through a cohesive zone approach. Solder joints are tested under cyclic shear and cyclic tension for different specimen sizes and strain amplitudes. Two different damagemechanisms are observed: local deformations in the bulk and at the bonding interface. The interfacial failure mode is typically favored at a high initial stress, and a small solder volume. Crack propagation is simulated by an irreversible linear traction-separation cohesive zone law accompanied by a non-linear interfacial damage parameter. Later, tensile and shear experiments are used to characterize the cohesive zone parameters for the normal and the tangential opening, respectively. Interfacial fatigue damage in BGA solders is caused by the difference in coefficient of thermal expansion (CTE) of the materials in the package. Apart from this thermal incompatibility in the package, Sn based solders are themselves prone to thermal fatigue damage due to the intrinsic thermal anisotropy of the ß-Sn phase. Thermal fatigue causes local deformations especially at the grain boundaries. Hence, the thermal fatigue response of bulk SnAgCu is investigated as well. Bulk SnAgCu specimens are thermally cycled between -40 and 125¿C and mechanically tested afterwards in order to quantify the thermal fatigue damage. A size dependent cyclic softening behavior is observed. Test specimens are individually modeled including the microstructure and local crystallographic orientations, on the basis of orientation imaging scans (OIM). Both thermal cycling and tensile testing are imposed as boundary conditions. Reproducing the experimental results in the simulations, parameters of a cohesive zone based intergranular fatigue damagemodel are identified. Finally, the intergranular damage law characterized in this study is combined with the bump/pad interfacial damage law, and a 2Dmicrostructure-incorporated fatigue life prediction tool is established. Using this tool, it is shown that the failure mode of a soldered joint depends extensively on its geometry. The model presented above is extended to 3D for a more complete description of the problem. To provide the microstructural input, a database containing OIM scans of several SnAgCu solder balls is constructed. A missing constituent in the model so far, interfacial defects, i.e. voids, are examined statistically using newly manufactured BGA packages, revealing information on their size, position and frequency. Combining all the data collected, i.e. material properties, microstructure, defects, local damage laws, a 3D slice model from a BGA package is constructed. The slice model contains a single solder ball connecting the board and the chip. A series of case studies is created using experimental input such as different microstructures and initial defects allowing a statistical analysis. Fatigue life of these models are predicted and the results are validated by failure distribution analyses of BGA packages provided by the industry. Here the critical solder ball assumption is made: if a solder ball fails, the electrical circuit of the BGA package is open, thus the package fails. Setting a critical damage value for the interfaces accumulating fatigue damage, a good agreement with the experiments and simulations is obtained. It is seen that microstructural modeling allows to predict and understand the scatter in the solder ball fatigue life observed in reality. Finally, the effect of solder ball size and geometry on interconnect reliability is dis cussed on the basis of numerical analyses. For this purpose, a geometry factor and a microstructure factor is defined, and their influence on damage evolution is discusse

Identification of damage and fracture modes in power electronic packaging from experimental micro-shear tests and finite element modeling

Micro-shear tests are performed in order to characterize the mechanical behavior and the fracture of the chip/metallized ceramic substrate assemblies of power electronic devices. These assemblies are elaborated using three types of junctions: AuGe solder/Au or Ag finish, transient liquid phase bonding (TLPB) AgIn/Ag finish and Ag nanoparticles/Au or Ag finish. The experiments are associated to finite element simulations of both nano-indentation and micro-shear tests. The mechanical behavior of the different assembly interfaces is represented using an in-built cohesive zone model (CZM) available in the user friendly finite element code Abaqus. It is worth noting that the fracture mechanisms observed during the test and service periods of the power electronic packaging are not only due to the debonding at the interfaces but also to the initiation and growth of voids in the joint. Therefore, in addition to the CZM model, Gurson-Tvergaard-Needlmann (GTN) damage model is used in combination with the Rice bifurcation theory to correctly describe the fracture in the joint and, therefore the overall fracture mechanism of the entire junction. The simulation results are compared with the experimental force displacement curves and the SEM observations in order to assess the implemented model

Thermo-mechanical reliability studies of lead-free solder interconnects

N/ASolder interconnections, also known as solder joints, are the weakest link in electronics packaging. Reliability of these miniature joints is of utmost interest - especially in safety-critical applications in the automotive, medical, aerospace, power grid and oil and drilling sectors. Studies have shown that these joints' critical thermal and mechanical loading culminate in accelerated creep, fatigue, and a combination of these joints' induced failures. The ball grid array (BGA) components being an integral part of many electronic modules functioning in mission-critical systems. This study investigates the response of solder joints in BGA to crucial reliability influencing parameters derived from creep, visco-plastic and fatigue damage of the joints. These are the plastic strain, shear strain, plastic shear strain, creep energy density, strain energy density, deformation, equivalent (Von-Mises) stress etc. The parameters' obtained magnitudes are inputted into established life prediction models – Coffin-Manson, Engelmaier, Solomon (Low cycle fatigue) and Syed (Accumulated creep energy density) – to determine several BGA assemblies' fatigue lives. The joints are subjected to thermal, mechanical and random vibration loadings. The finite element analysis (FEA) is employed in a commercial software package to model and simulate the responses of the solder joints of the representative assemblies' finite element models. As the magnitude and rate of degradation of solder joints in the BGA significantly depend on the composition of the solder alloys used to assembly the BGA on the printed circuit board, this research studies the response of various mainstream lead-free Sn-Ag-Cu (SAC) solders (SAC305, SAC387, SAC396 and SAC405) and benchmarked those with lead-based eutectic solder (Sn63Pb37). In the creep response study, the effects of thermal ageing and temperature cycling on these solder alloys' behaviours are explored. The results show superior creep properties for SAC405 and SAC396 lead-free solder alloys. The lead-free SAC405 solder joint is the most effective solder under thermal cycling condition, and the SAC396 solder joint is the most effective solder under isothermal ageing operation. The finding shows that SAC405 and SAC396 solders accumulated the minimum magnitudes of stress, strain rate, deformation rate and strain energy density than any other solder considered in this study. The hysteresis loops show that lead-free SAC405 has the lowest dissipated energy per cycle. Thus the highest fatigue life, followed by eutectic lead-based Sn63Pb37 solder. The solder with the highest dissipated energy per cycle was lead-free SAC305, SAC387 and SAC396 solder alloys. In the thermal fatigue life prediction research, four different lead-free (SAC305, SAC387, SAC396 and SAC405) and one eutectic lead-based (Sn63Pb37) solder alloys are defined against their thermal fatigue lives (TFLs) to predict their mean-time-to-failure for preventive maintenance advice. Five finite elements (FE) models of the assemblies of the BGAs with the different solder alloy compositions and properties are created with SolidWorks. The models are subjected to standard IEC 60749-25 temperature cycling in ANSYS 19.0 mechanical package environment. SAC405 joints have the highest predicted TFL of circa 13.2 years, while SAC387 joints have the least life of circa 1.4 years. The predicted lives are inversely proportional to the magnitude of the areas of stress-strain hysteresis loops of the solder joints. The prediction models are significantly consistent in predicted magnitudes across the solder joints irrespective of the damage parameters used. Several failure modes drive solder joints and damage mechanics from the research and understand an essential variation in the models' predicted values. This investigation presents a method of managing preventive maintenance time of BGA electronic components in mission-critical systems. It recommends developing a novel life prediction model based on a combination of the damage parameters for enhanced prediction. The FEA random vibration simulation test results showed that different solder alloys have a comparable performance during random vibration testing. The fatigue life result shows that SAC405 and SAC396 have the highest fatigue lives before being prone to failure. As a result of the FEA simulation outcomes with the application of Coffin-Manson's empirical formula, the author can predict the fatigue life of solder joint alloys to a higher degree of accuracy of average ~93% in an actual service environment such as the one experienced under-the-hood of an automobile and aerospace. Therefore, it is concluded that the combination of FEA simulation and empirical formulas employed in this study could be used in the computation and prediction of the fatigue life of solder joint alloys when subjected to random vibration. Based on the thermal and mechanical responses of lead-free SAC405 and SAC396 solder alloys, they are recommended as a suitable replacement of lead-based eutectic Sn63Pb37 solder alloy for improved device thermo-mechanical operations when subjected to random vibration (non-deterministic vibration). The FEA simulation studies' outcomes are validated using experimental and analytical-based reviews in published and peer-reviewed literature.N/

Dynamic Mechanical and Failure Properties of Solder Joints

Ph.DDOCTOR OF PHILOSOPH

Effects of underfill material on solder deformation and damage in 3D packages

This paper will examine the effects of the introduction of a periodic boundary condition and the presence of underfill material on the stress and strain fields and evolution of failure of an FEA model that is representative of a solder joint in a 3D IC package. The model solder joint is placed between two silicon substrates in contact with through-silicon vias without any other devices or components attached. Differing solder joint thicknesses, both with and without underfill, will be examined to study the effect on the stress and strain fields as well as the evolution of failure in the solder joint. A dynamic loading on the FEA model will be used to examine the fracture pattern and mode of failure when the solder thickness is varied both with and without underfill material present

Study Of Deformation And Crack Propagation On Component During Reflow Soldering Process

A typical element found in electronic assemblies and devices is the multi-layered ceramic capacitor (MLCC). However, MLCC mechanical defects such as voiding, cracking, and delamination would significantly reduce the device's usefulness, dependability, and longevity. This mechanical defect is one of the significant factors that will develop in the surface mount of the multi-layered ceramic capacitor, especially the layer between the two different materials that are mounted together. Therefore, the purpose of this study is to study the crack propagation that will be found in the boundary of the copper and copper-epoxy layers of the multi-layered ceramic capacitor during the reflow soldering process. The numerical simulation method for the thermal reflow process of the MLCC model and the crack propagation from the initial micro voids due to the high moisture contamination on that layer was approached. Besides, the temperature flow and the moisture contamination on the copper and copper-epoxy layers were examined during the simulation for the causes of the crack propagation on the MLCC. From the results of the simulation conducted, the crack propagation in between the copper and copper-epoxy layers was caused by the thermal mismatch and propagation growth of micro voids during the reflow soldering process. As a result of the high pressure of vapour absorbed in the gap between the copper and copper-epoxy layer, it will have a greater capacity to absorb moisture and cause crack delamination, resulting in the higher temperatures required to commence the crack at 270 °C during the reflow process. At 284.2 (mg/mm3), the concentration is at its highest. Because of this, a multi-layered ceramic capacitor results in a 0.077218 mm deformation between copper and copper-epoxy. Higher vicinity stress, mode I stress intensity factor, and crack elongation rate would result from this greater void. The main reason for the temperature reflows that is related to the fracture propagation problems in capacitors has been identified, and workable solutions have thus been suggested. This would help the end-users by enhancing the performance and dependability of the electronic equipment, as well as minimizing the additional manufacturing costs and lead times required in locating and resolving the problems

MICROSTRUCTURAL CHARACTERIZATION AND THERMAL CYCLING RELIABILITY OF SOLDERS UNDER ISOTHERMAL AGING AND ELECTRICAL CURRENT

Solder joints on printed circuit boards provide electrical and mechanical connections between electronic devices and metallized patterns on boards. These solder joints are often the cause of failure in electronic packages. Solders age under storage and operational life conditions, which can include temperature, mechanical loads, and electrical current. Aging occurring at a constant temperature is called isothermal aging. Isothermal aging leads to coarsening of the bulk microstructure and increased interfacial intermetallic compounds at the solder-pad interface. The coarsening of the solder bulk degrades the creep properties of solders, whereas the voiding and brittleness of interfacial intermetallic compounds leads to mechanical weakness of the solder joint. Industry guidelines on solder interconnect reliability test methods recommend preconditioning the solder assemblies by isothermal aging before conducting reliability tests. The guidelines assume that isothermal aging simulates a "reasonable use period," but do not relate the isothermal aging levels with specific use conditions. Studies on the effect of isothermal aging on the thermal cycling reliability of tin-lead and tin-silver-copper solders are limited in scope, and results have been contradictory. The effect of electrical current on solder joints has been has mostly focused on current densities above 104A/cm2 with high ambient temperature (≥100oC), where electromigration, thermomigration, and Joule heating are the dominant failure mechanisms. The effect of current density below 104A/cm2 on temperature cycling fatigue of solders has not been established. This research provides the relation between isothermal aging and the thermal cycling reliability of select Sn-based solders. The Sn-based solders with 3%, 1%, and 0% silver content that have replaced tin-lead are studied and compared against tin-lead solder. The activation energy and growth exponents of the Arrhenius model for the intermetallic growth in the solders are provided. An aging metric to quantify the aging of solder joints, in terms of phase size in the solder bulk and interfacial intermetallic compound thickness at the solder-pad interface, is established. Based on the findings of thermal cycling tests on aged solder assemblies, recommendations are made for isothermal aging of solders before thermal cycling tests. Additionally, the effect of active electrical current at 103 A/cm2 on thermal cycling reliability is reported

Thermal and thermo-mechanical performance of voided lead-free solder thermal interface materials for chip-scale packaged power device

The need to maximise thermal performance of electronic devices coupled with the continuing trends on miniaturization of electronic packages require innovative package designs for power devices and modules such as Electronic Control Unit (ECU). Chip scale packaging (CSP) technology offer promising solution for packaging power electronics. This is as a result of the technology’s relatively improved thermal performance and inherent size advantage. In CSP technology, heat removal from the device could be enhanced through the backside of the chip. Heat dissipating units such as heat spreader and/or heat sink can be attached to the backside (reverse side) of the heat generating silicon die (via TIM) in an effort to improve the surface area available for heat dissipation. TIMs are used to mechanically couple the heat generating chip to a heat sinking device and more crucially to enhance thermal transfer across the interface. Extensive review shows that solder thermal interface materials (STIMs) apparently offer better thermal performance than comparable state-of-the-art commercial polymer-based TIMs and thus a preferable choice in packaging power devices. Nonetheless, voiding remains a major reliability concern of STIMs. This is coupled with the fact that solder joints are generally prone to fatigue failures under thermal cyclic loading. Unfortunately, the occurrence of solder voids is almost unavoidable during manufacturing process and is even predominant in lead (Pb)-free solder joints. The impacts of these voids on the thermal and mechanical performance of solder joints are not clearly understood and scarcely available in literature especially with regards to STIMs (large area solder joints). Hence, this work aims to investigate STIM and the influence of voids on the thermo-mechanical and thermal performance of STIM. As previous results suggest that factors such as the location, configuration (spatial arrangement) and size of voids play vital roles on the exact effect of voids, extensive three dimensional (3D) finite element modelling is employed to elucidate the precise effect of these void features on a Pb-free STIM selected after thermo-mechanical fatigue test of standard Pb-free solder alloys. Finite element analysis (FEA) results show that solder voids configuration, size and location are all vital parameters in evaluating the mechanical and thermal impacts of voids. Depending on the location, configuration and size of voids; solder voids can either influence the initiation or propagation of damage in the STIM layer or the location of hot spot on the heat generating chip. Experimental techniques are further employed to compare and correlate levels of voiding and shear strength for representative Pb-free solders. Experimental results also suggest that void size, location and configuration may have an influence on the mechanical durability of solder joints. The findings of this research work would be of interest to electronic packaging engineers especially in the automotive sector and have been disseminated through publications in peer reviewed journals and presentations in international conferences