Design, development and characterisation of piezoresistive and capacitive polymeric pressure sensors for use in compression hosiery

The work in this thesis was focused in developing a flexible and cost-effective pressure sensor capable of detecting pressure variations within the low working range (0-6kPa) of compression hosiery. For this cause, both piezoresistive and capacitive pressure sensors were developed and characterised, utilising conductive and non-conductive polymeric elements to sense compressive loads. In the first case, the developed piezoresistive sensor is composed of a conductive filler - polymer composite, with a force-dependent conductivity, encapsulated in between a structured and unstructured configuration of electrodes. Initially, as the sensing element of the sensor a multi-walled carbon nanotubes-polydimethylsiloxane (MWCNT-PDMS) composite was tested. A fabrication process is also proposed for developing the MWCNT-PDMS composite which involves a series of successive direct ultrasonications and shear mixing in order to disperse the two constituents of the composite, with the use of an organic solvent. Developing the composite over a range of different filler concentrations revealed a sharp step-like conductivity behaviour, typical amongst percolating composites. The MWCNT-PDMS sensor exhibited a positive piezoresistive response when subjected to compression, which was substantially enhanced when structured electrode layers were utilised. A Quantum Tunnelling Composite (QTC) material was also tested as the sensing material, which displays a large negative piezoresistive response when deformed. The QTC pressure sensor exhibited an improved performance, which was similarly significantly increased when a structured electrode was employed. In the second case, a parallel-plate capacitive pressure sensor was developed and characterised, which successfully provided a pressure sensitivity within the working range of compression hosiery. The sensor employs an ultra-thin PDMS blend film, with tuneable Young’s modulus, as the dielectric medium of the capacitor, bonded in between two rigid copper-coated glass layers. A casting process is also presented, involving the use of a sacrificial mould, in order to pattern the polymeric film with a micro-pillar structure to assist the deformation of the medium under compressive loads. The performance of the sensor with regards to the polymeric film thickness, structure and mechanical softness was explored. Overall, the combination of an ultra-thin dielectric medium with a very low Young’s modulus and a microstructured surface resulted in a capacitive pressure sensor with a good performance within the desired pressure regime

Soft Sensors in digital healthcare monitoring

Stretchable sensors are a class of materials with applications across research fields from healthcare to structural engineering. Despite the extensive research aiming to improve the performance of individual materials or components, stretchable sensor devices are difficult to implement because conventional electronic components, mainly used for processing, which are rigid, have to make contact with soft components reliable enough to withstand real-world usage. This thesis introduces a method for creating electrical contacts that can be robustly attached onto soft, stretchable conductive polymer composites on one side and soldered to metal wires on the other side. Mechanically robust electrical contacts were developed to interface (soft) silicone-based strain sensors with conventional (hard) solid-state electronics using a nanoporous silicon-copper contact. Contacts are mounted on custom-made and commercial soft strain sensitive silicone sensors. The contacts are shown to be reliable under large deformations, then compared with a commonly used alternative under real-world strain conditions. The layered structure of the device creates a complex electronic component deriving from the silicon-copper Schottky junction. This thesis tests the versatility of the technology through a series of real-world applications. The silicon-copper contacts were used to produce a series of proof-of-concept devices, including a wearable respiration monitor, leg band for exercise monitoring, and squeezable ball to monitor rehabilitation of patients with hand injuries or neurological disorders. The sensor is shown to operate and detect multiple modes of motion regardless of placement on the body. Next, a proof-of-concept device was employed to measure hand grip strength. The optimized sensor can detect grip strength with high sensitivity. The hardness of the device was shown to increase sensitivity when healthy humans performed manual exercises and completed digital tasks. Providing patients with these devices can help monitor their rehabilitation following hand injuries or neurological disorders. This can be done through self-led at-home therapy which has been shown to improve treatment, engagement, long-term lifestyle adherence, while avoiding repeated visits to clinics which plays an important role in frequency of therapy, effectiveness, and accessibility.Open Acces

Carbon Nanotubes

Since their discovery in 1991, carbon nanotubes have been considered as one of the most promising materials for a wide range of applications, in virtue of their outstanding properties. During the last two decades, both single-walled and multi-walled CNTs probably represented the hottest research topic concerning materials science, equally from a fundamental and from an applicative point of view. There is a prevailing opinion among the research community that CNTs are now ready for application in everyday world. This book provides an (obviously not exhaustive) overview on some of the amazing possible applications of CNT-based materials in the near future

Textile materials

In this specialised publication, the reader will find research results and real engineering developments in the field of modern technical textiles. Modern technical textile materials, ranging from ordinary reinforcing fabrics in the construction and production of modern composite materials to specialised textile materials in the composition of electronics, sensors and other intelligent devices, play an important role in many areas of human technical activity. The use of specialized textiles, for example, in medicine makes it possible to achieve important results in diagnostics, prosthetics, surgical practice and the practice of using specialized fabrics at the health recovery stage. The use of reinforcing fabrics in construction can significantly improve the mechanical properties of concrete and various plaster mixtures, which increases the reliability and durability of various structures and buildings in general. In mechanical engineering, the use of composite materials reinforced with special textiles can simultaneously reduce weight and improve the mechanical properties of machine parts. Fabric- reinforced composites occupy a significant place in the automotive industry, aerospace engineering, and shipbuilding. Here, the mechanical reliability and thermal resistance of the body material of the product, along with its low weight, are very relevant. The presented edition will be useful and interesting for engineers and researchers whose activities are related to the design, production and application of various technical textile materials

Carbon Electronics: Nano-carbons for the development of radiation sensors, image intensifiers and medical sensors

Carbon nano-materials, both in sp2 (graphene like) and sp3 (diamond) con- figurations are renowned for their unmatched novel properties. In particular, its extremely high electrical conductivity, radiation hardness and electron amplification are widely coveted. This investigation aims to capitalise on the above by developing blood pressure sensors, radiation detectors and signal amplifiers from the said carbon nano-materials. Namely, carbon nanotubes (sp2 carbon) were integrated into a polymer host to form a composite. Where it has been found that by altering the surface functionalisations of carbon nanotubes (non-functionalised, -OH and -COOH) the electrical resistance of the composite could vary drastically as much as 1012Ω to 107Ω. This brings potential benefits in reduced production costs, reduced environmental damage and wider technological adoption of carbon composite based devices. Carbon nanotubes were then encased in a soft and biocompatible host, polydimethylsiloxane (PDMS), in order to fabricate an in vivo blood pressure sensor, exploiting its piezo-resistivity. Results have shown a successful and adequate degree of piezo-resistivity (109Ω to 106Ω for 2D and 4kΩ to 750kΩ for 3D compression) at the desired size-scale of 200µm and 4mm respectively. This is a size equivalent to that of the diameter of blood vessels in question. However, further investigation into re-miniaturisation is recommended for future works. Diamond (sp3 carbon), on the other hand, was used as a longlasting solution to neutron detection for a Trident nuclear submarine, HMS Artful. The investigation entailed a three-phase process of: α-particle detection, LiF conversion layer addition and neutron detection. Results has shown clear signs of α-particle and neutron detection with a device efficiency of 32.3% and 48.3% respectively, as well as γ-ray transparency and sufficient Q-factor between the signal peak and detection peak. Diamond was also used as a signal amplifier that has application as an image intensifier for night-vision goggles where it was found thatby altering the surface functionalisation of nano-diamonds (H, O and LiO) one could enhance or suppress the secondary electron emission effect. Additionally, it was found that the electrical gain from the said secondary electron emission has a strong dependence on the crystal structure of the diamond layer and in turn its growth conditions. Most notably, LiO functional group was found to be more resilient towards higher temperatures (800oC) and electron bombardments but fell short in the amount of electrical gain it generated in comparison to conventional functionalisations such as H. However, the X-ray photoelectron spectroscopy (XPS) results suggest that this may be due to the lack of LiO coverage and upon further investigation, LiO may potentially bode better if not surpass the gain performance of H

Advances in Computer Science and Engineering

The book Advances in Computer Science and Engineering constitutes the revised selection of 23 chapters written by scientists and researchers from all over the world. The chapters cover topics in the scientific fields of Applied Computing Techniques, Innovations in Mechanical Engineering, Electrical Engineering and Applications and Advances in Applied Modeling

Low electrical resistivity carbon nanotube and polyethylene nanocomposites for aerospace and energy exploration applications

An investigation was conducted towards the development and optimization of low electrical resistivity carbon nanotube (CNT) and thermoplastic composites as potential materials for future wire and cable applications in aerospace and energy exploration. Fundamental properties of the polymer, medium density polyethylene (MDPE), such as crystallinity were studied and improved for composite use. A parallel effort was undertaken on a broad selection of CNT, including single wall, double wall and multi wall carbon nanotubes, and included research of material aspects relevant to composite application and low resistivity such as purity, diameter and chirality. With an emphasis on scalability, manufacturing and purification methods were developed, and a solvent-based composite fabrication method was optimized. CNT MDPE composites were characterized via thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), Raman spectroscopy, and multiple routes of electron microscopy. Techniques including annealing and pressure treatments were used to further improve the composites' resulting electrical performance. Enhancement of conductivity was explored via exposure to a focused microwave beam. A novel doping method was developed using antimony pentafluoride (SbF 5 ) to reduce the resistivity of the bulk CNT. Flexible composites, malleable under heat and pressure, were produced with exceptional electrical resistivities reaching as low as 2*10 -6 Ω·m (5*10 5 S/m). A unique gas sensor application utilizing the unique electrical resistivities of the produced CNT-MDPE composites was developed. The materials proved suitable as a low weight and low energy sensing material for dimethyl methylphosphonate (DMMP), a nerve gas simulant