Nanocarbon/elastomer composites : characterization and applications in photo-mechanical actuation.

Materials that change shape or dimensions in response to external stimuli are widely used in actuation devices. While plenty of systems respond to heat, light, electricity, and magnetism, there is an emerging class of light-driven actuators based on carbon nanostructure/elastomer composites. The addition of nanomaterials to elastomeric polymers results not only in significant material property improvements such as mechanical strength, but also assists in creating entirely new composite functionalities as with photo-mechanical actuation. Efficient photon absorption by nanocarbons and subsequent energy transduction to the polymeric chains can be used to controllably produce significant amounts of pre-strain dependent motion. Photo-mechanical actuation offers a variety of advantages over traditional devices, including wireless actuation, electro-mechanical decoupling (and therefore low noise), electrical circuit elimination at point of use, massive parallel actuation of device arrays from single light source, and complementary metal–oxide–semiconductor / micro-electro-mechanical (CMOS/MEMS) compatible processing. Applications of photo-responsive materials encompass robotics, plastic motors, photonic switches, micro-grippers, and adaptive micro-mirrors. The magnitude and direction of photo-mechanical actuation responses generated in carbon nanostructure/elastomer composites depend on applied pre-strains. At low levels of pre-strains (3–9%), actuators show reversible photo-induced expansion while at high levels (15–40%), actuators exhibit reversible contraction. Large, light-induced reversible and elastic responses of graphene nanoplatelet (GNP) polymer composites were demonstrated for the first time, with an extraordinary optical-to-mechanical energy conversion factor (?M) of 7–9 MPa/W. Following this demonstration, similar elastomeric composite were fabricated with a variety of carbon nanostructures. Investigation into photo-actuation properties of these composites revealed both layer-dependent, as well as dimensionally-dependent responses. For a given carbon concentration, both steady-state photo-mechanical stress response and energy conversion efficiency were found to be directly related to dimensional state of carbon nanostructure additive, with one-dimensional (1D) carbon nanotubes demonstrating the highest responses (~60 kPa stress and ~5 × 10-3% efficiency at just 1 wt% loading) and three-dimensional (3D) highly ordered pyrolytic graphite demonstrating the lowest responses. Furthermore, development of an advanced dispersion technique (evaporative mixing) resulted in the ability to fabricate conductive composites. Actuation and relaxation kinetics responses were investigated and found to be related not to dimensionality, but rather the percolation threshold of carbon nanostructure additive in the polymer. Establishing a connective network of carbon nanostructure additive allowed for energy transduction responsible for photo-mechanical effect to activate carbon beyond the infrared (IR) illumination point, resulting in enhanced actuation. Additionally, in the conductive samples photoconductivity as a function of applied pre-strain was also measured. Photo-conductive response was found to be inversely proportional to applied pre-strain, demonstrating mechanical coupling. Following investigation into photo-mechanical actuation responses between the various carbon forms, use of these composite actuators to achieve both macroscopic as well as microscopic movement in practical applications was evaluated. Using dual GNP/elastomer actuators, a two-axis sub-micron translation stage was developed, and allowed for two-axis photo-thermal positioning (~100 µm per axis) with 120 nm resolution (limitation of the feedback sensor) and ~5 µm/s actuation speeds. A proportional-integral-derivative control loop automatically stabilizes the stage against thermal drift, as well as random thermal-induced position fluctuations (up to the bandwidth of the feedback and position sensor). Nanopositioner performance characteristics were found to be on par with other commercial systems, with resolution limited only by the feedback system used. A mathematical model was developed to describe the elastomeric composite actuators as a series of n springs, with each spring element having its own independent IR-tunable spring constant. Effects of illumination intensity, position, and amount of the composite actuator illuminated are discussed. This model provided several additional insights, such as demonstrating the ability to place not just one, but multiple stages on a single polymer composite strip and position them independently from one another, a benefit not seen in any other type of positioning system. Further investigation yielded interesting and novel photo-mechanical properties with actuation visible on macroscopic scales. Addition of a third component (thermally expanding microspheres), produced a new class of stimuli-responsive expanding polymer composites with ability to unidirectionally transform physical dimensions, elastic modulus, density, and electrical resistance. Carbon nanotubes and core-shell acrylic microspheres were dispersed in polydimethylsiloxane, resulting in composites that exhibit a binary set of material properties. Upon thermal or IR stimuli, liquid cores encapsulated within the microspheres vaporize, expanding the surrounding shells and stretching the matrix. Microsphere expansion results in visible dimensional changes, regions of reduced polymeric chain mobility, nanotube tensioning, and overall elastic to plastic-like transformation of the composite. Transformations include macroscopic volume expansion (\u3e500%), density reduction (\u3e80%), and elastic modulus increase (\u3e675%). Additionally, conductive nanotubes allow for remote expansion monitoring and exhibit distinct loading-dependent electrical responses. Compared to well-established actuation technologies, research into photo-mechanical properties of carbon-based polymer composites is still in its infancy. Results in this dissertation demonstrate some of the enormous potential of light-driven carbon-based composites for actuation and energy scavenging applications. Furthermore, mechanical response dependence to carbon nanostructure dimensional state could have significance in developing new types of carbon-based mixed-dimensional composites for sensor and actuator systems. As the fabrication processes used here are compatible with CMOS and MEMS processing, carbon-based polymer composites allow for not only scaling actuation systems, but also ability to pattern regions of tailorable expansion, strength, and electrical resistance into a single polymer skin, making these composites ideal for structural and electrical building blocks in smart systems. Continued development of carbon-based polymer composites will extend the promising potential of light-driven actuation technologies and will serve as a catalyst to inspire continued research into energy conversion devices and systems

Index to 1983 NASA Tech Briefs, volume 8, numbers 1-4

Short announcements of new technology derived from the R&D activities of NASA are presented. These briefs emphasize information considered likely to be transferrable across industrial, regional, or disciplinary lines and are issued to encourage commercial application. This index for 1983 Tech Briefs contains abstracts and four indexes: subject, personal author, originating center, and Tech Brief Number. The following areas are covered: electronic components and circuits, electronic systems, physical sciences, materials, life sciences, mechanics, machinery, fabrication technology, and mathematics and information sciences

Design and application of a cellular, piezoelectric, artificial muscle actuator for biorobotic systems

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 2010.Cataloged from PDF version of thesis.Includes bibliographical references (p. 219-227).One of the foremost challenges in robotics is the development of muscle-like actuators that have the capability to reproduce the smooth motions observed in animals. Biological muscles have a unique cellular structure that departs from traditional electromechanical actuators in several ways. A muscle consists of a vast number of muscle fibers and, more fundamentally, sarcomeres that act as cellular units or building blocks. A muscle's output force and displacement are the aggregate effect of the individual building blocks. Thus, without using gearing or transmissions, muscles can be tailored to a range of loads, satisfying specific force and displacement requirements. These natural actuators are desirable for biorobotic applications, but many of their characteristics have been difficult to reproduce artificially. This thesis develops and applies a new artificial muscle actuator based on piezoelectric technology. The essential approach is to use a subdivided, cellular architecture inspired by natural muscle. The primary contributions of this work stem from three sequential aims. The first aim is to develop the operating principles and design of the actuator cellular units. The basic operating principle of the actuator involves nested flexural amplifiers applied to piezoelectric stacks thereby creating an output length strain commensurate with natural muscle. The second aim is to further improve performance of the actuator design by imparting tunable stiffness and resonance capabilities. This work demonstrates a previously unavailable level of tunability in both stiffness and resonance. The final aim is to showcase the capabilities of the actuator design by developing an underwater biorobotic fish system that utilizes the actuators for resonance-based locomotion. Each aspect of this thesis is supported by rigorous analysis and functional prototypes that augment broadly applicable design concepts.by Thomas William Secord.Ph.D

Cumulative index to NASA Tech Briefs, 1986-1990, volumes 10-14

Tech Briefs are short announcements of new technology derived from the R&D activities of the National Aeronautics and Space Administration. These briefs emphasize information considered likely to be transferrable across industrial, regional, or disciplinary lines and are issued to encourage commercial application. This cumulative index of Tech Briefs contains abstracts and four indexes (subject, personal author, originating center, and Tech Brief number) and covers the period 1986 to 1990. The abstract section is organized by the following subject categories: electronic components and circuits, electronic systems, physical sciences, materials, computer programs, life sciences, mechanics, machinery, fabrication technology, and mathematics and information sciences

NASA patent abstracts bibliography: A continuing bibliography. Section 2: Indexes (supplement 42)

A subject index is provided for over 4900 patents and patent applications for the period May 1969 through December 1992. Additional indexes list personal authors, corporate authors, contract numbers, NASA case numbers, U.S. patent class numbers, U.S. patent numbers, and NASA accession numbers

NASA patent abstracts bibliography: A continuing bibliography. Section 2: Indexes (supplement 44)

A subject index is provided for over 5500 patents and patent applications for the period May 1969 through December 1993. Additional indexes list personal authors, corporate authors, contract numbers, NASA case numbers, U.S. patent class numbers, U.S. patent numbers, and NASA accession numbers

NASA patent abstracts bibliography: A continuing bibliography. Section 2: Indexes (supplement 45)

A subject index is provided for over 5600 patents and patent applications for the period May 1969 through June 1994. Additional indexes list personal authors, corporate authors, contract numbers, NASA case numbers, U.S. patent class numbers, U.S. patent numbers, and NASA accession numbers

NASA patent abstracts bibliography: A continuing bibliography. Section 2: Indexes (supplement 46)

A subject index is provided for over 5600 patents and patent applications for the period May 1969 through December 1994. Additional indexes list personal authors, corporate authors, contract numbers, NASA case numbers, U.S. patent class numbers, U.S. patent numbers, and NASA accession numbers

NASA patent abstracts bibliography: A continuing bibliography. Section 2: Indexes (supplement 43)

A subject index is provided for over 5400 patents and patent applications for the period May 1969 through June 1993. Additional indexes list personal authors, corporate authors, contract numbers, NASA case numbers, U.S. patent class numbers, U.S. patent numbers, and NASA accession numbers

NASA patent abstracts bibliography: A continuing bibliography. Section 2: Indexes (supplement 41)

A subject index is provided for over 5200 patents and patent applications for the period May 1969 through June 1992. Additional indexes list personal authors, corporate authors, contract numbers, NASA case numbers, U.S. patent class numbers, U.S. patent numbers, and NASA accession numbers