6 research outputs found

    Ephpheta Bulletin, May 1975

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    A newsletter published for Deaf Catholics in Los Angeles, C

    Mass spectroscopy of molecules following deep-core-shell photoexcitation

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    The relaxation dynamics of HCl, DCl, H{dollar}\sb2{dollar}S, and D{dollar}\sb2{dollar}S following photoexcitation in the vicinity of the Cl, and S K-shell thresholds ({dollar}\sim{dollar}2.8 keV for Cl, {dollar}\sim{dollar}2.5 keV for S) were studied by means of ion time-of-flight mass spectroscopy using monochromatic synchrotron radiation. In all cases, the onset of pre-edge core-shell photoionization precedes the formation on resonance of a significant amount of neutral hydrogen as well as post-collision-interaction effects above threshold. At the lowest resonant excitation to the 6{dollar}\sigma\sp{\*}{dollar} antibonding orbital in HCl, almost half of the excited molecules decay by emission of a neutral H atom, mostly in coincidence with a highly charged Cl{dollar}\sp{n+}{dollar} ion. The present work demonstrates that neutral-atom emission can be a significant decay channel for excited states with very-short lifetimes (1 fs). The first detailed observations of molecular fragmentation mediated by post-collision interaction between a photoelectron and an Auger electron are also presented, evidenced by the re-capture of Cl-K photoelectrons by either Cl{dollar}\sp{n+}{dollar} or H{dollar}\sp+{dollar} dissociation fragments. In addition, examination of the width of the H{dollar}\sp+{dollar} peak in HCl and H{dollar}\sb2{dollar}S spectra taken with the analyzer parallel and perpendicular to the polarization vector of the incident light indicate that the asymmetry parameter {dollar}\beta{dollar} is positive on resonance. Finally, the relaxation dynamics of CH{dollar}\sb3{dollar}Cl following core-shell excitation in the neighborhood of the chlorine K edge ({dollar}\approx{dollar}2.8 keV) were studied using multi-ion coincidence techniques. Analysis of the data provides evidence for sequential fragmentation of the molecule. In addition, for higher ionic charge states, the fragmentation mechanism was seen to change with photon energy

    Research and technology, 1992

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    Selected research and technology activities at Ames Research Center, including the Moffett Field site and the Dryden Flight Research Facility, are summarized. These activities exemplify the Center's varied and productive research efforts for 1992
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