Thermal characterisation of miniature hotplates used in gas sensing technology

The reliability of micro-electronic devices depends on the device operating temperature and therefore self-heating can have an adverse effect on the performance and reliability of these devices. Hence, thermal measurement is crucial including accurate maximum operating temperature measurements to ensure optimum reliability and good electrical performance. In the research presented in this thesis, the high temperature thermal characterisation of novel micro-electro-mechanical systems (MEMS) infra-red (IR) emitter chips for use in gas sensing technology for stable long-term operation were studied, using both IR and a novel thermo-incandescence microscopy. The IR emitters were fabricated using complementary-metal-oxide semiconductor (CMOS) based processing technology and consisted of a miniature micro-heater, fabricated using tungsten metallisation. There is a commercial drive to include MEMS micro-heaters in portable electronic applications including gas sensors and miniaturised IR spectrometers where low power consumption is required. IR thermal microscopy was used to thermally characterise these miniature MEMS micro-heaters to temperatures approaching 700 °C. The research work has also enabled further development of novel thermal measurement techniques, using carbon microparticle infra-red sensors (MPIRS) with the IR thermal microscopy. These microparticle sensors, for the first time, have been used to make more accurate high temperature (approaching 700 °C) spot measurements on the IR transparent semiconductor membrane of the micro-heater. To substantially extend the temperature measurement range of the IR thermal microscope, and to obtain the thermal profiles at elevated temperatures (> 700 °C), a novel thermal measurement approach has been developed by calibrating emitted incandescence radiation in the optical region as a function of temperature. The calibration was carried out using the known melting point (MP) of metal microparticles. The method has been utilised to obtain the high temperature thermo-optical characterisation of the MEMS micro-heaters to temperatures in excess of 1200 °C. The measured temperature results using thermo-incandescence microscopy were compared with calculated electrical temperature results. The results indicated the thermo-incandescence measurements are in reasonable agreement (± 3.5 %) with the electrical temperature approach. Thus, the measurement technique using optical incandescent radiation extends the range of conventional IR microscopy and shows a great potential for making very high temperature spot measurements on electronic devices. The high power (> 500mW) electrical characterisation of the MEMS micro-heaters were also analysed to assess the reliability. The electrical performance results on the MEMS micro-heaters indicated failures at temperatures greater than 1300 °C and Scanning Electron Microscope (SEM) was used to analyse the failure modes

Accurate temperature measurements on semiconductor devices.

Self-heating can have a detrimental effect on the performance and reliability of high power microwave devices. In this work, the thermal performance of the gallium arsenide (GaAs) Gunn diode was studied. Infrared (IR) thermal microscopy was used to measure the peak operating temperature of the graded-gap structured device. Temperature measurements were experimentally validated using micro-thermocouple probing and compared to values obtained from a standard 1D thermal resistance model. Thermal analysis of the conventionally structured Gunn diode was also undertaken using high resolution micro-Raman temperature profiling, IR thermal microscopy and electro/thermal finite element modeling. The accuracy of conventional IR temperature measurements, made on semiconductor devices, was investigated in detail. Significant temperature errors were shown to occur in IR temperature measurements made on IR transparent semiconductors layers and low emissivity/highly reflective metals. A new technique, employing spherical carbon microparticles, was developed to improve the measurement accuracy on such surfaces. The new ‘IR microparticle’ technique can be used with existing IR microscopes and potentially removes the need to coat a device with a high emissivity layer, which causes damage and heat spreading

Strong coupling regime of semiconductor quantum dot embedded in the nano-cavity

Photonic lattices represent suitable systems for investigation of wave propagation in periodic structures [1]. However, different unavoidable defects may arise either during their process of fabrication or as result of misusage, accidental damage, etc. Although undesirable in the first place, these imperfections enable the existence of different types of stable, localized defect modes [2]. In this paper, we investigate light propagation through composite photonic lattice composed of two identical linear and lossless lattices. The interface between them represents a geometric defect, while each lattice contains a single nonlinear defect that is placed symmetrically with respect to the interface. Depending on the input light beam parameters (its position, width and transverse tilt), the width of geometric defect, strength and position of the nonlinear defects, different dynamical regimes have been identified. These dynamical regimes are caused by the balance of photonic lattice potentials’ contributions originating from the presence of the geometric and two nonlinear defects. We have found numerically conditions under which dynamically stable bounded modes can exist in the area between nonlinear defects or between a nonlinear and a geometric defect. Various types of localized modes such as: two-hump, multi-hump, one- and multicomponent moving breathers localized at a certain area among defects have been observed. The parameters can be adjusted to capture light and to prevent light launched inside the area among defects to leave it, i.e. this corresponds to the appearance of the modes trapped inside this area. Since the configuration of the lattice prevents transmission of the light through the area confined by defects, these modes can formally be related to Fano resonances and Fano- blockade [3, 4]. When light is launched outside the area among defects, different dynamical regimes have been distinguished: total reflection, single and double partial reflection and full transmission through the area among defects. These numerical findings may lead to interesting applications such as blocking, filtering and transporting light beams through the optical medium. Photonic devices based on resonant tunneling such as waveguides interacting through the area between defects, may be applied as add-drop filters.V International School and Conference on Photonics and COST actions: MP1204, BM1205 and MP1205 and the Second international workshop "Control of light and matter waves propagation and localization in photonic lattices" : PHOTONICA2015 : book of abstracts; August 24-28, 2015; Belgrad

Photothermal response of a double-layered semi-transparent sample

In this work, a double-layered sample is considered. One layer of the sample is assumed to have high optical absorption coefficient (β1>>1, surface absorber) while the other layer’s optical absorption coefficient, β2 is low, which is a common situation in transmission photothermal experiments with optically transparent samples [1-5] (Figure 1). The expressions are derived for surface temperature variations due to the absorption of excitation EM radiation and its conversion into heat within the sample. The study focused on two experimental cases: In the first, the surface absorber is considered to be exposed to the excitation EM beam, while in the second, the other layer is the one to be exposed. The differences in amplitude and phase characteristics, predicted by theory in these two cases, are discussed.V International School and Conference on Photonics and COST actions: MP1204, BM1205 and MP1205 and the Second international workshop "Control of light and matter waves propagation and localization in photonic lattices" : PHOTONICA2015 : book of abstracts; August 24-28, 2015; Belgrad

Entropie‐dominierte Selbstorganisationsprozesse birnenförmiger Teilchensysteme

The ambition to recreate highly complex and functional nanostructures found in living organisms marks one of the pillars of today‘s research in bio- and soft matter physics. Here, self-assembly has evolved into a prominent strategy in nanostructure formation and has proven to be a useful tool for many complex structures. However, it is still a challenge to design and realise particle properties such that they self-organise into a desired target configuration. One of the key design parameters is the shape of the constituent particles. This thesis focuses in particular on the shape sensitivity of liquid crystal phases by addressing the entropically driven colloidal self-assembly of tapered ellipsoids, reminiscent of „pear-shaped“ particles. Therefore, we analyse the formation of the gyroid and of the accompanying bilayer architecture, reported earlier in the so-called pear hard Gaussian overlap (PHGO) approximation, by applying various geometrical tools like Set-Voronoi tessellation and clustering algorithms. Using computational simulations, we also indicate a method to stabilise other bicontinuous structures like the diamond phase. Moreover, we investigate both computationally and theoretically(density functional theory) the influence of minor variations in shape on different pearshaped particle systems, including the stability of the PHGO gyroid phase. We show that the formation of the gyroid is due to small non-additive properties of the PHGO potential. This phase does not form in pears with a „true“ hard pear-shaped potential. Overall our results allow for a better general understanding of necessity and sufficiency of particle shape in regards to colloidal self-assembly processes. Furthermore, the pear-shaped particle system sheds light on a unique collective mechanism to generate bicontinuous phases. It suggests a new alternative pathway which might help us to solve still unknown characteristics and properties of naturally occurring gyroid-like nano- and microstructures.Ein wichtiger Bestandteil der heutigen Forschung in Bio- und Soft Matter Physik besteht daraus, Technologien zu entwickeln, um hoch komplexe und funktionelle Strukturen, die uns aus der Natur bekannt sind, nachzubilden. Hinsichtlich dessen ist vor allem die Methode der Selbstorganisation von Mikro- und Nanoteilchen hervorzuheben, durch die eine Vielzahl verschiedener Strukturen erzeugt werden konnten. Jedoch stehen wir bei diesem Verfahren noch immer vor der Herausforderung, Teilchen mit bestimmten Eigenschaften zu entwerfen, welche die spontane Anordnung der Teilchen in eine gewünschte Struktur bewirken. Einer der wichtigsten Designparameter ist dabei die Form der Bausteinteilchen. In dieser Dissertation konzentrieren wir uns besonders auf die Anfälligkeit von Flüssigkristallphasen bezüglich kleiner Änderungen der Teilchenform und nutzen dabei das Beispiel der Selbstorganisation von Entropie-dominierter Kolloide, die dem Umriss nach verjüngten Ellipsoiden oder "Birnen" ähneln. Mit Hilfe von geometrischen Werkzeugen wie z.B. Set-Voronoi Tessellation oder Cluster-Algorithmen analysieren wir insbesondere die Entstehung der Gyroidphase und der dazugehörigen Bilagenformation, welche bereits in Systemen von harten Birnen, die durch das pear hard Gaussian overlap (PHGO) Potential angenähert werden, entdeckt wurden. Des Weiteren zeigen wir durch Computersimulationen eine Strategie auf, um andere bikontinuierliche Strukturen, wie die Diamentenphase, zu stabilisieren. Schlussendlich betrachten wir sowohl rechnerisch (durch Simulationen) als auch theoretisch (durch Dichtefunktionaltheorie) die Auswirkungen kleiner Abweichungen der Teilchenform auf das Verhalten des kolloiden, birnenförmigen Teilchensystems, inklusive der Stabilität der PHGO Gyroidphase. Wir zeigen, dass die Entstehung des Gyroids auf kleinen nicht-additiven Eigenschaften des PHGO Birnenmodells beruhen. In ''echten'' harten Teilchensystemen entwickelt sich diese Struktur nicht. Insgesamt ermöglichen unsere Ergebnisse einen besseren Einblick auf das Konzept von notwendiger und hinreichender Teilchenform in Selbstorganistationsprozessen. Die birnenförmigen Teilchensysteme geben außerdem Aufschluss über einen ungewöhnlichen, kollektiven Mechanismus, um bikontinuierliche Phasen zu erzeugen. Dies deutet auf einen neuen, alternativen Konstruktionsweg hin, der uns möglicherweise hilft, noch unbekannte Eigenschaften natürlich vorkommender, gyroidähnlicher Nano- und Mikrostrukturen zu erklären

Laser-induced forward transfer (LIFT) of water soluble polyvinyl alcohol (PVA) polymers for use as support material for 3D-printed structures

The additive microfabrication method of laser-induced forward transfer (LIFT) permits the creation of functional microstructures with feature sizes down to below a micrometre [1]. Compared to other additive manufacturing techniques, LIFT can be used to deposit a broad range of materials in a contactless fashion. LIFT features the possibility of building out of plane features, but is currently limited to 2D or 2½D structures [2–4]. That is because printing of 3D structures requires sophisticated printing strategies, such as mechanical support structures and post-processing, as the material to be printed is in the liquid phase. Therefore, we propose the use of water-soluble materials as a support (and sacrificial) material, which can be easily removed after printing, by submerging the printed structure in water, without exposing the sample to more aggressive solvents or sintering treatments. Here, we present studies on LIFT printing of polyvinyl alcohol (PVA) polymer thin films via a picosecond pulsed laser source. Glass carriers are coated with a solution of PVA (donor) and brought into proximity to a receiver substrate (glass, silicon) once dried. Focussing of a laser pulse with a beam radius of 2 µm at the interface of carrier and donor leads to the ejection of a small volume of PVA that is being deposited on a receiver substrate. The effect of laser pulse fluence , donor film thickness and receiver material on the morphology (shape and size) of the deposits are studied. Adhesion of the deposits on the receiver is verified via deposition on various receiver materials and via a tape test. The solubility of PVA after laser irradiation is confirmed via dissolution in de-ionised water. In our study, the feasibility of the concept of printing PVA with the help of LIFT is demonstrated. The transfer process maintains the ability of water solubility of the deposits allowing the use as support material in LIFT printing of complex 3D structures. Future studies will investigate the compatibility (i.e. adhesion) of PVA with relevant donor materials, such as metals and functional polymers. References: [1] A. Piqué and P. Serra (2018) Laser Printing of Functional Materials. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA. [2] R. C. Y. Auyeung, H. Kim, A. J. Birnbaum, M. Zalalutdinov, S. A. Mathews, and A. Piqué (2009) Laser decal transfer of freestanding microcantilevers and microbridges, Appl. Phys. A, vol. 97, no. 3, pp. 513–519. [3] C. W. Visser, R. Pohl, C. Sun, G.-W. Römer, B. Huis in ‘t Veld, and D. Lohse (2015) Toward 3D Printing of Pure Metals by Laser-Induced Forward Transfer, Adv. Mater., vol. 27, no. 27, pp. 4087–4092. [4] J. Luo et al. (2017) Printing Functional 3D Microdevices by Laser-Induced Forward Transfer, Small, vol. 13, no. 9, p. 1602553