Minimum Dissipation Principle in Nonlinear Transport

We extend Onsager's minimum dissipation principle to stationary states that are only subject to local equilibrium constraints, even when the transport coefficients depend on the thermodynamic forces. Crucial to this generalization is a decomposition of the thermodynamic forces into those that are held fixed by the boundary conditions, and the subspace which is orthogonal with respect to the metric defined by the transport coefficients. We are then able to apply Onsager and Machlup's proof to the second set of forces. As an example we consider two-dimensional nonlinear diffusion coupled to two reservoirs at different temperatures. Our extension differs from that of Bertini et al. in that we assume microscopic irreversibility and we allow a nonlinear dependence of the fluxes on the forces.Comment: 20 pages, 1 figur

Cumulant expansions for atmospheric flows

The equations governing atmospheric flows are nonlinear. Consequently, the hierarchy of cumulant equations is not closed. But because atmospheric flows are inhomogeneous and anisotropic, the nonlinearity may manifest itself only weakly through interactions of mean fields with disturbances such as thermals or eddies. In such situations, truncations of the hierarchy of cumulant equations hold promise as a closure strategy. We review how truncations at second order can be used to model and elucidate the dynamics of atmospheric flows. Two examples are considered. First, we study the growth of a dry convective boundary layer, which is heated from below, leading to turbulent upward energy transport and growth of the boundary layer. We demonstrate that a quasilinear truncation of the equations of motion, in which interactions of disturbances among each other are neglected but interactions with mean fields are taken into account, can capture the growth of the convective boundary layer even if it does not capture important turbulent transport terms. Second, we study the evolution of two-dimensional large-scale waves representing waves in Earth's upper atmosphere. We demonstrate that a cumulant expansion truncated at second order (CE2) can capture the evolution of such waves and their nonlinear interaction with the mean flow in some circumstances, for example, when the wave amplitude is small enough or the planetary rotation rate is large enough. However, CE2 fails to capture the flow evolution when nonlinear eddy--eddy interactions in surf zones become important. Higher-order closures can capture these missing interactions. The results point to new ways in which the dynamics of turbulent boundary layers may be represented in climate models, and they illustrate different classes of nonlinear processes that can control wave dissipation and momentum fluxes in the troposphere.Comment: 43 pages, 10 figures, accepted for publication in the New Journal of Physic

Thermal conduction in classical low-dimensional lattices

Deriving macroscopic phenomenological laws of irreversible thermodynamics from simple microscopic models is one of the tasks of non-equilibrium statistical mechanics. We consider stationary energy transport in crystals with reference to simple mathematical models consisting of coupled oscillators on a lattice. The role of lattice dimensionality on the breakdown of the Fourier's law is discussed and some universal quantitative aspects are emphasized: the divergence of the finite-size thermal conductivity is characterized by universal laws in one and two dimensions. Equilibrium and non-equilibrium molecular dynamics methods are presented along with a critical survey of previous numerical results. Analytical results for the non-equilibrium dynamics can be obtained in the harmonic chain where the role of disorder and localization can be also understood. The traditional kinetic approach, based on the Boltzmann-Peierls equation is also briefly sketched with reference to one-dimensional chains. Simple toy models can be defined in which the conductivity is finite. Anomalous transport in integrable nonlinear systems is briefly discussed. Finally, possible future research themes are outlined.Comment: 90 pages, revised versio

Broken space-time symmetries and mechanisms of rectification of ac fields by nonlinear (non)adiabatic response

We consider low-dimensional dynamical systems exposed to a heat bath and to additional ac fields. The presence of these ac fields may lead to a breaking of certain spatial or temporal symmetries which in turn cause nonzero averages of relevant observables. Nonlinear (non)adiabatic response is employed to explain the effect. We consider a case of a particle in a periodic potential as an example and discuss the relevant symmetry breakings and the mechanisms of rectification of the current in such a system.Comment: 11 pages, 10 figure