Fine Tuning Classical and Quantum Molecular Dynamics using a Generalized Langevin Equation

Generalized Langevin Equation (GLE) thermostats have been used very effectively as a tool to manipulate and optimize the sampling of thermodynamic ensembles and the associated static properties. Here we show that a similar, exquisite level of control can be achieved for the dynamical properties computed from thermostatted trajectories. By developing quantitative measures of the disturbance induced by the GLE to the Hamiltonian dynamics of a harmonic oscillator, we show that these analytical results accurately predict the behavior of strongly anharmonic systems. We also show that it is possible to correct, to a significant extent, the effects of the GLE term onto the corresponding microcanonical dynamics, which puts on more solid grounds the use of non-equilibrium Langevin dynamics to approximate quantum nuclear effects and could help improve the prediction of dynamical quantities from techniques that use a Langevin term to stabilize dynamics. Finally we address the use of thermostats in the context of approximate path-integral-based models of quantum nuclear dynamics. We demonstrate that a custom-tailored GLE can alleviate some of the artifacts associated with these techniques, improving the quality of results for the modelling of vibrational dynamics of molecules, liquids and solids

Parallel generation of quadripartite cluster entanglement in the optical frequency comb

Scalability and coherence are two essential requirements for the experimental implementation of quantum information and quantum computing. Here, we report a breakthrough toward scalability: the simultaneous generation of a record 15 quadripartite entangled cluster states over 60 consecutive cavity modes (Qmodes), in the optical frequency comb of a single optical parametric oscillator. The amount of observed entanglement was constant over the 60 Qmodes, thereby proving the intrnisic scalability of this system. The number of observable Qmodes was restricted by technical limitations, and we conservatively estimate the actual number of similar clusters to be at least three times larger. This result paves the way to the realization of large entangled states for scalable quantum information and quantum computing.Comment: 4 pages + 7 supplemental-info pages, 6+1 figures, accepted by Physical Review Letters. One minor revision to main text. One error corrected in Eq. (18) of Supplemental informatio

Part I - Application of ultra-stable oscillators to one-way ranging systems. Part II - Fluctuation spectra of ultra- stable oscillators - Measurement and estimation Final report

Application of ultrastable oscillators to one-way ranging systems - Measurement technique for determining phase fluctuation spectrum of highly stable oscillator

Theory of quantum fluctuations of optical dissipative structures and its application to the squeezing properties of bright cavity solitons

We present a method for the study of quantum fluctuations of dissipative structures forming in nonlinear optical cavities, which we illustrate in the case of a degenerate, type I optical parametric oscillator. The method consists in (i) taking into account explicitly, through a collective variable description, the drift of the dissipative structure caused by the quantum noise, and (ii) expanding the remaining -internal- fluctuations in the biorthonormal basis associated to the linear operator governing the evolution of fluctuations in the linearized Langevin equations. We obtain general expressions for the squeezing and intensity fluctuations spectra. Then we theoretically study the squeezing properties of a special dissipative structure, namely, the bright cavity soliton. After reviewing our previous result that in the linear approximation there is a perfectly squeezed mode irrespectively of the values of the system parameters, we consider squeezing at the bifurcation points, and the squeezing detection with a plane--wave local oscillator field, taking also into account the effect of the detector size on the level of detectable squeezing.Comment: 10 figure

Squeezed Light and Entangled Images from Four-Wave-Mixing in Hot Rubidium Vapor

Entangled multi-spatial-mode fields have interesting applications in quantum information, such as parallel quantum information protocols, quantum computing, and quantum imaging. We study the use of a nondegenerate four-wave mixing process in rubidium vapor at 795 nm to demonstrate generation of quantum-entangled images. Owing to the lack of an optical resonator cavity, the four-wave mixing scheme generates inherently multi-spatial-mode output fields. We have verified the presence of entanglement between the multi-mode beams by analyzing the amplitude difference and the phase sum noise using a dual homodyne detection scheme, measuring more than 4 dB of squeezing in both cases. This paper will discuss the quantum properties of amplifiers based on four-wave-mixing, along with the multi mode properties of such devices.Comment: 11 pages, 8 figures. SPIE Optics and Photonics 2008 proceeding (San Diego, CA

Performance measures for single-degree-of-freedom energy harvesters under stochastic excitation

We develop performance criteria for the objective comparison of different classes of single-degree-of-freedom oscillators under stochastic excitation. For each family of oscillators, these objective criteria take into account the maximum possible energy harvested for a given response level, which is a quantity that is directly connected to the size of the harvesting configuration. We prove that the derived criteria are invariant with respect to magnitude or temporal rescaling of the input spectrum and they depend only on the relative distribution of energy across different harmonics of the excitation. We then compare three different classes of linear and nonlinear oscillators and using stochastic analysis tools we illustrate that in all cases of excitation spectra (monochromatic, broadband, white-noise) the optimal performance of all designs cannot exceed the performance of the linear design. Subsequently, we study the robustness of this optimal performance to small perturbations of the input spectrum and illustrate the advantages of nonlinear designs relative to linear ones.Comment: 24 pages, 12 figure