ENMat international projects: FP7 NMP coordination action: 2BFUNTEX

Boosting collaboration between research centres and industry to enhance rapid industrial uptake of innovative functional textile structures and textile-related materials in a mondial market 2BFUNTEX will exploit the untapped potential in functional textile structures and textile related materials. It will bring together all innovation actors in the field fostering a multidisciplinary approach between universities, research institutes, SMEs and sector associations. The 2BFUNTEX team will identify technological gaps and eliminate barriers resulting in a faster industrial uptake of added value functional materials with new functionalities and improved performance and resulting in creation of new business worldwide. Technological needs will be mapped, new joint international research disciplines will be identified and multidisciplinary lab teams will be created. International cooperation will be favoured to exploit the worldwide market expansion potential. Industry will be involved at all stages of the process. The inventory will enlarge the team of important textile universities and renowned materials research centres and will identify new collaborations. Synergy will be reinforced and created which will enable to identify and develop new functional materials. Training materials regarding functional materials for research and industrial purposes will be developed and implemented to allow a common language regarding functional textile structures and text ile related materials, and will increase the number of well-trained people in this field. Further, the 2BFUNTEX partners will organise and participate in conferences, workshops and brokerage events. Along with a website with an extensive database comprising all information gained throughout the project, collaboration will be boosted and rapid industrial uptake catalysed and enhanced. The project duration will be 4 years and the consortium includes 26 partners from 16 countries. Start date : 01/01/2012 More information: Ir. Els Van der Burght Department of Textiles/Ghent University [email protected] [email protected] URL: http://www.2bfuntex.e

ENMat international projects: FP7 NMP large collaborative project: 3D-LightTrans

Large scale manufacturing technology for high-performance lightweight 3D multifunctional composites The goal of the 3D-LightTrans project is to provide groundbreaking, highly flexible, efficient and adaptable low-cost technologies for the manufacturing of integral large scale 3D textile reinforced plastic composites, including innovative approaches for the individual processes and its integration in complete manufacturing chains, which will enable to shift them from its current position in cost intensive, small series niche markets, to broadly extended mass product applications, not only in transportation, but also in other key sectors, like health and leisure. To fulfil this goal, the 3DLightTrans manufacturing chains will be based on multimaterial semifinished fabrics, processed to deep draped prefixed multilayered and multifunctional 3D -textile preforms, which will be processed into composites by a thermoforming process. By integrating these new, innovative process steps with full automation in -nowadays mostly manually performed- complex handling operations, it will be possible to obtain a fully automated and highly adaptable manufacturing chain to achieve integral large scale 3D composites. 3D-LightTrans will open the way to a totally new concept for the design, manufacturing and application of composites for low-cost mass products in a wide range of sectors. The Consortium brings together multidisciplinary research teams involving European leading companies, including industrial stakeholders from machine tools and machine automation and several OEM active in the field of processing of flexible materials and composite manufacturing, as well as from the application sector, and extensive expertise from well known research specialists in the area of materials, production research and technical textiles in particular. Start date : 01/04/2011 Project duration : 4 years More information: Dr. Erich Kny Austrian Institute of Technology, [email protected] URL: http://www.3d-lighttrans.com

Identification of single nucleotides in MoS2 nanopores

Ultrathin membranes have drawn much attention due to their unprecedented spatial resolution for DNA nanopore sequencing. However, the high translocation velocity (3000-50000 nt/ms) of DNA molecules moving across such membranes limits their usability. To this end, we have introduced a viscosity gradient system based on room-temperature ionic liquids (RTILs) to control the dynamics of DNA translocation through a nanometer-size pore fabricated in an atomically thin MoS2 membrane. This allows us for the first time to statistically identify all four types of nucleotides with solid state nanopores. Nucleotides are identified according to the current signatures recorded during their transient residence in the narrow orifice of the atomically thin MoS2 nanopore. In this novel architecture that exploits high viscosity of RTIL, we demonstrate single-nucleotide translocation velocity that is an optimal speed (1-50 nt/ms) for DNA sequencing, while keeping the signal to noise ratio (SNR) higher than 10. Our findings pave the way for future low-cost and rapid DNA sequencing using solid-state nanopores.Comment: Manuscript 24 pages, 4 Figures Supporting Information 24 pages, 12 Figures, 2 Tables Manuscript in review Nature Nanotechnology since May 27th 201

Magnetoresistive junctions based on epitaxial graphene and hexagonal boron nitride

We propose monolayer epitaxial graphene and hexagonal boron nitride (h-BN) as ultimate thickness covalent spacers for magnetoresistive junctions. Using a first-principles approach, we investigate the structural, magnetic and spin transport properties of such junctions based on structurally well defined interfaces with (111) fcc or (0001) hcp ferromagnetic transition metals. We find low resistance area products, strong exchange couplings across the interface, and magnetoresistance ratios exceeding 100% for certain chemical compositions. These properties can be fine tuned, making the proposed junctions attractive for nanoscale spintronics applications.Comment: 5 page

Magnetic nano-fluctuations in a frustrated magnet

Frustrated systems exhibit remarkable properties due to the high degeneracy of their ground states. Stabilised by competing interactions, a rich diversity of typically nanometre-sized phase structures appear in polymer and colloidal systems, while the surface of ice pre-melts due to geometrically frustrated interactions. Atomic spin systems where magnetic interactions are frustrated by lattice geometry provide a fruitful source of emergent phenomena, such as fractionalised excitations analogous to magnetic monopoles. The degeneracy inherent in frustrated systems may prevail all the way down to absolute zero temperature, or it may be lifted by small perturbations or entropic effects. In the geometrically frustrated Ising--like magnet Ca3Co2O6, we follow the temporal and spatial evolution of nanoscale magnetic fluctuations firmly embedded inside the spin--density--wave magnetic structure. These fluctuations are a signature of a competing ferrimagnetic phase with an incommensurability that is different from, but determined by the host. As the temperature is lowered, the fluctuations slow down into a super-paramagnetic regime of stable spatiotemporal nano-structures

Nonlinear Optical Properties of Core-Shell Nanocavities for Enhanced Second-Harmonic Generation

A nonlinear optical plasmonic core-shell nanocavity is demonstrated as an efficient, subwavelength coherent light source through second-harmonic generation. The nonlinear optical plasmonic nanocavity incorporates a noncentrosymmetric medium, which utilizes the entire mode volume for even-order nonlinear optical processes. In previous plasmonic nanocavities, enhancement of such processes was only possible at the interface but symmetry prohibited in the body. We measured an enhancement of over 500 times in the second-harmonic radiation power. Calculations show that an enhancement of over 3500 times is achievable

Patchy Amphiphilic Dendrimers Bind Adenovirus and Control Its Host Interactions and in Vivo Distribution

The surface of proteins is heterogeneous with sophisticated but precise hydrophobic and hydrophilic patches, which is essential for their diverse biological functions. To emulate such distinct surface patterns on macromolecules, we used rigid spherical synthetic dendrimers (polyphenylene dendrimers) to provide controlled amphiphilic surface patches with molecular precision. We identified an,. I optimal spatial arrangement of these patches on certain dendrimers that enabled their interaction with human adenovirus 5 (Ads). Patchy dendrimers bound to the surface of Ads formed a synthetic polymer corona that greatly altered various host interactions of Ads as well as in vivo distribution. The dendrimer corona (1) improved the ability of Ad5-derived gene transfer vectors to transduce cells deficient for the primary Ad5 cell membrane receptor and (2) modulated the binding of Ads to blood coagulation factor X, one of the most critical virus host interactions in the bloodstream. It significantly enhanced the transduction efficiency of Ad5 while also protecting it from neutralization by natural antibodies and the complement system in human whole blood. Ads with a synthetic dendrimer corona revealed profoundly altered in vivo distribution, improved transduction of heart, and dampened vector sequestration by liver and spleen. We propose the design of bioactive polymers that bind protein surfaces solely based on their amphiphilic surface patches and protect against a naturally occurring protein corona, which is highly attractive to improve Ad5-based in vivo gene therapy applications