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    Wilhelmum I. Serenissimum Hassiae Electorem, Etc. Etc. Magnum Ducem Fuldae Datum Esse Fuldamque XIII Cal. Junias Advenisse Civibus Gratulatur V. Vogt, Clericus

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    WILHELMUM I. SERENISSIMUM HASSIAE ELECTOREM, ETC. ETC. MAGNUM DUCEM FULDAE DATUM ESSE FULDAMQUE XIII CAL. JUNIAS ADVENISSE CIVIBUS GRATULATUR V. VOGT, CLERICUS Wilhelmum I. Serenissimum Hassiae Electorem, Etc. Etc. Magnum Ducem Fuldae Datum Esse Fuldamque XIII Cal. Junias Advenisse Civibus Gratulatur V. Vogt, Clericus ( - ) Titelseite ( - ) [Hauptteil.] ( -

    Chinese Ceramics: The Wong Collection

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    tableOfContents: Preface Page iv Introduction Page v Notes Page xi Chronology Page xiii Collection Page 1 Acknowledgements Page 8

    Detailed crystallographic analysis of the ice V to ice XIII hydrogen-ordering phase transition

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    Ice V is a structurally highly complex material with 28 water molecules in its monoclinic unit cell. It is classified as a hydrogen-disordered phase of ice. Yet, some of its hydrogen-bonded water molecules display significant orientational order. Upon cooling pure ice V, additional orientational ordering cannot be achieved on the experimental time scale. Doping with hydrochloric acid has been shown to be most effective in enabling the phase transition of ice V to its hydrogen-ordered counterpart ice XIII. Here, we present a detailed crystallographic study of this phase transition investigating the effects of hydrochloric and hydrofluoric acid as well as lithium and potassium hydroxide doping. The magnitudes of the stepwise changes in the lattice constants during the phase transition are found to be more sensitive indicators for the extent of hydrogen order in ice XIII than the appearance of new Bragg peaks. Hydrofluoric acid and lithium hydroxide doping enable similar ordering processes as hydrochloric acid but with slower kinetics. The various possible space groups and ordered configurations of ice XIII are examined systematically, and the previously determined P21/a structure is confirmed. Interestingly, the partial hydrogen order already present in ice V is found to perpetuate into ice XIII, and these ordering processes are found to be independent of pressure. Overall, the hydrogen ordering goes along with a small increase in volume, which appears to be the origin of the slower hydrogen-ordering kinetics under pressure. Heating pressure-quenched samples at ambient pressure revealed low-temperature "transient ordering" features in both diffraction and calorimetry

    World Peace: Rational Idea and Reality On the Principles of Kant's Political Philosophy

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    Kant's various teachings concerning (world) peace are characterized by a philosophically unique realism. Thereby, they are fundamentally distinguished from all preceding doctrines about peace. This thesis of realism refers to various aspects, respectively levels, of the doctrine, namely: 1) in general to the assumptions of the doctrine of Right3 altogether (ch. II); 2) in particular to the assumptions of the doctrine of eternal peace (chs. III-V); 3) to the recommendations with regard to the realization of eternal peace (chs. VI-XI); 4) to the reasons by which Kant justifies the hope with regard to eternal peace (ch. XII, XIV-XVII); 5) to Kant's strict denial of a specifically political "morals" (ch. XIII-XVII)

    Low modulus novel bone substitutes for osteoporotic vertebral fracture management

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    Oral presentationpublished_or_final_versioneCM XIII - Bone Fixation, Repair & Regeneration, Davos Platz, Switzerland, 24-26 June 2012. In European Cells & Materials, 2012, v. 24 n. Suppl. 1, p. 1

    Ressenyes

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    Index de les obres ressenyades: Claude CAROZZI, Le voyage de l'âme dans l'au-delà. D'après la littérature latine (v-XIII siècle). Paris: École Française de Rome, 199

    Benchmarking acid and base dopants with respect to enabling the ice V to XIII and ice VI to XV hydrogen-ordering phase transitions

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    Doping the hydrogen-disordered phases of ice V, VI and XII with hydrochloric acid (HCl) has led to the discovery of their hydrogen-ordered counterparts ices XIII, XV and XIV. Yet, the mechanistic details of the hydrogen-ordering phase transitions are still not fully understood. This includes in particular the role of the acid dopant and the defect dynamics that it creates within the ices. Here we investigate the effects of several acid and base dopants on the hydrogen ordering of ices V and VI with calorimetry and X-ray diffraction. HCl is found to be most effective for both phases which is attributed to a favourable combination of high solubility and strong acid properties which create mobile H3O+ defects that enable the hydrogen-ordering processes. Hydrofluoric acid (HF) is the second most effective dopant highlighting that the acid strengths of HCl and HF are much more similar in ice than they are in liquid water. Surprisingly, hydrobromic acid doping facilitates hydrogen ordering in ice VI whereas only a very small effect is observed for ice V. Conversely, lithium hydroxide (LiOH) doping achieves a performance comparable to HF-doping in ice V but it is ineffective in the case of ice VI. Sodium hydroxide, potassium hydroxide (as previously shown) and perchloric acid doping are ineffective for both phases. These findings highlight the need for future computational studies but also raise the question why LiOH-doping achieves hydrogen-ordering of ice V whereas potassium hydroxide doping is most effective for the 'ordinary' ice Ih.Comment: 18 pages, 7 figures, 1 tabl
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