The Influence of Halide Substituents on the Structural and Magnetic Properties of Fe6_{6}Dy3_{3} Rings

We report the synthesis and magnetic properties of three new nine-membered Fe(III)-Dy(III) cyclic coordination clusters (CCCs), with a core motif of [Fe$_{6}$Dy$_{3}$(μ-OMe)$_{9}$(vanox)$_{6}$(X-benz)$_{6}$] where the benzoate ligands are substituted in the para-position with X = F (1), Cl (2), Br (3). Single crystal X-ray diffraction structure analyses show that for the smaller fluorine or chlorine substituents the resulting structures exhibit an isostructural Fe$_{6}$Dy$_{3}$ core, whilst the 4-bromobenzoate ligand leads to structural distortions which affect the dynamic magnetic behavior. The magnetic susceptibility and magnetization of 1-3 were investigated and show similar behavior in the dc (direct current) magnetic data. Additional ac (alternating current) magnetic measurements show that all compounds exhibit frequency-dependent and temperature-dependent signals in the in-phase and out-of-phase component of the susceptibility and can therefore be described as field-induced SMMs. The fluoro-substituted benzoate cluster 1 shows a magnetic behavior closely similar to that of the corresponding unsubstituted Fe$_{6}$Dy$_{3}$ cluster, with U$_{eff}$ = 21.3 K within the Orbach process. By increasing the size of the substituent toward 4-chlorobenzoate within 2, an increase of the energy barrier to U$_{eff}$ = 36.1 K was observed. While the energy barrier becomes higher from 1 to 2, highlighting that the introduction of different substituents on the benzoate ligand in the para-position has an impact on the magnetic properties, cluster 3 shows a significantly different SMM behavior where U$_{eff}$ is reduced in the Orbach regime to only 4.9 K

The high latitude ionosphere-magnetosphere transition region: Simulation and data comparison

A brief description of the major activities pursued during the last year (March 1994 - February 1995) of this grant are: (1) the development of a 200 km to 1 Re, O(+) H(+) Model; (2) the extension of the E x B convection heating study to include centrifugal effects; (3) the study of electron precipitation effects; (4) the study of wave heating of O(+); and (5) the polar wind acceleration study. A list of both papers published and papers submitted, along with a proposal for next year's study and a copy of the published paper is included

Reduced scale feasibility of temperature rise tests in substation connectors

Due to the important increase of the power of electrical transmission and distribution grids expected for the following years, especially in developing countries such as Kenya, Brazil, Philippines or Mexico among others, that have planes of generating energy from clean sources far away from the centres of consumption [1] it becomes a matter of special importance adapting and developing new substation connectors’ testing methods according to the power and temperature regimes at which they are expected to work. The international normative frame of substation connectors established both by the International Electrotechnical Committee (IEC) [2] and the National Electrical Manufacturers Association (NEMA) [3] sets standardized tests for the evaluation of high voltage connectors. These tests are routinely done within the quality plans of the manufacturers. At the moment, testing of substation connectors –and in general switchgear and fittings- is time demanding and costly due to the energy consumed by such tests. The expectations for the following years are that the power consumption of these tests will not do nothing but grow due to expected increase of power of worldwide overhead lines. For instance, today temperature rise tests in substation connectors involve power ranges up to 100 kVA, which are applied in cycles that can last several weeks. These tests are only feasible in few laboratories and at a very high cost: temporary, monetary, energetic and environmental. For this reason, following the line of other technologies such as aeronautics, naval engineering, or automotive as well as other studies done in the field of electrical engineering specially related to the corona effect [4], this study proposes to develop a reduced scale test system to perform temperature rise tests for substation connectors. Both, a theoretical framework based on analytical formulas, finite element method (FEM) simulations and experimental data has been developed to conduct reduced scale temperature rise tests and to set the conditions at which they provide comparable results to those attained in the original scale tests. Firstly, two circular loops (original and reduced scale loops) composed of a power conductor and two terminal connectors were analysed. The aim of this first study was to determine in an easy and trustful way the voltage and current values to be applied in experimental reduced scale tests to achieve the same steady-state temperature as in the original scale temperature rise test. The scale relationship between tests was set in 1:1.8, although the method proposed in this study can deal with any other scale factor. This study was useful in order to have a first sight of the final results of the procedure using substation connectors.Postprint (published version