textjournal article
Palladium-Catalyzed Carbonylation of Aryl Tosylates and Mesylates
Abstract
A general protocol for the palladium-catalyzed carbonylation of aryl tosylates and mesylates to form esters has been developed using a catalyst system derived from Pd(OAc)2 and the bulky, bidentate dcpp ligand. The system operates under mild conditions: atmospheric CO pressure and temperatures of 80−110 °C. A broad substrate scope has been demonstrated allowing carbonylation of electron-rich, electron-poor, and heterocyclic tosylates and mesylates, and the reaction shows wide functional group tolerance- Text
- Journal contribution
- Biophysics
- Biochemistry
- Molecular Biology
- Chemical Sciences not elsewhere classified
- Physical Sciences not elsewhere classified
- Carbonylation
- Pd
- carbonylation
- substrate scope
- MesylatesA
- form esters
- heterocyclic tosylates
- Aryl Tosylates
- mesylate
- group tolerance
- CO pressure
- catalyst system
- aryl tosylates
- bidentate dcpp ligand
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Last time updated on 16/03/2018
This paper was published in The Francis Crick Institute.
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