textjournal article
Leaving Group Property of Dimethyl Sulfide
Abstract
The LFER equation log k = sf(Ef + Nf) was used to derive the nucleofuge specific parameters (Nf and sf) for dimethyl sulfide in the series of aqueous alcohols, using the SN1 solvolysis rate constants obtained for X-substituted benzhydryl dimethyl sulfonates 1−5. The slope parameters (sf) are practically independent of the solvent used, while Nf parameters slightly decrease as the polarity of the solvent increases- Text
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- Dimethyl SulfideThe LFER equation log k
- dimethyl sulfide
- slope parameters
- SN 1 solvolysis rate constants
- Nf parameters
- Group Property
- sf
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Last time updated on 16/03/2018
This paper was published in The Francis Crick Institute.
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