Synthesis of Coumarin/Pyrrole-Fused Heterocycles and Their Photochemical and Redox-Switching Properties
Abstract
Two coumarin/pyrrole-fused heterocycles were synthesized to investigate their photochemical and redox-switching properties. Photooxidation of the colorless diphenyl-substituted pyrrolocoumarin resulted in a distinct change to red and a sharp decrease in fluorescence intensity. The photooxidized product can be swiftly reverted to the original form by NaCNBH3 reduction or hydrogenation- Dataset
- Dataset
- Biochemistry
- Medicine
- Plant Biology
- Chemical Sciences not elsewhere classified
- Physical Sciences not elsewhere classified
- PropertiesTwo
- Coumarin
- Heterocycle
- hydrogenation
- coumarin
- Synthesi
- Photochemical
- heterocycle
- pyrrolocoumarin
- photooxidized product
- fluorescence intensity
- Photooxidation
- NaCNBH 3 reduction
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Last time updated on 12/02/2018
This paper was published in The Francis Crick Institute.
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