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oaioai:figshare.com:article/3175027

Copper(I)-Catalyzed Heterocyclization of α‑Acyl-α-alkynyl Ketene Dithioacetals: Synthesis of 3‑Cyanofurans

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Publication date
2 May 2016
Publisher
Doi

    Abstract

    A new method for the synthesis of 3-cyanofurans via Cu­(I)-catalyzed heterocyclization of α-acyl-α-alkynyl ketene dithioacetals in the presence of ammonium acetate has been developed. The procedure generates the cyano moiety in situ with ammonium acetate as the nitrogen source. Based upon experimental observations, a plausible reaction mechanism is proposed

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    The Francis Crick Institute

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    Last time updated on 12/02/2018

    This paper was published in The Francis Crick Institute.

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