Construction and catalytic activities of polyoxometalate-based compound containing helical chains

Abstract

<p>A polyoxometalate-based, inorganic–organic hybrid compound containing a helical structure along the <i>a</i> axis, [Ag(pyttz)₂][H₂PW₁₂O₄₀]·2H₂O (<i>p-</i>pyttz = 3-(pyrid-4-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl), has been isolated and structurally characterized. Single-crystal X-ray diffraction analysis reveals that the new compound possesses two helical channels constructed by the left- and right-handed helical chains, respectively, which are fused together through sharing POMs dimer fabricating a 3-D framework with {4⁴·5³·6³} {4⁴·5³·6³} topolopy. The new compound displays good acid-catalytic activity toward the synthesis of Aspirin and good oxidation-catalytic activity to the decomposition of Rhodamine B dye; the catalytic reaction kinetics are discussed.</p