Synthesis of 6‑Phosphorylated Phenanthridines by Mn(II)-Promoted Tandem Reactions of 2‑Biaryl Isothiocyanates with Phosphine Oxides
Abstract
A novel Mn(II)-promoted tandem phosphorylation/cyclization reaction of 2-biaryl isothiocyanates with phosphine oxides is described. This is the first general method to synthesize 6-phosporylated phenanthridines from 2-biaryl isothiocyanates. The approach is featured by oxidant-free, low loading of P-reagent, easy operation, and high functional group tolerance- Dataset
- Dataset
- Biochemistry
- Medicine
- Microbiology
- Genetics
- Molecular Biology
- Physiology
- Chemical Sciences not elsewhere classified
- oxidant-free
- Phosphine Oxides
- phosphine oxides
- loading
- Isothiocyanate
- group tolerance
- P-reagent
- Tandem
- approach
- method
- Synthesi
- Phenanthridine
- Mn
- Phosphorylated
- tandem
- 6- phosporylated phenanthridines
- phosphorylation
- 2- biaryl isothiocyanates
- Biaryl
Similar works
This paper was published in FigShare.
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