First total synthesis of parvistone C and its C8-epimer
Abstract
<p>Diastereoselective first total synthesis of parvistone C <b>1</b> and C8-epimer <b>1a</b> are described. The key features of our synthesis include Sharpless asymmetric dihydroxylation, stereoselective aryl Grignard reactions, Still–Gennari olefination, and intramolecular cyclization.</p- Text
- Journal contribution
- Biophysics
- Biochemistry
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- Molecular Biology
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- Marine Biology
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- Chemical Sciences not elsewhere classified
- Intramolecular cyclization
- parvistones
- Sharpless asymmetric dihydroxylation
- Still–Gennari olefination
- styryl lactones
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This paper was published in FigShare.
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